Angewandte Chemie International Edition
Articles in this Issue
Mesoporous Enhanced Heterostructured Halide Solid Electrolytes with High Air Stability and High Abundance for Sustainable Sodium Metal Batteries
Abstract Chlorides and fluorides solid‐state electrolytes (SEs) exhibit contrasting extremes in ionic conductivity and moisture sensitivity. In light of these co...
Constructions of Biaryl‐Bridged Macrocycles Through Phosphine‐Ligand‐Controlled Switch of Selectivity Between Intra‐ and Intermolecular Cyclizations
Abstract The rigid biaryl‐bridged macrocycles serve as core scaffolds in numerous bioactive molecules. However, constructing biaryl‐bridged macrocycles smaller t...
Optimizing Molecular Packing and Interfacial Contact via Halogenated N‐Glycidyl Carbazole Small Molecules for Low Energy Loss and Highly Efficient Inverted Perovskite Solar Cells
Abstract Nonideal interfacial contact and non‐radiative voltage loss in self‐assembled monolayers (SAMs)‐based inverted perovskite solar cells (PSCs) limit their...
Solvent‐Driven Interconversion of Pyridine Dicarbanion‐Bonded Ag <sub>13</sub> Nanocluster Isomers
Abstract Solvent screening is pivotal for optimizing metal‐catalyzed reactions, yet its impact on the in situ formation and reactivity of polynuclear organometal...
Synergistic Mechanism for Unconventional Anodic Reaction of Aldehyde Oxidation for Hydrogen Production
Abstract Anodic reactions involving non‐faradaic processes have significantly expanded the potential application of anodic oxidation half‐reactions. Metallic Cu...
Synergistic C─N Coupling for Efficient Cyclohexanone Oxime Synthesis from Ambient Air by Supported Molecular Catalysts
Abstract Electrocatalytic synthesis of cyclohexanone oxime from rich nitrogen resources is a promising alternative to traditional industrial processes. However,...
Circular RNA‐Based Molecular Computation Enhances Plasma Biomarker Detection in Biliary Tract Cancer
Abstract Molecular diagnosis of biliary tract cancer (BTC) remains a significant clinical challenge due to the lack of sensitive and specific diagnostic tools. Although large panels...
Engineered Biocatalyst for Enantioselective Hydrazone Reduction
Abstract Enantioselective reduction of hydrazones provides a convergent and versatile route to synthesize hydrazine‐containing motifs that are commonly found in...
Guideline for Analysis and Prevention of Contamination Catalysis
Abstract Over the last decades, numerous efforts have been made to replace metal catalysts with cheaper and earth‐abundant alternatives or to completely exclude metals from cross‐cou...
A Fluorine‐Free Organic/Inorganic Interphase for Highly Reversible Aqueous Zinc Batteries
Abstract Construction of robust solid electrolyte interphases (SEIs) has proved effective in mitigating dendrite growth and side reactions of zinc (Zn) anodes in...
Histidine‐Based “Transfer Stations” at Carbon‐Immobilized Metal Particles Enable Rapid Hydrogen Transfer for Efficient Formic Acid Dehydrogenation
Abstract The interaction of surface metal species with the solution plays a key role in engineering heterogeneous catalytic processes. Herein, we present the fac...
Precise Engineering of Asymmetric Tri‐Active Sites by Symbiotic Strategy for Photocontrolled Directional Reforming of Biomass
Abstract Sunlight‐driven production of high‐value chemicals from renewable resources represents a pivotal driver toward achieving sustainable energy supply. Howe...
Sequence Control in Sulphur‐Containing Ring‐Opening Co‐ and Terpolymerisations
Abstract Sulphur‐containing polymers uniquely expand the catalogue of accessible material properties compared to current commodity materials, yet their synthesis remains underdevelop...
Pore Engineering in Isoreticular Titanium‐Isophthalate Coordination Polymers
Abstract Pore engineering through chemical environment modification is vital for developing industrial porous materials. Understanding the effects of substitutions in isoreticular po...
Leaching‐Induced Ti Trapping Stabilizes Amorphous IrO <i> <sub>x</sub> </i> for Proton Exchange Membrane Water Electrolysis
Abstract Transition metal nitrides are promising conductive support materials in oxygen evolution reaction (OER), whereas it is unclear if their electrochemical...
An Autonomously Liquefied Hydrogel Adhesive for Programmable Bioelectronic Interface
Abstract Hydrogel adhesives have many important applications in the fields of drug delivery, regenerative medicine, and bioelectronics. The detachment of hydrogel adhesives under the...
Exploring the Interplay of Lattice Dynamics and Charge Transport in Organic Semiconductors: Progress Toward Rational Phonon Engineering
Abstract Organic semiconductors (OSCs) have garnered significant attention due to their potential use in flexible, lightweight, and cost‐effective electronic devices. Despite their p...
Solid–Liquid Interfacial Hydrogen Bond‐Mediated Mass Transfer Toward Industrial Water Electrolysis
Abstract The rapid migration of reactive ions across the electrolyte–catalytic sites interface is crucial in various catalytic processes. Herein, we introduce hy...
Stable Mg <sup>2+</sup> Dication Weakly Stabilized/Coordinated in Solution: Synthesis, Structure, Reactivity, and Use in Catalysis
Abstract The first soluble and stable Mg 2+ dication stabilized only by weakly coordinating and chemically robust carbora...
Harnessing the Hofmeister Effect for Dynamic Self‐Assembly of Supramolecular Hydrogels
Abstract Dynamic regulation of intermolecular interactions is essential for the creation of dynamic supramolecular materials with lifelike self‐regulating functi...
Self‐Photosensitizing Cobalt Complexes for Photocatalytic CO <sub>2</sub> Reduction Coupled with CH <sub>3</sub> OH Oxidation
Abstract The use of metal complexes as homogeneous molecular catalysts has attracted considerable attention regarding photocatalytic CO 2...
β‐Quaternary α‐Amino Acids via Iridium‐Catalyzed Branched and Enantioselective Hydroalkylation of 1,1‐Disubstituted Styrenes
Abstract A cationic Ir(I)‐complex modified with the chiral diphosphine DM‐SEGPHOS mediates the hydroalkylation of diverse α‐methyl styrenes with N‐aryl glycine derivatives. The proce...
Catalytic Enantioselective α‐Ethynylation of Oxindoles: Total Synthesis of (‐)‐Corynoxine, (‐)‐Isorhynchophylline, (‐)‐Aspidospermidine, and (‐)‐Limaspermidine
Abstract The all‐carbon quaternary stereogenic center of oxindoles is a crucial structural element of a broad spectrum of indole alkaloids, imparting these molecules with rigid three...
Inside Back Cover: Photocatalytic Nitrogen Reduction for Ammonia Synthesis Accelerated by Overcoming Photo‐Dember Effect (Angew. Chem. Int. Ed. 26/2025)
Enantiomerically Enriched Aziridine‐2‐carboxylates via Copper‐Catalyzed Reductive Kinetic Resolution of 2 <i>H</i> ‐Azirines
Abstract We present the first reductive kinetic resolution of racemic 2 H ‐azirines to prepare optically enriched...