Angewandte Chemie International Edition
Articles in this Issue
Adaptive Defluoroamination of Aryl Fluorides: Harnessing the Catalytic Potential of a Unique Zinc Amide Compound
Abstract The activation and functionalization of C─F bonds, the strongest bonds between carbon and any other element, via C─N bond formation to generate complex...
Day‐Long Organic Persistent Luminescence in Flexible Polymeric Materials
Abstract The progress in organic afterglow materials has drawn significant attention due to their extensive applications in fields such as optoelectronics, anti‐counterfeiting, and b...
Assembly of High‐Nuclearity Copper(I) Alkynyl Nanoclusters with Exposed Polyoxomolybdate Templates
Abstract The directed synthesis of copper(I) nanoclusters with atomically precise active sites for photocatalytic CO 2 re...
Porous Aromatic Frameworks Filler with Anion‐Constrained Centers in Composite Polymer Electrolyte for Lithium‐Ion Batteries
Abstract The widespread use of lithium‐ion batteries (LIBs) based on solid polymer electrolytes (SPEs) is hindered by their low Li +...
Probing the Catalytic Degradation of Unsaturated Polyolefin Materials via Fe‐Based Lewis Acids‐Initiated Carbonyl–Olefin Metathesis
Abstract Degradation and recyclability of polymeric materials, including extensively used polyolefins, are becoming increasingly necessary. Chemically stable saturated polyolefin bac...
Fullerene Network‐Buffered Platinum Nanoparticles Toward Efficient and Stable Electrochemical Ammonia Oxidation Reaction for Hydrogen Production
Abstract Green ammonia is a promising hydrogen carrier due to its well‐established production, storage, and transportation infrastructure. Moreover, hydrogen pro...
Decoding Double Layer Dynamics for CO2 Electroreduction over Cu
Abstract Understanding the nature and role of the electric double layer (EDL) at electrocatalytic interfaces and its dynamic evolution, is critical to optimizing...
Construction of Nonadjacent Stereocenters Through Iridium‐Catalyzed Desymmetric Hydroheteroarylation of Cyclopentenes
Abstract Transition metal–catalyzed direct addition of (hetero)aryl C─H bond to an alkene provides an expedited route to construct benzylic stereocenter from readily available arene...
Scalable and Ultrathin Dual Entangled Network Polymer Electrolytes for Safe Solid‐State Sodium Batteries
Abstract Identifying ultrathin and flexible solid‐state electrolytes with high ionic conductivity and low interfacial resistance is crucial for scale‐up producti...
Intramolecular Thiol‐Promoted Decomposition of Cysteine Ester (ITPDC): A General Platform for Controllable Release of Reactive Sulfur Species
Abstract Endogenously generated reactive sulfur species (RSS) play critical roles in various physiological processes. RSS donors can enhance our understanding of...
Inside Front Cover: Identification of an Activity Selector for the Nitroso‐Forming Activity in Bacterial Type‐III Copper Enzymes (Angew. Chem. Int. Ed. 26/2025)
Asymmetric Electrochemical Alkenylation by Synergistic Chiral Primary Amine and Naphthalene Catalysis
Abstract External tuning of enamine intermediate has significantly expanded reaction space of typical aminocatalysis. Notwithstanding the progress of chemo‐ and...
NO‐Enhanced Sonodynamic Nanovesicles with Co‐Stimulatory Molecule Self‐Presentation for Multidimensional Tumor Immunotherapy
Abstract Synergistically improving T cell responsiveness represents a promising therapeutic strategy for tumors; however, current treatments struggle to fully ac...
Synergistic Regulation of Multi‐Interface Chemistry by Functional Carbon Dots for High‐Performance Composite Solid Electrolytes
Abstract Low ionic conductivity, poor mechanical strength, and unstable interface structure are still the main factors hindering the practical application of pol...
Correction to “High‐Connectivity 3D Covalent Organic Frameworks with pdp Net for Efficient C <sub>2</sub> H <sub>2</sub> /CO <sub>2</sub> Separation”
Outside Back Cover: A Single‐Molecule Liposome Assay for Membrane Permeabilisation (Angew. Chem. Int. Ed. 26/2025)
Iron(III)‐Catalyzed C─H Hydroxylation of Low‐Density Polyethylene Coupled with Short Chain Branching Growth
Abstract Low‐density polyethylene (LDPE) is widely used in packaging applications, but after being discarded its environmental impact is a pressing concern due to a lack of effective...
Adaptive Mo‐Fe‐S Clusters: Consistent Redox Behavior Versus Reversible Structural Transformations
Abstract Iron‐sulfur clusters are critical in a number of important biological processes, where their structural integrity can be maintained or reversibly transf...
A General Strategy for Enhanced Single‐Molecule Imaging Through Intramolecular Energy Transfer
Abstract Single‐molecule imaging demands fluorophores with exceptional photostability and photon budget. This study presents an intramolecular energy transfer (IMET) strategy to enha...
Modulating Electron Transfer via Cerium Photocatalysis for Alkoxy Radical‐Mediated Selective Hydroetherification
Abstract We present a ligand‐to‐metal charge transfer (LMCT)‐enabled catalytic platform utilizing cerium(IV) benzoate complexes to address the long‐standing challenge of directly cou...
S‐Vacancy‐Induced “Proton Fence Effect” Enables Selectivity Switching between CH <sub>4</sub> and CO in Photo‐Assisted CO <sub>2</sub> Electroreduction
Abstract Upcycling CO 2 into high‐value C 1 products is impressive for achieving...
Tumor Microenvironment‐Responsive Polymer Delivery Platforms for Cancer Therapy
Abstract Most chemotherapeutic and bioimaging agents struggle with inadequate bioavailability, primarily due to their limited biocompatibility and lack of specificity in targeting, l...
Luminescent Detection of Photomagnetic Effect in a Near‐Infrared Emissive Neodymium(III)–Octacyanidotungstate(IV) Framework
Abstract Photomagnetic materials form a class of magnetic systems, in which light irradiation changes their magnetization. Photomagnetic behavior is often observ...
Nanoconfined Ultrathin Polymer Membrane for Ultrafast Separation of Biobutanol from Water
Abstract Efficient recovery of biobutanol, a next‐generation biofuel, from fermentation liquor remains challenging due to its low concentration and volatility. T...
Identification of an Activity Selector for the Nitroso‐Forming Activity in Bacterial Type‐III Copper Enzymes
Abstract O ‐aminophenol oxidases, a specialized subclass of type‐III copper proteins, play a crucial role in the biosynthesis of bioactive ni...