Angewandte Chemie International Edition
Articles in this Issue
Ionized Water Facilitates the Sustainable Radical‐Mediated Reduction of CO <sub>2</sub> to Multi‐Carbon Hydrocarbons and Oxygenates
Abstract The abiotic synthesis of organic compounds from CO 2 and water under prebiotic conditions is a fundamental yet u...
A Novel Tandem Reaction System for High‐Concentration Acetic Acid Production from Methane and Oxygen
Abstract Directly converting methane into high‐value products like CH 3 COOH poses significant challenges owing to the ki...
Predator–Prey Behavior of Droplets Propelling Through Self‐Generated Channels in Crystalline Surfactant Layers
Abstract Motile droplets provide an attractive platform for liquid matter‐based applications and protocell analogues displaying life‐like features. The functiona...
Sprayed Microdroplets Architect a Polyoxometalate Framework
Abstract Although many past attempts have utilized micron‐sized droplets for breaking and forming organic bonds, their potential in promoting inorganic bond form...
Entropy‐Driven Competitive Adsorption Sites Tailoring Unlocks Efficient Hybrid Conversion Zn–Air Batteries
Abstract Hybrid conversion Zn–air batteries (HC‐ZABs) epitomize a typical integrated energy storage and conversion device that advances green chemistry and reduc...
Regiospecific Halogenation Modulates Molecular Dipoles in Self‐Assembled Monolayers for High‐Performance Organic Solar Cells
Abstract Halogenated carbazole‐derived self‐assembled monolayers (SAMs) are promising hole‐extraction materials in conventional organic solar cells (OSCs). While...
Switchable Closed‐Shell and Open‐Shell Biradical States in Bis‐Palladium Complexes of Tetrathiadodecaphyrin via Coordination Rearrangement
Abstract A figure‐eight tetrathiadodecaphyrin ( 1 ), featuring two porphyrin‐like sub‐pockets separated by central carbaz...
Chen Wang
Solar‐Driven Reversible Hydrogen Storage of Sodium Cyclohexanolate/Phenoxide Pair
Abstract Reversible hydrogen storage is a key challenge for the implementation of hydrogen energy, with dehydrogenation being particularly difficult because of its endothermic nature...
Selective Leaflet‐Anchored DNA Nanoprobes for Simultaneous Monitoring of Juxta‐Plasma Membrane Environments
Abstract The cell membrane functions as a bidirectional interface that coordinates the selective transport of substances and information between the interior and...
Mn(II)‐Based Hybrid Halide Ionogel Scintillator Film for Large‐Area and High‐Resolution X‐ray Imaging
Abstract Functionalized ionogels have attracted significant attention in chemical design of new materials and versatile applications, which are formed by polymer...
Aptamer‐Based Galvanic Potentiometric Sensor for Real‐Time Monitoring of Serotonin Signaling Under Psychosocial Stress
Abstract Psychosocial stress, a pervasive factor in mental health disorders, is tightly linked to serotonin (5‐HT) dysregulation. Real‐time electrochemical monit...
Alcohol Activation by Benzodithiolylium for Deoxygenative Alkylation Driven by Photocatalytic Energy Transfer
Abstract The 1,3‐benzodithiolylium (BDT) cation was identified as an efficient hydroxyl‐activating reagent for the photocatalytic deoxygenative radical functiona...
Hopping Diffusion in Wiggling Nanopore Architecture of MOF Enabling Synergistic Equilibrium‐Kinetic Separation of Fluorinated Propylene and Propane
Abstract The separation of octafluoropropane (C 3 F 8 ) from hexafluoropropylene...
Site‐Selective Carbonylation of Azetidines via Copper‐Catalyzed Difluorocarbene Insertion
Abstract γ‐Lactams are privileged five‐membered pharmaco‐phores in numerous bioactive compounds, but access to these motifs typically relies on cycloaddition/substitution chemistry i...
Gang Li
Unveiling the Catalytic Potential of Facet Heterojunctions in Platinum Alloys for Oxygen Reduction Reaction
Abstract Ensuring high‐quality activity of proton exchange membrane fuel cells (PEMFCs) while mitigating the degradation of Pt‐based alloy catalysts remains chal...
A Donor–Acceptor‐Type Two‐Dimensional Poly(Arylene Vinylene) for Efficient Electron Transport and Sensitive Chemiresistors
Abstract Two‐dimensional (2D) conjugated polymers and their layer‐stacked 2D conjugated covalent organic frameworks, such as 2D poly(arylene vinylene)s (2D PAVs)...
Oligoether Chain Engineering in Covalent Organic Frameworks: Enhancing Transport Pathways and Oxygen Reduction Activity for Efficient Electrocatalytic Hydrogen Peroxide Production
Abstract Oligoethers with various numbers of ethylene oxide (EO) units, known for their flexibility, electronegativity, and hydrophilicity, can be leveraged to c...
Self‐Compartmented Electrolyte Design for Stable Cycling of Lithium Metal Batteries under Extreme Conditions
Abstract Electrolyte is the key component dictating lithium battery performance, especially under extreme conditions such as fast cycling and low temperatures. H...
A Powerful Regulator to Enhance Electrocatalytic Reaction Kinetics and Thermodynamics: The Ordered Hetero‐Nanowire
Abstract Optimizing the thermodynamics of electrode reactions is a valid strategy for achieving superior electrocatalysts for direct methanol fuel cells (DMFCs). However, as the cata...
Nitrogen Insertion via Asymmetric Condensation and Chirality Transfer: A Stereodivergent Entry to Cyanocyclopropanes
Abstract The condensation of prochiral cyclobutanones and diphenylphosphinyl hydroxylamine is achieved under Brønsted acid catalysis. Interestingly, the competing aza‐Baeyer–Villiger...
Antibacterial Siderophores of <i>Pandoraea</i> Pathogens and Their Impact on the Diseased Lung Microbiota
Abstract Antibiotic‐resistant bacteria of the genus Pandoraea , frequently acquired from the environment, are an emerging...
Spherical Nucleic Acids‐Directed Cryosynthesis of Manganese Nanoagents for Tumor Imaging and Therapy
Abstract DNAzyme‐based theranostic nanotechnologies that can respond to specific tumor pathophysiological parameters hold great promise for tumor diagnostics and...
Engineering Bodipy‐Based Metal–Organic Frameworks for Efficient Full‐Spectrum Photocatalysis in Amide Synthesis
Abstract Developing photocatalysts that can efficiently utilize the full solar spectrum is a crucial step toward transforming sustainable energy solutions. Due t...