Angewandte Chemie International Edition
Articles in this Issue
Interfacial‐Confined Oxygen Vacancy Clusters in ZrO <sub>2</sub> ‐Supported In <sub>2</sub> O <sub>3‐</sub> <i> <sub>x</sub> </i> Catalysts Boost Methanol Production From CO <sub>2</sub>
Abstract Oxygen vacancies (V O ) play a vital role in catalytic reactions. Tuning the V O...
Scalable H <sub>2</sub> O <sub>2</sub> Production via O <sub>2</sub> Reduction Using Immobilized Vanadyl Phthalocyanine
Abstract The production of hydrogen peroxide (H 2 O 2 ) via the two‐electron oxyg...
“Rigid Exterior, Soft Interior” Design Enables High‐Voltage Polyether Electrolytes for Quasi‐Solid‐State Batteries
Abstract Polyether electrolytes with high Li + conductivity and excellent interfacial contact have garnered significant a...
Catalytic α‐Site‐Selective Hydrogen‐Deuterium Exchange of Benzylic Alcohols by Palladium Single‐Atom Catalyst
Abstract Catalytic hydrogen‐deuterium exchange (HDE) has emerged as a valuable tool for achieving site‐selective deuteration and the precision labeling of bioactive molecules. Incorp...
A Platform for the Development of Highly Red‐Shifted Azobenzene‐Based Optical Tools
Abstract Azobenzenes are versatile photoswitches that can be used to generate elaborate optical tools, including photopharmaceuticals. However, the targeted appl...
Selective Production of Acetylene from the C─C Coupling Reaction of CH <sub>4</sub> with CO <sub>2</sub> Mediated by Ta <sub>2</sub> O <sub>2</sub> <sup>+</sup> Cluster Cations
Abstract Coconversion of methane and carbon dioxide to C 2 hydrocarbons via the C CH4...
Multivariate MOF Hollow Fiber Membranes with Precision‐Tuned Subnanometer Channels Toward Aromatic Hydrocarbon Separation
Abstract Metal‐organic framework (MOF) membranes exhibit great potential for molecular separations, but it remains a considerable challenge to achieve precise pore aperture regulatio...
Non‐Innocent Ligands as Mediators for Visible‐Light‐Initiated Element–Carbon Bond Homolysis in Main Group Chemistry
Abstract Photoinitiated homolysis of element–carbon bonds is an important method for the generation of carbon‐centered radicals in catalysis and organometallic or polymer chemistry....
Insights into the Mechanisms Behind Structural Repair of Spent Layered Cathode Materials for Lithium‐Ion Batteries
Abstract Structural repair is a vital step in the direct recycling of spent LiNi x...
Self‐Assembly of a Customizable Library of Nickel Trifluoromethylation Catalysts via Selective C─F and C─O Bond Cleavage
Abstract Using a combination of metal‐promoted reactivity, in situ covalent bond modification, and hydrogen bonding‐promoted fluorine labilization, a unified approach was developed t...
Visible‐Light‐Controlled Lysine‐Selective Crosslinking Decodes Protein Complexes and Dynamic Interactomes in Live Cells
Abstract Crosslinking strategies have emerged as an attractive technology for deciphering protein complexes and protein–protein interactions (PPIs). However, com...
3D‐Printed COF/Zeolite Composites for Augmented Photocatalytic Hydrogen Peroxide Production
Abstract Covalent organic frameworks (COFs), characterized by high porosity and fine‐tuned structures, are promising photocatalysts for hydrogen peroxide (H...
Zhishuai Geng
Cascade Electrocatalytic Reduction of Nitrate to Ammonia Using Bimetallic Covalent Organic Frameworks with Tandem Active Sites
Abstract Electrochemical nitrate reduction reaction (NO 3 RR) is a promising approach to simultaneously realize pollutant...
Multi‐ion Coordinated Water Network in Dilute Acid Electrolytes for Ultralow‐Temperature (≤−80 °C) Proton Energy Storage
Abstract Proton batteries/capacitors, known for fast ion diffusion kinetics, are a promising alternative for low‐temperature energy storage. However, ultralow‐te...
Ternary Potassium‐Bismuth‐Telluride Intermetallic Support Promotes Electrochemical Stability in Potassium Metal Anodes
Abstract We employed accumulative roll bonding to fabricate self‐standing metallurgical composite of in situ formed alkaline potassium‐bismuth‐telluride intermet...
Enantioconvergent Cobalt‐Catalyzed Hydroalkylation for the Construction of Fluoro, Chloro, and Trifluoromethyl Stereogenic Centers
Abstract Organic compounds containing a chiral, halogenated aliphatic carbon center are useful in medicinal chemistry, but their enantioselective synthesis remains difficult. Here, w...
Lattice Distortion Promoting Wavelength‐Tunable Emissions in Cu(I)‐Based Halides for Thermography and Anti‐Counterfeiting
Abstract Low dimensional hybrid metal halides as a chemically tunable platform achieve multi‐functional optical applications with versatile luminescence mechanis...
Direct Integration of Functionalized Bridges by One‐Step Superacid‐Catalyzed Reaction to Fabricate Porous Polymers for CO <sub>2</sub> Capture and Separation
Abstract A novel class of ultra‐microporous functionalized porous organic polymers (POPs) was developed starting from glyoxylic acid as a cross‐linker and trifli...
Intramolecular Dual Donor‐Acceptor Featured Covalent Organic Frameworks Enabled by Gating Effects for Ultra‐Stable Na‐Metal Batteries
Abstract Sodium metal batteries (SMBs) face severe challenges of uncontrolled sodium dendrite growth and interfacial instability. Herein, guided by theoretical p...
Markus D. Kärkäs
Twist‐Promoted Photoredox Catalysis in Metal‐Organic Framework for Defluorination Reactions
Abstract The relatively short excited‐state lifetime is one main drawback of organic photosensitizers, resulting in their restricted catalytic capability and hig...
Enhanced Cycling Performance of Li‐Rich Oxide Cathode via a Vaccine Effect
Abstract Multi‐component incorporation and its inoculated gradient disorder structure can greatly modify the properties of materials. However, the contribution o...
Quenching‐Induced Three‐Phase Heterostructured Catalysts for Oxygen Electrocatalysis with Lattice Oxygen Participation
Abstract Lattice oxygen‐mediated mechanism of oxygen evolution reaction can overcome the scaling relations‐induced limitations imposed by conventional adsorption...
“Gene‐Editing” Design Upgrades Eutectic‐Polymer Electrolytes with Ultra‐High Li <sup>+</sup> Conductivity
Abstract Deep eutectic polymer electrolytes (DEPEs) have emerged as highly promising next‐generation electrolytes, offering unparalleled electrochemical performa...