Angewandte Chemie International Edition
Articles in this Issue
Stepwise Reduction of Ruthenium and Growth of Magnetic Structure During Hydrothermal Crystallisation of SrRu <sub>2</sub> O <sub>6</sub> from KRuO <sub>4</sub>
Abstract Using a new design of hydrothermal reactor constructed from a null‐scattering TiZr alloy in situ powder neutron diffraction data are collected to follow...
Compressed Co–O Bonds Resist Chlorine Corrosion to Enhance the Stability of Chlorine‐Involved Anodic Reactions
Abstract Chlorine (Cl)‐involved anodic reactions are essential for green manufacturing, whereas electrocatalysts suffer from deactivation due to Cl corrosion. He...
Are i‐Motif Structures in DNA Compatible with Cytosine–Ag(I)–Cytosine Base Pairs?
Abstract To evaluate whether the protons of hemi‐protonated C:CH + base pairs in DNA i‐motif structures can be replaced b...
Overcoming the Activity‐CH <sub>4</sub> Reducibility Trade‐off in Dry Reforming of Methane via Spatially Separated Rh <sub>1</sub> and Frustrated Lewis Pairs
Abstract Achieving high CO 2 conversion with minimal reductant input is essential for enabling a sustainable carbon cycle...
Vertically Aligned Metal–Organic Framework Arrays as Protective Layers for Durable Zinc Anodes with Low Overpotentials
Abstract Rechargeable aqueous zinc–ion batteries (ZIBs) are promising for large‐scale energy storage due to their high safety and low cost, yet side reactions an...
Enhanced CO Oxidation on PtO <sub>x</sub> Raft Species Synthesized via Citric Acid‐Assisted Electrostatic Adsorption
Abstract Platinum‐based catalysts have attracted considerable attention for CO oxidation, with their activity critically dependent on the nanostructures of Pt sp...
Construction of Artificial Cells with Urea Cycle Pathway for Ammonia Detoxification
Abstract The bottom‐up construction of artificial cells helps to understand cell working mechanisms. It is a great challenge to build artificial cells capable of...
Generation of the NCN Radical from Co‐Conversion of N <sub>2</sub> and CO <sub>2</sub> Mediated by the Niobium Oxide Cluster Anion Nb <sub>2</sub> O <sub>3</sub> <sup>–</sup>
Abstract Cyanonitrene radical (NCN) is a valuable species involved in many subareas of chemistry including combustion, atmospheric, interstellar, and synthetic c...
Energy‐Efficient Electro‐Fenton Oxidation Enabled by CoCu Dual‐Atom Catalysts with High Oxygen Utilization
Abstract The Electro‐Fenton (EF) technique offers a promising strategy for recalcitrant organic pollutant removal by coupling the two‐electron oxygen reduction r...
Merging Pyrrole with Boron into Versatile Di(2‐pyrryl)borane Building Blocks: π‐Extension, Polymerization, and Coordination
Abstract Conjugated di(hetaryl)boranes—particularly those of thiophene, but also of furan—have recently proven to be extremely useful building blocks for organic...
Controlled‐Disorder Asymmetrical Donors Enable Efficient All‐Small‐Molecule Solar Cells with Excellent Solution‐Processability
Abstract All‐small‐molecule organic solar cells (all‐SMOSCs) are promising candidates for next‐generation photovoltaics owing to their well‐defined molecular structures and excellent...
Crystal Structures and Intermolecular Interactions in α$\alpha$‐ and β$\beta$‐phosgene
Abstract The crystal structures of ‐ and ‐phosgene have been elucidated on the basis of variable temperature neutron powder diffraction. Although the stable ‐pha...
Engineering Full‐Spectrum Upconversion Through Coherent Energy Recycling in NaYF <sub>4</sub> :Yb,Tm/Cs <sub>4</sub> PbBr <sub>6</sub> Heterostructure
Abstract Hybrid heterojunctions integrating lanthanide‐doped upconversion nanoparticles (UCNPs) and lead‐halide perovskites (LHPs) offer compelling opportunities...
De Novo Design of Hexamer‐Linker Dual‐Action Nano‐PROTAC for Tumor‐Specific Ferroptosis
Abstract Proteolysis‐Targeting Chimera (PROTAC) technology, a groundbreaking approach in drug discovery, leverages the ubiquitin‐proteasome system to degrade disease‐related proteins...
Low‐Pressure‐Threshold Triggered Irreversible Emission Transformation toward Flexible Pressure Imaging and Information Encryption
Abstract Pressure‐driven irreversible emission transformation as an efficient means greatly facilitates the development of the rational structural design of high...
Unlocking the Orbital Interaction Mode in Li–O <sub>2</sub> Batteries
Abstract Understanding electrocatalyst‐intermediate orbital interaction in oxygen evolution reactions (OER) is critical for designing high‐performance lithium–ox...
Anchored Zn(002) Orientation with Rapid Interfacial Response Guiding High‐Utilization Alloy Anode and Ah‐Scale Aqueous Zinc Metal Batteries
Abstract Reversibility of zinc anode under high utilization and rational ampere‐hour (Ah)‐scale evaluation represents a key metrics for practical aqueous zinc me...
C <sub>sp</sub> , C <sub>sp</sub> <sup>2</sup> , and C <sub>sp</sub> <sup>3</sup> Hydrocarbyl Group Migration from Pd(II) to P(III): Accessing Metallophosphoranes via Nonspectator Ligand Reactivity
Abstract Migration of palladium‐bound hydrocarbyl ligands to tricoordinate phosphorus ligand P(N(o‐N(2‐pyridyl)C 6 H...
Cyclically Dynamic Defect Management Enables High‐efficiency Sn─Pb Perovskite Photovoltaics with Enhanced Photostability and Fatigue Resistance
Abstract Narrow‐bandgap mixed Sn‐Pb perovskite solar cells (PSCs) have showcased great promise to approach the Shockley‐Queisser limit. Despite continuously prov...
Non‐Alternant Helical Bilayer Molecular Carbons Bearing a Diaza[9]Helicene with Enhanced Emission and Circularly Polarized Luminescence
Abstract Helical bilayer molecular carbons have attracted considerable attention due to their distinct physicochemical properties. However, constrained by the li...
Balancing Oxidative Stability and Ion Transport in Quasi‐Solid Polymer Electrolytes via Chlorine‐Driven Halogenation Engineering
Abstract Polyether‐based solid electrolytes offer significant promise for lithium metal batteries (LMBs), yet their practical application is limited by poor room...
Triplet‐Enhanced Photoiniferter Polymerization: Ultrafast, Oxygen‐Tolerant, and Biocompatible Synthesis of Well‐Defined Polymers Under Visible Light
Abstract Photoiniferter polymerization offers an attractive, additive‐free strategy for precision polymer synthesis but is often constrained by a trade‐off betwe...
Organosulfur‐Rich Porous Carbon Cathode Enables Soluble‐Polysulfide‐Free and High‐Rate Potassium‐Sulfur Batteries
Abstract Potassium–sulfur (K–S) batteries are emerging as one of the most promising candidates for next‐generation energy storage, owing to their high energy den...
Coupled Engineering of Short‐/Long‐Range Disorder in Oxyhalides Unlocks Benchmark Sodium Superionic Conductor
Abstract Oxyhalide‐based sodium solid electrolytes (SSEs) distinguished by exceptionally high‐voltage electrochemical stability and mechanical compliance, have c...
Tailored Core‐Shell Nanocarrier for Therapeutic Drug Delivery via Visible Light Activation
Abstract We present a novel drug delivery nanocarrier consisting of 300 nm‐sized POT/Fe 3 O 4...