Angewandte Chemie International Edition
Articles in this Issue
<i>Cine</i> ‐Reductive Carboboration of Alkenyl Electrophiles via Iron Catalysis
ABSTRACT In traditional transition‐metal‐catalyzed cross‐coupling reactions, alkenyl electrophiles typically undergo transformation at the ip...
Between Order and Confusion: Clearing up Structural Misconceptions in Carbon Materials Nomenclature
Abstract Carbon materials are of increasing importance for various applications especially in the field of energy storage and conversion as well as electrocatalysis, and thus, they a...
Mild Generation of Highly Nucleophilic <i>N</i> ‐Heterocyclic Carbene Boryl Anion From Neutral sp <sup>2</sup> –sp <sup>3</sup> Diboron Reagents and Its Applications in Nucleophilic Borylation
ABSTRACT Due to its high activity, the synthesis or generation of the N ‐heterocyclic carbene (NHC) boryl anion remains c...
Atomic Level Fabrication of Oxychloride Interface for High‐Rate and High‐Voltage Lithium‐Ion Batteries
Abstract In recent years, oxychloride‐based materials have emerged as a promising solid‐state electrolyte (SSE) candidate owing to its ultrahigh ionic conductivi...
Synergistic Rh <sub>1</sub> –Cu <sub>1</sub> Dual‐Atom‐Site Enhancing Performance of Ethane Low‐Temperature Oxidation via Auto‐Selective Oxygen Source From O <sub>2</sub> /H <sub>2</sub> O
ABSTRACT The low‐temperature direct conversion of ethane is more appealing for the utilization of shale gas. Dual‐atom catalysts have attracted considerable atte...
Solar Flow Synthesis of Polymer Nanoparticles: Scaling Local Experiments to Global Potential
ABSTRACT We present the scalable, additive‐free synthesis of polymer nanoparticles in continuous flow, using solely solar radiation. Using a custom‐made flow rea...
Combined In‐Solution and On‐Surface Synthesis of a Fully Fused Cross‐Shaped Phthalocyanine Pentamer
Abstract Phthalocyanines (Pcs) are a class of technologically relevant tetrapyrrolic macrocycles that offer rich photophysical properties as well as excellent tunability by means of...
Unsaturated Phosphorus Electrophiles to Probe Protein Tyrosine Phosphatases
ABSTRACT Protein tyrosine phosphatases (PTPs) represent an important pharmacological target and subject of study. Although a number of broad‐spectrum electrophilic, phosphotyrosine‐m...
Dynamic Binder Exchange Improves Protein Labeling Efficiency in DNA‐PAINT up to 15‐Fold
Abstract Dynamic Binder Exchange (DyBE) enhances DNA‐PAINT (Point Accumulation for Imaging in Nanoscale Topography) super‐resolution microscopy by exploiting transient, reversible bi...
Tuning Circular Dichroism and Circularly Polarised Luminescence in Single Crystals of a Perylene Diimide Macrocycle
Abstract Chiral materials that manipulate circularly polarised light have burgeoning applications across optoelectronics, sensing and information encoding, yet t...
Bioinspired Total Synthesis of Curtachalasin B and Biosynthetically Related Cytochalasans
Abstract We report the first total syntheses of curtachalasin B and a series of biosynthetically related cytochalasans, including ketocytochalasin, xylariasins, brunnesins, zygospori...
A Monkey‐Saddle‐Shaped Nanographene Embedding a Dicyclohepta[ <i>cd</i> , <i>fg</i> ]‐ <i>as</i> ‐Indacene Core and Two Additional Heptagons, and Its Paddle‐Wheel Co‐Assembly With Fullerenes
ABSTRACT We present a novel nanographene 1 that embeds a dicyclohepta[ cd ,...
Anodic H <sub>2</sub> O <sub>2</sub> Production via CO <sub>3</sub> <sup>2−</sup> /HCO <sub>3</sub> <sup>−</sup> ‐Mediated Spillover Effect in Three‐Phase Electrochemical System
ABSTRACT Two‐electron water oxidation reaction (2e − WOR) mediated by (bi)carbonate (CO 3...
Electrocatalytic C─C Coupling of Dimethyl Oxalate to C <sub>4</sub> Dicarboxylate on Cu
ABSTRACT Electrocatalytic conversion of CO to value‐added multi‐carbon chemicals enables carbon resource recycling and emission reduction. Building on the indust...
Proton Exchange Membranes from Microemulsion‐Synthesized COF Nanosheets for Water Electrolysis
Abstract Proton exchange membranes (PEMs) simultaneously with high proton conductivity, strong mechanical strength and low swelling are urgently required for PEM...
Redox‐Activated Probes Enable High‐Contrast Live Imaging of Native Postsynaptic Scaffolds
ABSTRACT Direct visualization of postsynaptic scaffolds in living neurons is essential for dissecting synaptic dynamics and plasticity. Existing methods for live synapse visualizatio...
Development of PolyHis‐Targeting PROTAC Degraders
ABSTRACT Targeted protein degradation (TPD) via proteolysis targeting chimeras (PROTACs) enables selective removal of proteins of interest (POIs) by hijacking th...
Heavy is the Crown: Crown Ether Modulation of Cobalt Porphyrin CO <sub>2</sub> Electroreduction in Zero‐Gap Electrolyzers
ABSTRACT Since decades, metalloporphyrins have been studied to catalyze the electrochemical CO 2 reduction (eCO...
Observations of Isolated Mobile Au–Br and Au–S Surface Complexes on Au(100) Electrodes
ABSTRACT Wet‐chemical processing of metals, for example, galvanic deposition, etching, and nanoparticle synthesis, usually requires complexing agents. In particular, for noble metal...
Highways Construction in Amorphous Carbon Anode Enables 10C Fast‐Charging Sodium‐Ion Batteries
ABSTRACT Conventional hard carbons offering high sodium‐ion (Na + ) storage capacity through closed pores formed by disor...
Electron Delocalization in Ni–Co Active Pairs for Efficient and Robust Urea Electrooxidation
ABSTRACT Ni(OH) 2 is a promising urea oxidation reaction (UOR) catalyst, yet its performance is fundamentally limited by...
Sharpened Dirac Cone and Elevated Carrier Mobility in Bi <sub>4</sub> Te <sub>3</sub> Engineered by a High [Bi <sub>2</sub> ] Bilayer Content for Thermoelectrics
ABSTRACT The [Bi 2 ] m [Bi...
Anion Pillars Enable High Energy Density Sodium Dual‐Ion Battery With Ultra‐Long Cycle Life
ABSTRACT Sodium dual‐ion batteries (SDIBs) are emerging as promising energy storage systems due to their low cost, environmental friendliness, and high operating...
Manipulating the Dispersed Domain of Pinning Dopants in Layered Oxide Cathodes for Sodium‐Ion Batteries
ABSTRACT Layered oxide cathodes are primary candidates for high‐performance sodium‐ion batteries, which often suffer from structural degradation during deep Na...
Ultralow‐Potential Photoelectrochemical Synthesis of Hydroxylamine and Oximes
Abstract The efficient and environmentally friendly synthesis of hydroxylamine (NH 2 OH) remains a challenge in sustainab...