Angewandte Chemie International Edition
Articles in this Issue
Unprecedented Tetravalent Uranium Photocatalysts for Efficient C(sp <sup>3</sup> )─C(sp <sup>3</sup> ) Bond Cleavage and Formation
Abstract Photocatalysis is a pivotal area in synthetic chemistry. Despite extensive application potential in nuclear industry, uranium‐based photocatalysts are h...
pH‐Responsive AIE Photosensitizers for Enhanced Antibacterial Therapy
Abstract Bacterial infections significantly alter the local microenvironment, with acidic byproducts from bacterial metabolism leading to a pronounced pH reduction. Leveraging this c...
Bimetallic Design Based on the Nucleation Rate of Prussian Blue Analogues for Enhanced Aqueous Zinc Ion Batteries with Glycerol–Water Hybrid Electrolytes
Abstract A magical heterostructures of M‐PBAs (M = Co, Cu, and Zn) encapsulated by V‐PBA have been successfully obtained by a facile one‐pot coprecipitation method based on the diffe...
Natural Sunlight‐Driven Activation of Inert Aryl Halides Using Plasmonic Cu@CdS with Polysulfide Active Sites
Abstract Visible light photoredox catalysis has become a rapidly emerging area owing to its potential of using sunlight to tame previously hard‐to‐harness radica...
Understanding the Position Effects of Monoatom Doping in Silver Nanoclusters on Oxygen Reduction by Single Entity Electrochemistry
Abstract Alloying nanoclusters (NCs) with monoatom doping represents an effective strategy to enhance catalytic performances due to the synergistic interactions...
2D Conjugated Metal–Organic Frameworks as Electrocatalysts for Boosting Glycerol Upgrading Coupled with Hydrogen Production
Abstract The valorisation of glycerol using renewable electricity is recognised as an effective and attractive approach for producing high‐value compounds from b...
Metathetical Exchange, Synthesis, and Carbon Dioxide Addition of Higher Homologues of Group 9 Metal Carbynes
Abstract A one‐pot synthesis for previously unknown heavy homologues of Group 9 metal carbynes [(Me 3 P)...
Modular Access to Aliphatic Polycarbonates with Tunable Properties and Dual Closed‐Loop Recyclability by Polycondensation–Depolymerization–Repolymerization Strategy
Abstract Great achievements have been made in CO 2 /epoxide copolymerization and dialkyl carbonate/diol polycondensation;...
Localized High‐Concentration Electrolytes With Semi‐Solvated Hexafluoroisopropyl Methyl Ether Diluent for Wide‐Temperature‐Range Lithium Metal Batteries
Abstract Conventional electrolytes in lithium metal batteries (LMBs) suffer from irreversible interfacial degradation at elevated temperatures and sluggish Li⁺ d...
Ultrabright and Water‐Stable Eu(III)‐Based MOF Scintillators Sensitized by Dual‐Antenna Ligands for Real‐Time and Underwater X‐Ray Imaging
Abstract Lanthanide‐based metal–organic framework (Ln‐MOF) scintillators are promising for X‐ray imaging owing to their structural tunability and high X‐ray atte...
Bridging the Interlayer Binding to Ordered π‐Conjugated Units for Constructing High‐Performing Light Polarization Crystals
Abstract The light polarization modulation involves the capacity to respond selectively to light‐mater interaction and is dependent on the optical anisotropy of...
Organic Cage Encapsulated Within Metal Cluster‐Based Open Frameworks: A Single‐Crystal Host‐in‐Host Material with Inter‐Host Charge Cooperation
Abstract Integrating dissimilar building units of discrete organic cages and inorganic clusters into single‐crystal supramolecular frameworks with tailored architectures and synergis...
Generation, Capture, Storage, and Release of Singlet Oxygen from a Perylene Diimide‐Based Metallacage for Oxygen Sensing
Abstract The controlled generation and utilization of singlet oxygen ( 1 O 2 ) ar...
Nonbonding Electron Inversion‐Driven Structural Engineering: Synergistic Enhancement of Linear and Nonlinear Optical Properties
Abstract The simultaneous optimization of large birefringence (Δn, a linear optical property) and strong second‐harmonic generation (SHG, a nonlinear optical (NL...
Taxonomy of Chemical Bondings: Opportunities and Challenges
Abstract The concept of the chemical bond is fundamental to chemistry, governing atomic interactions that define all known matter. Despite this central role, the classification and m...
Intrinsically Disordered Peptide Nanofibers from a Structured Motif Within Proteins
Abstract Intrinsically disordered regions (IDRs) are ubiquitous in proteins, orchestrating complex cellular signaling through higher‐order protein assemblies. However, the properties...
Pyrazine‐Embedded 2D Conjugated Metal–Organic Framework with Quasi‐Honeycomb Lattice for High‐Capacitance Lithium‐Ion Storage
Abstract As a unique class of framework electronic materials, 2D conjugated metal–organic frameworks (2D c ‐MOFs) exhibit...
Harnessing Lithium‐Mediated Green Ammonia Synthesis with Water Electrolysis Boosted by Membrane Electrolyzer with Polyoxometalate Proton Shuttles
Abstract Integrating water electrolysis (WE) with lithium‐mediated nitrogen reduction (Li‐NRR) offers a sustainable route for green ammonia production by directl...
Interfacial Atom Rearrangement Drives Potential‐Adaptive Electrocatalytic Olefin Hydrogenation
Abstract Dynamic rearrangement of metal atoms at heterointerfaces by chemical bond conversion drives high efficiency electrocatalytic processes, which is a new c...
Halogen Bonding Enable Improved Performance and Stability of Dion–Jacobson Perovskite Solar Cells
Abstract The undesired phase distribution and intrinsic residual lattice strain remain the bottleneck for high‐performance and stable 2D or Q‐2D perovskite solar cells (PSCs), especi...
Oscillatory Strong Metal‐Support Interaction in Pd/TiO <sub>2</sub> Under Redox Conditions
Abstract Strong metal‐support interaction (SMSI) plays a crucial role in catalysis, with its encapsulation configuration being highly dependent on the chemical e...
Anchoring Highly Unsaturated Nickel(II) Sites into a Metal–Organic Framework for Simultaneous High C <sub>2</sub> H <sub>2</sub> Adsorption and Separation
Abstract Separation of acetylene (C 2 H 2 ) from carbon dioxide (CO...
Triple Synergy Engineering via Metal‐Free Dual‐Atom Incorporation for Self‐Sustaining Acidic Ammonia Electrosynthesis
Abstract Electrochemical nitrate reduction reaction (NO 3 RR) for ammonia synthesis under acidic conditions offers signif...
Synergistic Effect of Boron and Oxygen Coordination on Ruthenium Clusters for Industrial Water Splitting in Alkaline Medium
Abstract The alteration in the coordination environment of metal atoms can manipulate their electronic structure and regulate the electrocatalytic hydrogen evolu...
Synthesis of Nitriles from Dinitrogen via N‐Atom Transfer on Rhenium Nitride Complex
Abstract Transition‐metal mediated dinitrogen (N 2 ) splitting into terminal nitrido moiety followed by N‐atom transfer i...