Angewandte Chemie International Edition
Articles in this Issue
Selective Aerobic Oxidation of Toluene to Benzaldehyde by Parallel Photoinduced Proton‐Coupled Electron Transfer and Energy Transfer Through Multiphoton Excitation
Abstract Selectively aerobic oxidation of toluene to benzaldehyde is an important but challenging task due to the high proclivity of aldehydes to undergo over‐ox...
Interfacial Engineering and Structural Modulation of RuO <sub>2</sub> ‐Based Catalysts for Highly Active and Durable Oxygen Evolution Reaction in Acidic Environment
Abstract Developing highly active and durable catalysts for the oxygen evolution reaction (OER) under acidic conditions is key to commercializing green hydrogen...
Ming Zhao
Thermally Triggered Redox Flexibility of Pt/CeO <sub>2</sub> Cluster Catalyst Against In‐Situ Atomic Redispersion
Abstract For supported catalysts, the redispersion of aggregated metal sites into single atoms is dictated by the reactant‐induced metal‐support interaction, whi...
Jing Wei
High‐Performance FeP Catalyst for Electrochemical Ammonia Production and Recovery via Joule‐Stripping
Abstract The electrochemical reduction of nitrate (NO₃RR) offers a promising route for decentralized and sustainable ammonia production while addressing environm...
Chiral Diazatriptycene Exhibiting Acid‐Induced Ternary Circularly Polarized Luminescence Switching and Crystal Morphology Changes
Abstract Doubly N ‐doped triptycene 2,6‐diazatriptycene 1 was synthesized as the...
Covalent Organic Frameworks Coupled with Redox Center and Adsorption Site for Efficient Shuttle‐Free Zn‐Iodine Batteries
Abstract Aqueous zinc‐iodine (Zn‐I 2 ) batteries exhibit significant potential for next‐generation energy storage system,...
Hydrogen Bond‐Assisted PCET and Formation of W <sup>III</sup> ─OH in Bis(Dithiolene) Complex
Abstract The redox non‐innocent nature of dithiolene ligands is well known for stabilizing high‐valent metal ions and facilitating proton‐coupled electron transf...
MOF Coating Enhances the Ion Tolerance of Micromotors
Abstract Electrophoretic‐driven micro/nanomotors (EMNMs) offer great potential for biomedical applications due to their design flexibility. However, they face ch...
Three‐Motif Molecular Junction Covalent Organic Frameworks for Symmetric All‐Organic Lithium‐Ion Battery
Abstract The symmetric all‐organic batteries (SAOBs) based on the same organic electrode materials for both cathode and anode are promising in achieving an effic...
Substrate Preorganization Within Photoactive Pt <sub>12</sub> L <sub>24</sub> Nanospheres for Accelerated Decarboxylation Catalysis at Low Concentrations
Abstract Photoredox catalysis with short‐excited state lifetimes or in dilute conditions is challenging because the photochemical mechanism relies on collisions...
Frontispiece: <i>ortho</i> ‐C─H Alkylation of Aryl Chlorides by a Catellani Strategy
Frontispiece: Unexpected Activities of CYP152 Peroxygenases Toward Non‐carboxylic Substrates Reveal Novel Substrate Recognition Mechanism and Catalytic Versatility
Boron‐Activated Single‐Metal‐Site Catalysts Break Adsorption‐Energy Scaling Relations for Robust Bifunctional Oxygen Catalysis
Abstract The electrocatalytic oxygen evolution and reduction reaction (OER/ORR) catalysts are paramount to many renewable energy technologies. Atomically‐dispers...
Harmonizing Nanoparticle Exsolution From Ce–Sm Oxide Matrix for Stable Methane Dry Reforming
Abstract Catalyst deactivation hinders the application of high‐temperature catalysis such as methane dry reforming, where nanoparticle exsolution will likely cle...
A Resonance Hybrid Design for Stable Aqueous Organic Redox Flow Batteries
Abstract Organic molecules are promising candidates for aqueous organic redox flow batteries (AORFBs) due to their structural versatility, tunability, and relian...
Inside Back Cover: Late‐Stage C─N Bond Cleavage Enables Diversification of Multiple Resonance Materials (Angew. Chem. Int. Ed. 31/2025)
Self‐Healing Indium Sulfide Catalyst for Efficient and Robust Electrocatalytic CO2 Conversion
Abstract The reduction–reconstruction of the catalyst under negative bias has been identified as a significant rationale underlying the performance degradation o...
Iridium‐Catalyzed Enantioselective Intramolecular Hydroarylation of Allenes: Formal Synthesis of (+)‐Rhazinilam
Abstract We report a versatile, highly enantioselective intramolecular hydroarylation of allenyl‐tethered pyrroles and indoles. The reaction, promoted by an iridium(I)/bisphosphine c...
Fully Conjugated Sp <sup>2</sup> Carbon‐Linked Covalent Organic Frameworks Enables Accelerated Exciton Process for Superior Singlet Oxygen Photosynthesis for Water Remediation
Abstract Photocatalytic oxygen (O 2 ) activation via energy transfer offers a sustainable approach for singlet oxygen (...
A Thorough Characterization of the Tellurocyanate Anion
Abstract Tellurocyanate, [TeCN] − , is the heaviest group 16 congener of the cyanate anion, [OCN] −...
Isothiourea‐Catalysed Acylative Kinetic and Dynamic Kinetic Resolution of Planar Chiral Paracyclophanols
Abstract The development of synthetic methods for the catalytic enantioselective preparation of planar chiral paracyclophane derivatives is of considerable inter...
Conformational Change in a Four‐Tetrad DNA G‐Quadruplex upon Intercalation of a Small‐Molecule Ligand PyDH2
Abstract G‐quadruplexes (G4s) are non‐canonical DNA structures implicated in a number of biological processes. Small‐molecule ligands can alter stability and fol...
Systematic Evaluation of Polarizing Agents for Dynamic Nuclear Polarization Enhanced NMR
Abstract Dynamic nuclear polarization (DNP) can significantly enhance the sensitivity of nuclear magnetic resonance (NMR) spectroscopy, via the transfer of polarization from unpaired...