Angewandte Chemie International Edition
Articles in this Issue
Titanium‐Mediated Rearrangement of Bis(alkynyl)boranes: B─C Activation versus C─H Activation
Abstract Reactions between Rosenthal's titanocene (Cp 2 Ti) and decamethyltitanocene (Cp* 2...
Machine‐Learning‐Driven Exploration of Surface Reconstructions of Reduced Rutile TiO <sub>2</sub>
Abstract Titanium dioxide (TiO 2 ) is widely used as a catalyst support due to its stability, tunable electronic properti...
Cooperative Dinuclear Gold Catalysis Unlocking 1,2‐Reductive Elimination Elementary Reaction in Oxidative C─C Coupling
Abstract Cooperative catalysis enabled by dinuclear metal complexes can integrate the catalytic properties of each metal center, thus opening new avenues to achi...
Catching Fullerenes: Synthesis of Molecular Nanogloves
Abstract Herein, we report the synthesis of a new series of rigid, all meta ‐phenylene, conjugated deep‐cavity molecules,...
Copper‐Catalyzed Asymmetric Cyanation of Propargylic Radicals Derived From Silyl‐Substituted Allenes and Alkynes
Abstract Here, we report an efficient method to synthesize enantiomerically enriched propargyl nitriles via copper‐catalyzed asymmetric cyanation of propargylic...
Deciphering the Crystallographic Effect in Radially Architectured Polycrystalline Layered Cathode Materials for Lithium‐Ion Batteries
Abstract Layered oxide cathode materials with primary–secondary architecture face challenges of inhomogeneous Li + diffus...
Mixing and Matching of Hybrid Megasynthases is a Hub for the Evolution of Metabolic Diversity in Cyanobacteria
Abstract Modular megasynthases, such as polyketide synthases (PKSs) and nonribosomal peptide synthetases (NRPSs), are molecular assembly lines that biosynthesize...
Mark C. Lipke
Light‐Induced Disruption of 1D Wire‐Like Arrays of Monoatomic Ag(I) Ions: Single‐Crystal Reaction with Crystal Softening
Abstract The exploitation of noncovalent bonding in the solid state is attractive to generate one‐dimensional (1D) wire‐like assemblies of metals and uncover dynamic and physical pro...
Ordered Co‐Assembly of Soft‐in‐Hard Hetero‐Structured Pulse Guidance Ion‐Accelerator for Dendrite‐Free Aqueous Zinc‐Ion Battery Anodes
Abstract Constructing a solid electrolyte interface (SEI) layer to suppress dendrite growth is an effective approach in Zn‐based aqueous batteries. Traditional SEI layers are limited...
Mn–N–C with High‐Density Atomically Dispersed Mn Active Sites for the Oxygen Reduction Reaction
Abstract The utilization of transition metal–based catalysts as alternatives presents an attractive solution for enhancing the sluggish oxygen reduction reaction...
Thionated Perylenebisimides as Heavy‐Atom‐Free Triplet Photosensitizers: Intersystem Crossing, Electron Spin Dynamics, and Application in Photodynamic Therapy
Abstract The thionation induced intersystem crossing (ISC) in perylenebisimide (PBI) derivatives was studied. The triplet state lifetimes of the thionated PBIs a...
Meticulous Design of High‐Polarity Interface Material for FACsPbI <sub>3</sub> Perovskite Solar Cells with Efficiency of 26.47%
Abstract Designing new interface materials with the multifunctions of upper film crystallization control, interfacial defects passivation, and interfacial energy...
Unnatural Triggers Converted From Tetrazine‐Attached Sialic Acid for Activation of Optoacoustic Imaging‐Guided Cancer Theranostics
Abstract Constructing chemical groups on cell membranes through metabolic glycoengineering of unnatural sugars is an effective means to solve the issue of insuff...
Desulfurizative Fluorination of <i>N</i> ‐CF <sub>3</sub> Thioformamides for the Efficient Synthesis of <i>N</i> (CF <sub>3</sub> )(CF <sub>2</sub> H) Amines with Enhanced Stability
Abstract With poor metabolic stability being a major cause of failure in drug development, there is a pressing need for strategic molecular modifications to opti...
Mechanistic Insights: Correspondence on “Tuning Co‐Operative Energy Transfer in Copper(I) Complexes Using Two‐Photon Absorbing Diimine‐Based Ligand Sensitizers”
Abstract In a recent communication, Collins and coworkers presented a Cu(I) complex with photocatalytic activity under red light LED conditions, mainly for singlet oxygen‐driven reac...
Integrating Multifunctionalities into a 3D Covalent Organic Framework for Efficient CO <sub>2</sub> Photoreduction
Abstract Fabrication of highly efficient photocatalysts for CO 2 conversion is still challenging. Herein, integrating nit...
Isomerisation and Insertion Chemistry of Imidosilanes Enabled by Reversible Si(IV)/Si(II) Redox Shuttling
Abstract Spontaneous redox shuttling at silicon is very rare, primarily reflecting the thermodynamic challenges associated with reduction processes for lighter...
Enantioselective Abiotic Synthesis of Ribose on Chiral Mesostructured Hydroxyapatite
Abstract The prebiotic synthesis and symmetry breaking of ribose are crucial processes in the origin of life. However, the prebiotic emergence of enantiomericall...
Evaluation of Intermolecular Weak Binding Through the Zero‐Field Splitting of an Endofullerene High‐Spin Probe
Abstract Weak binding between molecules is becoming a renowned aspect of molecular engineering, offering an alternative to the tuning of conventional chemical bo...
Uncovering the Photochemical Conversion of Atmospheric Chlorinated Organics on Mineral Dust: In‐Field Evidence of a New Source of Dioxin
Abstract Hazardous chemicals are typically assessed based on their inherent toxicity, often neglecting the fact that their atmospheric secondary transformation p...
A Programmable Nanoparticle Conversion Pathway to Monodisperse Polyelemental High Entropy Alloy, Intermetallic, and Multiphase Nanoparticles
Abstract Polyelemental nanoparticles (PE NPs), those consisting of four or more elements, exhibit unique properties from synergistic compositional effects. Examples include high entr...
Au <sub>147</sub> (SPh) <sub>30</sub> (PPh <sub>3</sub> ) <sub>12</sub> : A Geometrically Closed, but Electronically Open Triple‐Shell Icosahedral Gold Cluster and its Geometrically Open Counterpart
Abstract The aesthetic platonic solids have been known since ancient times, and the structure of all five platonic solids is also found in chemical compounds. Wh...
Manganese‐Catalyzed Enantioselective Dearomative Epoxidation of Naphthalenes with Aqueous Hydrogen Peroxide
Abstract Arenes are abundantly occurring molecules of significant interest as versatile starting materials in organic reactions. Typically, oxidation of arenes y...