Angewandte Chemie International Edition
Articles in this Issue
Phosphorescent Iridium(III) Phenanthrolinedione Complexes as Lifetime‐Responsive Bioorthogonal Probes for Wash‐Free Time‐Resolved Bioimaging of Cellular Labeling
Abstract Fluorogenic bioorthogonal probes are crucial tools in biomedical research, which enable non‐invasive, wash‐free imaging of specific biomolecules in living systems. Lifetime‐...
Interface Engineered Electrolyte Design Strategy for Ultralong‐Cycle Solid‐State Lithium Batteries Over Wide Temperature Range
Abstract Achieving stable operation under a wide temperature range is the direction of development for the practical application of solid‐state lithium batteries...
Protonated Glutamate and Aspartate Side Chains Can Recognize Phosphodiester Groups via Strong and Short Hydrogen Bonds in Biomacromolecular Complexes
Abstract Phosphodiester groups occur ubiquitously in nature, e.g. in nucleic acids or in cyclic (di‐)nucleotides important for signal transduction. Proteins ofte...
Electrochemically Promoted Activation of Light Alkanes at Ambient Conditions
Abstract The electrochemical activation of light alkanes into value‐added products represents a promising pathway for sustainable chemical synthesis and the stor...
Palladium‐Catalyzed Enantioselective Arylative Dearomatization of Naphthols and Phenols for Constructing Quinazoline‐Containing Spirocycles
Abstract We report a palladium‐catalyzed enantioselective arylative dearomatization of phenols and naphthols, demonstrating a broad substrate scope and excellent...
Nitrate Reduction for Deaminative Suzuki–Miyaura Coupling of Anilines
Abstract We present a deaminative Suzuki–Miyaura‐type coupling (SMC) of anilines with nitrate as a diazotization reagent, which integrates transition‐metal catalysis with nitrate‐bas...
Chemically Fueled Active Transport
Abstract Biology uses chemical potential differences from molecules like ATP to drive membrane pumps, transporting molecules across membranes even against concentration gradients. He...
Biomass‐Derived Functional Polyacetals via Controlled Cascade Enyne Metathesis Polymerization: Tunable Degradability, Postpolymerization Modification, and Self‐Assembly
Abstract We present a versatile platform for the synthesis of functional polyacetals from sugar and furfuryl alcohol derivatives using controlled cascade enyne m...
Inside Back Cover: Rare Earth Single‐Atomic Hybrid Glasses for Near‐Infrared II Optical Waveguides (Angew. Chem. Int. Ed. 27/2025)
Electrochemical Synthesis of Hydroxylamine
Abstract Hydroxylamine (NH 2 OH) serves as an important industrial feedstock. The conventional production and transportat...
Inside Front Cover: Giant Birefringence Enabled by the Highly Anisotropic Linear IX <sub>2</sub> <sup>‐</sup> (X=Cl, Br) Building Blocks (Angew. Chem. Int. Ed. 27/2025)
Photodriven Aquatic Locomotion in Liquid Crystalline Elastomer Composites with Tunable Wettability
Abstract Photodriven liquid crystalline elastomer (LCE) composites with thiol‐functionalized Ti₃C₂T x...
Regulating Multifunctional Oxygen Vacancies for Plasma‐Driven Air‐to‐Ammonia Conversion
Abstract Current ammonia (NH₃) synthesis is hindered by challenges including N₂ activation, NH₃ separation and process complexity. Here, we report a plasma‐elect...
A Biodegradable Radical Polymer Enables High‐Performance, Physically Transient Organic Memory
Abstract Electronic devices often demand high reliability and longevity, but they also contribute significantly to electronic waste. Physically transient electro...
An Atmosphere‐Responsive Protective Strategy Based on Deciphering the Anode Degradation Mechanism in Li–CO <sub>2</sub> Batteries
Abstract Lithium–carbon dioxide (Li–CO 2 ) batteries, with high energy density and CO 2...
Introducing Photochemical Action Plots as a Tool for Unlocking On–Off Switchable Behavior in a Polymeric Eosin Y Photocatalyst
Abstract Photochemical action plots are a powerful tool for investigating the wavelength‐dependent efficiency of photochemical processes. Herein, we apply the ph...
Frontispiece: Ultra‐Stable Gold Nanoparticles with Tunable Surface Characteristics
Promoting Alkane Binding: Crystallization of a Cationic Manganese(I)‐Pentane <i>σ</i> ‐Complex from Solution
Abstract Transition metal–alkane σ ‐complexes are key intermediates in C–H activation and, until now, analysis of these s...
Development of Chiral Bisphosphine Ligands with a Terminal Olefin Enables Asymmetric Orthogonal Auto‐Tandem Catalysis
Abstract Auto‐tandem catalysis (ATC) leverages the multiple roles of the catalyst, facilitating the direct synthesis of complex molecules from simple starting materials in a highly e...
Nanoengineering Carbon Dot‐Polymer Brush Interfaces for Adaptive Optical Materials
Abstract We present a versatile platform for fabricating two‐photon excitable carbon dot‐based nanocomposite thin films by harnessing the structural versatility of polymer brushes in...
Facile N═N Bond Cleavage of <i>Cis</i> ‐Azobenzene with Bis‐silylenes
Abstract The very different features of cooperative disilicon(II)‐mediated N═N bond activation of trans ‐ vs....
Ultra‐Stable Gold Nanoparticles with Tunable Surface Characteristics
Abstract Gold nanoparticles (Au NPs), as a class of functional nanomaterials, have attracted considerable interest for biomedical applications owing to their unique chemical and phys...
p–p Orbital Hybridization Stabilizing Lattice Oxygen in Two‐Dimensional Amorphous RuO <i> <sub>x</sub> </i> for Efficient Acidic Oxygen Evolution
Abstract Developing efficient Ru‐based catalysts is crucial in reducing reliance on costly Ir for the acidic oxygen evolution reaction (OER). However, these Ru‐b...
Metal‐Organic Frameworks at the Edge of Stability: Mediating Node Distortion to Access Metastable Nanoparticle Polymorphs
Abstract Metal‐organic frameworks (MOFs) are emerging as unconventional precursors for nanoparticle synthesis, with potential to leverage their tunable structure...