Angewandte Chemie International Edition
Articles in this Issue
Acyclic Quaternary Stereocenters via Catalytic Asymmetric Cross‐Couplings with Unactivated Alkyl <i>N</i> ‐Hydroxyphthalimide Esters
Abstract While significant advancements have been made in creating quaternary stereocenters (all‐carbon substituents) within cyclic frameworks, generating acycli...
Crystalline Silagermenides as Powerful Synthons: Unraveling π‐Bonding and Lone Pair Effects in the Multiple Bonds of Heavier Main Group Analogs of the Vinyl Anion
Abstract Compared to common vinyl anions, their heavier heteronuclear analog, silagermenides [R 2 Si═GeR]ˉ, remain exceed...
Mechanistic Insights into the CO <sub>2</sub> ‐Assisted NO Electrochemical Deoxygenation and Hydrogenation
Abstract Electrocatalytic NO reduction to NH 3 holds significant potential for pollutant treatment and resource recovery....
Dimensionality Reduction of Metal–Organic Frameworks to Monolayers for Enhanced Electrocatalysis
Abstract Metal–organic frameworks (MOFs) are potential candidates for electrocatalysis due to their well‐defined, tunable structures, and ability to incorporate...
Synthesis of Chiral δ‐Aminoboronic Esters by Enantioselective Hydrogenation of 1,2‐Azaborines
Abstract We describe herein an iridium‐catalyzed highly diastereo‐ and enantioselective hydrogenation of 1,2‐azaborines to access δ‐aminoboronic esters of potent...
Enhanced Luminance of Pentaazaphenalene‐Based Delayed Fluorescence Emitters by Breaking Forbidden Transition
Abstract 1,3,4,6,9 b ‐pentaazaphenalene (5AP) derivatives are of growing interest because of their potential for exhibiti...
High‐Throughput DFT‐Assisted Design of Electrode for Efficient High‐Temperature Electrochemical Dehydrogenation
Abstract Protonic ceramic electrolysis cell (PCEC) is a promising technique to enable efficient dehydrogenation reactions for producing valuable chemicals, but i...
Modification of [2.2]Paracyclophanes via Cobalt/Salox‐Catalyzed Enantioselective Electrooxidative or Photoredox C─H Acyloxylation and Alkoxylation
Abstract Chiral [2.2]paracyclophanes (PCPs) have widespread application in asymmetric catalysis and materials science. However, enantioselective C─H activation o...
<i>N</i> ‐(Acyldithio)Saccharin: Design, Synthesis and Applications in Catalytic Enantioselective Disulfuration/Amination of Alkenes
Abstract We have designed and successfully synthesized N ‐(acyldithio)saccharin, which is a highly electrophilic, bench‐s...
Decatungstate‐Driven Photocatalytic Pathways for Sustainable and Cleaner Recovery of Precious Metals
Abstract The recovery of precious metals from waste streams is crucial for sustainable resource utilization but remains hindered by traditional methods involving...
Development of an Automated Workflow for Screening the Assembly and Host–Guest Behavior of Metal‐Organic Cages Towards Accelerated Discovery
Abstract Metal‐organic cages (MOCs) are a class of self‐assembled materials with promising applications in chemical purifications, sensing, and catalysis. Their...
Building a Confluence Charge Transfer Pathway in COFs for Highly Efficient Photosynthesis of Hydrogen Peroxide from Water and Air
Abstract Sunlight‐driven photosynthesis by covalent organic frameworks (COFs) from water and air without using sacrificial reagents is a promising H...
A Capping‐assisted Strategy for Synthesis of Glass‐like Carboxylate‐based Coordination Polymers
Abstract The direct preparation of glass‐like carboxylate‐based coordination polymers (CPs) possessing continuous internal structure and transparency is challeng...
Unprecedented “off‐pathway” [2+2] Cycloaddition‐Retroelectrocyclization Reaction Between an Unsymmetric Alkyne and Tetracyanoquinodimethane
Abstract In recent years, the [2+2] cycloaddition‐retroelectrocyclization (CA‐RE) reaction between electron‐rich alkynes and electron‐deficient alkenes has emerged as one of the most...
Optimizing Charge Separated Synergistic Binding Sites in Self‐Healing Crystalline Porous Organic Salts for Benchmark Trace Alkyne/Alkene Separation
Abstract The separation of trace alkyne (C 2 H 2 /C 3...
Cathodic Hydroxide Ions Induce Tetrose Formation during Glycolaldehyde Electroreduction to Alcohols: A Potential CO <sub>2</sub> ‐to‐Carbohydrate Pathway
Abstract The electrochemical synthesis of organic compounds from CO 2 can potentially alleviate climate change by hamperi...
DNA Nanotubule‐Based Nanodevices with ATP‐Responsive Gating for Direct Cytosolic Delivery of Nucleic Acids and Proteins
Abstract Delivering biomacromolecules to the cytosol remains a formidable challenge, as these molecules are predominantly sequestered within endosomes after endocytosis. The limited...
Beyond Structure: Methylation Fine‐Tunes Stability and Folding Kinetics of bcl2Mid G‐Quadruplex
Abstract Cytosine methylation, a key epigenetic modification in the regulation of gene expression, raises intriguing questions about its role in the formation an...
Structurally Engineering Multi‐Shell Hollow Zeolite Single Crystals via Defect‐Directed Oriented‐Kinetics Transformation and Their Heterostructures for Hydrodeoxygenation Reaction
Abstract Single‐crystalline multi‐shell hollow porous materials with high compartment capacity, large active surface area, and superior structural stability are...
Tetranuclear Titanium Nitride Cluster: Dinitrogen Cleavage Under Mild Conditions and Its Reactivity
Abstract Heating the readily available trinuclear Ti dinitrogen complex [{TiCp*( µ ‐Cl)} 3...
Towards High‐Performance Aqueous Zn‐Organic Batteries via Using I <sup>−</sup> ‐Based Active Electrolyte
Abstract Organic cathodes possess inherent structural diversity and fast redox kinetics, showing great application prospects in aqueous Zn batteries. Nevertheles...
Theory‐Guided Design of Surface‐Enhanced Ni–Mn Diatomic Site Catalysts for Efficient Seawater Electrolysis via the Degradation of High Ionization Potential Organic Pollutants
Abstract In response to energy shortages and hard‐to‐degrade chemical pollution, especially high ionization potential (IP) organic pollutants, this study develop...
Octalenobisterphenylene and Its Diradical Dianionic Cyclodimer: Synthesis, Structural Analysis, and Properties
Abstract Octalenobisterphenylene 1 (also known as terphenylene dimer) was synthesized from 3,3′,5,5′‐tetraaryl‐substitute...
Boron Doping‐Induced Ultrahigh Ce <sup>3+</sup> Ratio in Amorphous CeO <sub>2</sub> /GO Catalyst for Low‐Concentration CO <sub>2</sub> Photoreduction
Abstract Direct utilization of diluted CO 2 enables sustainable CO 2 conversion i...
ATP‐Assisted Electron and Proton Transfer Boosting Redox Metabolism‐Induced Ferroptosis and Apoptosis for Cancer Therapy
Abstract Compared to the intractability of traditional apoptosis, the vulnerability exposed by cancer cell metabolic reprogramming provides an advantage for ferroptosis treatment. He...