Angewandte Chemie International Edition
Articles in this Issue
Mechanically Triggered Chemical Recyclable Polyethylene‐Like Materials
ABSTRACT Polyethylene (PE) materials are indispensable to modern infrastructure due to their exceptional thermal, mechanical, and chemical resilience. However, the same properties th...
Regulating Both In‐Plane and Out‐Of‐Plane Supramolecular Interactions in COFs for Simultaneously Enhanced Crystallinity and Stability
ABSTRACT The demand for high‐performance applications of covalent organic frameworks (COFs) under harsh conditions drives the need for reaching both outstanding crystallinity and hig...
Sustainable Ammonia Electrosynthesis Coupled With Glycerol Valorization via an Adaptive Tri‐Component Catalyst
ABSTRACT Electrochemical nitrate reduction represents a promising route for sustainable ammonia (NH 3 ) production, yet i...
Piezoelectric Polarization Optimized Photocharge Separation and Surface Proton Cycling for Efficient Pure Water Splitting
ABSTRACT The simultaneous production of hydrogen (H 2 ) and hydrogen peroxide (H 2...
Substituent‐Induced Secondary Interactions Reprogram Ion Permselectivity in Cationic Covalent Organic Framework Membranes
ABSTRACT Precise modulation of ion permselectivity in synthetic membranes is crucial for advancing separation and energy conversion technologies. Here, we demons...
Confining a Single Water Molecule Through Molecular Crystal Engineering for Water Oxidation
ABSTRACT Hydrogen‐bonded water clusters (H 2 O) n obscure the intrinsic reactivit...
Boron‐Nitrogen Multi‐Resonance Framework With Heptagon‐Fused Carbazole and Spiro‐Locking Units Enables Extremely Long‐Lifetime Narrowband Green OLEDs
ABSTRACT Achieving high efficiency, narrow emission bandwidth, and long operational stability simultaneously remains a major challenge for organic light‐emitting...
Reaction Discovery Involving Digital co‐Expert with a Practical Application in Atom‐Economic Cycloaddition
Abstract The discovery of new chemical transformations is central to advancing modern chemistry, yet conventional approaches often require months or years of extensive experimental s...
Dynamic Color‐Tunable Dual Room Temperature Phosphorescence via Activation of Both Host and Guest Triplet States
ABSTRACT The design of dual organic room‐temperature phosphorescence (RTP) from both the host and guest remains a significant challenge, as most organic doping systems generally enab...
Selective Carbocation Functionalization by Catalytic Transchalcogenation Reactions
ABSTRACT Introducing functionalities via acid‐mediated carbocation chemistry is conceptually straightforward, but typically lacks in selectivity and broad‐scale...
A Metallosupramolecular Receptor for Squaraine Dyes Enabling Ultrafast Dark Resonance Energy Transfer
ABSTRACT A metal‐organic cage was obtained by combining acridone‐based dipyridyl ligands with Pd 2+ ions. The cage acts a...
Living Polymerization Strategy for Conjugated Multiblock Copolymers: A Systematic Study of Structure–Property Relationships in Stretchability and Charge Transport
ABSTRACT Achieving high mechanical stretchability while maintaining charge carrier mobility in semiconducting polymers remains a central challenge due to their intrinsic trade‐off. C...
Area‐Selective Atomic Layer Deposition of AlO <sub>x</sub> at the Buried Interface for High‐Performance Perovskite Solar Cells
ABSTRACT Self‐assembled monolayers (SAM) have demonstrated significant potential for enhancing the performance of perovskite solar cells (PSCs). However, their i...
Conformation‐Resolved Single‐Luminogen Systems for Time‐Dependent Multicolor Afterglow
ABSTRACT Time‐dependent multicolor afterglow enables temporal encoding of naked‐eye distinguishable optical signals that cannot be achieved with static luminescence. However, availab...
Total Synthesis of Limonoids Enabled by Sterically Assisted Boron Chain‐Walking
ABSTRACT Limonoids are architecturally complex tetranortriterpenoids with diverse biological activities, yet their synthetic inaccessibility has limited detailed investigations. Here...
Proton Tautomerism for Anhydrous Superprotonic Conduction in 1,2,3‐Triazolium Dihydrogen Phosphate Crystal
ABSTRACT Proton dynamics within molecular organic solids are crucial for energy‐related technologies. Proton conductors for use as solid electrolytes in hydrogen...
Programmable Antigen‐Specific Immunity via Self‐Adjuvanting Nanovaccines Co‐Delivering Immune Modulators
Abstract Cancer peptide vaccines harness the host immune system to generate tumor‐specific immune responses, offering potential for treating metastatic cancers a...
Distinct Tunable In‐Plane Birefringence via Domain Manipulation in a 2D Metal Halide Ferroelectric
ABSTRACT Single crystals with tunable birefringence hold an exciting position in optical and photonic devices due to their exceptional ability of light manipulat...
Adhesive Photoinitiator Constructs Polymer Jackets on Enzymes: Direct, Release‐Free Cytosolic Delivery
ABSTRACT Enzyme therapeutics require both catalytic activity and efficient cytosolic delivery—yet protective encapsulation typically compromises enzymatic functi...
Pyridine Into Pyrrole Transformation Induced Within the Confinement of the Macrocycle
ABSTRACT The pyridine contracted to form the pyrrole ring. This transformation belongs to a unique class of reactions with the fundamental characteristic of the cleavage of the aroma...
Correction to “pH‐Dependent Packing Mode Variations and Chirality Inversion in Short Peptide Self‐Assembly”
Stereospecific Assembly of Triply Chiral Pseudopeptidic Cages Through Dynamic Dual Chirality Transfer
ABSTRACT A stereospecific transmission of chiral information within tripodal pseudopeptidic cages has been observed from dynamic constitutional co‐operation of reversible orthogonal...
Enabling Rotated Stacking Displacement in Two‐Dimensional Covalent Organic Frameworks via Interlayer Electrostatic Repulsion
ABSTRACT Tuning the interlayer stacking in 2D covalent organic frameworks (2D COFs) allows unique structural and optoelectronic properties. However, the diversity of 2D COF stacking...
Persistent Mono‐Oxo Bonding with Protactinium(V) Revealed in Highly Acidic Chloride Solutions
Abstract Protactinium is one of those long discovered elements with poorly known physico‐chemical properties. In aqueous solution, protactinium(V), highly prone...