Angewandte Chemie International Edition
Articles in this Issue
Reticular Synthesis of 3D Metal Cluster‐Based COFs With Record High‐Connectivity for Efficient Photocatalytic H <sub>2</sub> O <sub>2</sub> Synthesis
Abstract The assembly of metal clusters with organic building units by covalent bonds to form metal cluster‐based covalent‐organic frameworks (MCCOFs) material i...
Ionic Liquid Accelerates Electrochemically Driven Single‐Molecule Oxidative Coupling
Abstract Molecular adsorption covers a broad spectrum of chemical processes and device fabrications at solid/liquid interfaces. The unraveling of the underlying mechanisms relies on...
Electronic Modulation and Active Site Exposure Using C <sub>60</sub> Fullerenolamine Enable High‐Performance Alcohol Oxidation on Pd Metallene Catalysts
Abstract The availability of active sites and the electronic structure of metal heterogeneous catalysts are crucial to maximize their catalytic performance. In t...
Chain–Chain Synergistic Hydrogel Electrolytes Regulate Zinc Ions Desolvation for Stabilized Anodes and High Operating Voltage in Flexible Zinc Ions Hybrid Capacitors
Abstract To maximize the energy density output, the complementary charge storage mechanism of aqueous zinc ion hybrid capacitors (ZIHCs) is superior and advanced...
Atomically Engineered Acridine Derivatives Serve as Metal‐Free and Self‐Sensitized Catalysts for Solar‐Driven CO <sub>2</sub> to Formic Acid with High‐Efficiency and Near‐Perfect Selectivity
Abstract Achieving efficient and selective light‐driven CO 2 conversion to formic acid is a significant scientific challe...
Boosting Ultra‐Wide Temperature Sodium‐Bromine Batteries via Chlorine‐Bromine Activation
Abstract The development of high‐energy‐density batteries operable over a wide temperature range is critical for sustainable energy storage. Sodium‐chlorine (Na‐...
Epitaxial Electrodeposition of Lithium Metal in Cubic Wulff Structures
Abstract Electrodeposition of lithium (Li) metal is crucial for highenergydensity rechargeable Li batteries. The electrodeposition morphology governs the reversibility of the deposit...
Solution‐Mediated Photoreversible Switch Between 2D and 3D Hydrogen‐Bonded Organic Frameworks
Abstract In photoresponsive crystalline porous materials, the light‐driven reversible topological transformation is of particular interest, as it can cause an ov...
Spin‐State and Clustering Effects in Fe‐Complex Negolytes for Near‐Neutral Aqueous Redox Flow Batteries
Abstract Cost‐effective redox‐active materials are essential for advancing redox flow batteries (RFBs). Iron, with its abundance and suitability as a redox coupl...
Proteome‐Wide Ligand and Target Discovery by Using <i>β</i> ‐Nitrostyrene Electrophiles: Supporting Targeted Protein Degradation
Abstract Bioconjugation chemistry has been a powerful avenue in expanding the repertoire of druggable proteome, as well as in identifying new E3 ligases to suppo...
Probing the Heteroepitaxial Seeded Growth and Self‐Sorting Processes of Segmented Co‐Micelles with Chemically Distinct Crystalline Cores
Abstract The ability to produce uniform micellar nanoparticles with controlled dimension and spatially controlled functionality is a key challenge in nanoscience. Living crystallizat...
Mechanism of First Proton‐Coupled Electron Transfer of Water Oxidation at the BiVO4${\rm BiVO}_4$–Water Interface
Abstract The oxygen evolution reaction (OER) at the –water interface is considered to be the bottleneck of the overall water splitting at this aqueous interface. To provide insight i...
The Doping Effects on the NIR Emission Enhancement of Gold Nanoclusters and the Application in Efficient NIR‐OLED
Abstract Metal nanoclusters (NCs) have emerged as promising near‐infrared (NIR) emissive materials. A series of highly red/NIR luminescent Au–Cu nanoclusters hav...
Flexible‐Linked Oligomeric Acceptors: Precise Synthesis and Enhanced Photovoltaic/Mechanical Properties for Stretchable Devices
Abstract Intrinsically stretchable organic solar cells (IS‐OSCs) are among the most promising technologies for wearable power applications. However, the developm...
Co‐sustained Release Strategy of Nonflammable Gel Polymer Electrolytes Enables Long‐Life Sodium Metal Batteries
Abstract Sodium metal batteries (SMBs) with gel polymer electrolytes (GPEs) are considered promising candidates for high energy‐density batteries due to their high theoretical capaci...
Thio‐Tetracosulene: A Highly Twisted Molecular Plectoneme
Abstract We report the synthesis and characterization of thio‐tetracosulene 3 , a highly twisted chiral macrocycle constr...
The Crucial Role of Oxygen Evolution Reaction in Electrocatalytic Oxidative C─C Bond Cleavage in Lignin Biomass Valorization
Abstract The electrocatalytic oxidative cleavage of the C─C bond is highly effective for converting lignin biomass into high‐value‐added aromatic chemicals. Howe...
Circumventing Scaling Relations via Gradient Orbital Coupling Promotes Ammonia Electrosynthesis on Cobalt Catalyst
Abstract Highly efficient electrocatalytic nitrate reduction to ammonia (NH 3 ) relies on the balanced activation of vari...
Synergistic Dual‐Interface Engineering in Perovskite Solar Cells via Chloramine Hydrochloride Molecular Bridges
Abstract High‐performance perovskite solar cells (PSCs) require synergistic passivation strategies to address defects at the electron transport layer (ETL)/perov...
NbGa <sub>2</sub> S <sub>4</sub> (S <sub>2</sub> ): A Rare Linear [S <sub>2</sub> ] <sup>2−</sup> Coordination to Niobium Resulting in Simultaneously Large SHG Effect and Giant Birefringence
Abstract We report a novel niobium thiogallate, NbGa 2 S 4 (S...
Simultaneous Boosting of Second Harmonic Generation and Circularly Polarized Luminescence in Chiral Hybrid Metal Halides Through Enhanced Octahedral Distortion
Abstract Chiral hybrid metal halides (HMHs), characterized by their non‐centrosymmetric crystal structures and exceptional photophysical properties, are promisin...
Molecule‐Cooperative Strategy for Dopant‐Free Hole Transporting Layer toward Fully Printed High‐Performance Perovskite Solar Cell Modules
Abstract Enabling large‐area deposition of dopant‐free organic hole transport layers (HTLs) with high reproducibility and uniformity is crucial for fully printed...
Elucidating the Correlation Between the Redox Potential, Spin State, and Crystal Structure in a Series of Ferrous Complexes with Redox‐Active Ligands
Abstract Accurately predicting the spin crossover (SCO) temperature ( T 1/2 ) in spin crossover compo...
Small Molecule‐Induced Alterations of Protein Polyubiquitination Revealed by Mass‐Spectrometric Ubiquitome Analysis
Abstract Small molecules that alter protein ubiquitination are emerging as therapeutics due to their ability to modulate targets previously deemed undruggable. These compounds compri...
Acidic Nitrate Electroreduction with Ultrahigh Energy Efficiency
Abstract Ammonia (NH 3 ) is an important feedstock for industry, an ideal energy carrier, and a perspective storage media...