Angewandte Chemie International Edition
Articles in this Issue
Topological Structure Design of Ether Solvents for Lithium Storage Chemistry in Graphite Anode
Abstract Ether‐based electrolytes hold great promise for next‐generation lithium‐ion batteries (LIBs) owing to their low melting points and viscosities. However,...
Gradient Adsorption Energy Strategy Unlocks Ultra‐Long Stability and Efficient Electrocatalytic Ammonia Synthesis from Nitrate Over CoP/Cu <sub>3</sub> P
Abstract Electrocatalytic nitrate (NO 3 − ) reduction to ammonia (NRA) is an important approach for a...
LiPb <sub>3</sub> GeS <sub>4</sub> Cl <sub>3</sub> : Quasi‐T <sub>2</sub> ‐Supertetrahedral 3D Framework Enabling Superior Optical Performance
Abstract The anisotropic structure building unit involving diverse chemical bond (ABUCB) has been proven effective in exploring high‐performance nonlinear optica...
Speciation‐Dependent Solvent Extraction of Polyoxopalladates Toward Separation of Critical Materials
Abstract Innovating robust separation methods for critical elements extraction and reuse is important to sustain the global consumption of microelectronics, ener...
Conjugated Inorganic–Organic Hybrid Polymers with p‐Block Elements
Abstract Conjugated polymers with small band gaps and the ensuing semiconductivity are increasingly used as active layers in organic electronics. In order to achieve purpose‐built po...
Chemoenzymatically Synthesized <i>O</i> ‐Acetylated GD3 Gangliosides to Examine Viral Receptor Specificities in a Cellular Context
Abstract Gangliosides are a class of sialic acid‐containing glycosphingolipids involved in a wide range of biological processes. The terminal sialic acid of gang...
Switchable Phenanthroline‐Cu Catalysts for Enantioselective Alkynylation and Amination of Cyclic Diaryliodonium Salts
Abstract Regio‐ and enantioselective ring‐opening alkynylation and amination of cyclic diaryliodoniums have been achieved through the development of conformationally switchable axial...
Enhanced Selectivity of Chalcogen Bonding over Halogen Bonding Catalyzed <i>C</i> ‐glycosylation Through Differentiated Intermediate Activation
Abstract σ‐hole‐based noncovalent interactions are gaining intense attention as robust tools in stereoselective carbohydrate synthesis. However, the mechanistic...
Noble Metal‐Free Photosensitive Terpyridine Coordination Assemblies for Efficient Single‐Molecule H <sub>2</sub> O <sub>2</sub> Photocatalysis
Abstract Conventional molecular photocatalysts characterized by long‐lived excited states, such as Ru and Ir complexes are widely recognized and used in photocat...
From Data to Physics: An Agentic Large Language Model Solves a Competitive Adsorption Puzzle
Abstract Scientific modeling often requires navigating a trade‐off between physical interpretability and empirical accuracy—a task that can take weeks of iteration, especially in sys...
Construction of Biaryl Skeletons Initiated with Benzyne Insertion into C═S Double Bond of Pyridine‐2(1 <i>H</i> )‐thiones
Abstract Benzyne insertion reactions have become a versatile strategy for introducing diverse functional groups onto the benzene ring under transition‐metal‐free...
Sorp‐Vection‐Based Membrane Silicone Oil Purification
Abstract “Sorp‐vection” is a membrane separation technique that synergistically combines sorption with convective flow mechanisms. Beyond its conceptual discussi...
Ultrabroadband 1D and 2D NMR Spectroscopy
Abstract The chemical shift range of many NMR‐active isotopes cannot be excited in a single experiment by classical hard pulse high‐resolution spectroscopy or ev...
Selective, Oxygen‐Tunable, and Metal‐Free Functionalization of Polyethylene Through Dual‐Mode Nitrosation and Carbonylation
Abstract Polyethylene (PE), the world's most produced synthetic polymer, is highly durable but resistant to chemical modification due to its inert carboncarbon b...
Live‐Cell RNA Imaging via Clickable Tri <i>PPP</i> ro Nucleotide Reporters
Abstract Understanding RNA synthesis and dynamics in cells requires efficient labeling strategies that are not only compatible with cellular environments but can...
BODIPY‐Anthracene‐Binaphthyl Compounds Display Aging‐Driven Narrow‐Band Circularly Polarized Luminescence Enhancement with Light‐Activated AIE‐to‐ACQ Transformation
Abstract The development of circularly polarized luminescence (CPL) materials has garnered considerable interest owing to their promising applications in areas s...
Electron‐Enriched Pt‐In Synergistic Sites for Highly Selective and Direct Photo‐Reforming of PET Plastic Wastes into Acetic Acid
Abstract Photocatalytic selective upcycling of polyethylene terephthalate (PET) waste into valuable C 2 products is an id...
Rechargeable Aprotic Zinc–Oxygen Batteries with Reversible ZnO Formation on Cathodes
Abstract Mastering the redox reactions of oxygen—a naturally abundant and high‐energy material—holds transformative potential to address the limitations in energ...
Electrooxidative Divergent Halocyclizations of Ambident Amides
Abstract Herein, we report a divergent electrochemical halocyclization of ambident amides that enables selective formation of either C–O or C–N bonds. Unique chemoselectivity is gove...
Synergistic Enhancement of Photoredox Catalysis Beyond the Singlet Bottleneck Through Triplet Charge Recombination and Magnetic Field Effects
Abstract Organic photosensitizers with redox‐active excited states have revitalized photoredox catalysis, but their efficiency is often hindered by spontaneous back electron transfer...
Directed Evolution of a Nonheme Iron Enzyme to Access Chiral α‐Amino Acid Derivatives by 1,3‐Migratory Nitrene C(sp <sup>3</sup> )─H Insertion
Abstract Nonheme iron enzymes are among nature's most versatile catalysts for molecular functionalization. Engineering nonheme enzymes for abiological reactions...
Covalently Anchored Cationic Groups Tailor Electric Double Layer for Supporting‐Electrolyte‐Free CO <sub>2</sub> Reduction in Acidic Media
Abstract Electrochemical CO 2 reduction reaction (CO 2 RR) in acidic media withou...
Polarized N <sup>+</sup> ‐Mediated Charge‐Transfer State Drives Two‐Electron Water Oxidation
Abstract Achieving selective two‐electron water oxidation (2e − WOR) for sustainable hydrogen peroxide (H...
Metalloid Coordination Reinforcing Electronic Synergy in Dual‐Atom Sites for Large‐Scale CO <sub>2</sub> Electrolysis
Abstract Reinforcing electronic synergy in dual‐atom catalysts (DACs) is critical yet challenging for boosting electrocatalytic CO 2...
Bifunctional Cationic Covalent‐Organic‐Framework for All‐Solid‐State Proton Batteries with High‐Rate and Ultra‐Stable Cyclability
Abstract Despite promising prospects afforded by high power density and abundant proton sources, proton batteries (PBs) face practical limitations. Liquid electr...