Angewandte Chemie International Edition
Articles in this Issue
Tailoring Coordination Microenvironment of Nickel Molecular Complexes for Electrooxidation of Organic Nucleophiles
Abstract Electrochemical oxidation of organic nucleophiles to value‐added chemicals using nickel‐based catalysts is promising yet hindered by the dynamic evoluti...
Thermally Activated Sensitized Fluorescence Enables Efficient Carbon Quantum Dot‐Based Electroluminescent LEDs with Current Efficiency of 31 cd A <sup>−1</sup>
Abstract Carbon quantum dots (CQDs) are gaining increasing attention as eco‐friendly alternatives to conventional heavy‐metal‐based QDs for full‐color displays a...
Modulating Diffusion Kinetics and Interfacial Stability via In‐Situ Constructed Self‐Healing Interfaces for Highly Reversible Zinc Metal Anodes
Abstract Commercial Zn anodes contain inherent manufacturing defects, such as scratches, rough surfaces, fold lines, and microcracks. These surface defects damag...
Anion Vacancies Triggered Spin Polarization Enables Efficient Piezocatalysis for Water Cleanup
Abstract The conversion of aromatic organic pollutants into value‐added chemical feedstocks is still suffering from sluggish carbon reduction kinetics with spin‐...
Unlocking Ultrafast‐Kinetics Asymmetric Heterojunction with Multi‐Anionic Redox Chemistry Enables High Energy/Power Density and Low‐Temperature Zinc‐Ion Batteries
Abstract The development of high‐performance Zn‐ion batteries is hindered by sluggish reaction kinetics and inadequate redox activity in conventional vanadium‐ba...
Frontispiece: Molecular Design and Synthesis of Narrowband Near‐Ultraviolet and Pure Deep‐Blue Thermally Activated Delayed Fluorescence Materials by an Ether Group Strategy
Light‐Driven Ligand Exchange for Palladium‐Catalyzed Regiodivergent Transfer Hydrothiocarbonylation
Abstract Transfer hydrocarbonylation of alkenes could streamline the synthesis of value‐added carbonylated molecules by avoiding the use of pressurized toxic CO. Existing methods, ho...
Patch‐Clamp‐Like Micropipette Electrode with Exterior and Interior Interfaces for Simultaneous Monitoring of Extracellular and Intracellular Serotonin Across Neuron
Abstract Simultaneous monitoring of intracellular and extracellular serotonin (5‐HT) across five orders of magnitude is crucial for understanding 5‐HT‐related diseases. Here, we crea...
Synthesis of Versatile DNA‐Conjugated Aldehydes by Controlled Oxidation of Amines
Abstract Aldehyde‐functionalized oligonucleotides have found diverse applications in chemical biology and material science. However, due to the electrophilic nat...
Continuous Intermediates Spillover Boosts Electrochemical Nitrate Conversion to Ammonia over Dual Single‐Atom Alloy
Abstract Electrochemical nitrate conversion to ammonia driven by sustainable green electricity is regarded as a promising supplement to the traditional Haber–Bos...
Modulation of Lanthanide Luminescence with the Mechanical Bond: Antenna‐Emitter Confinement in a Compact [2]Rotaxane
Abstract Luminescent emitters based on lanthanide ions are of ubiquitous importance in the biological sciences, but typically need sensitization from a covalently attached adjacent c...
Relay‐Enhanced Electron Transfer in Triple‐Layer Ru@Ir@Pt Core–Shell Nanoparticles for the Ammonia Oxidation Reaction
Abstract Ammonia oxidation reaction (AOR) is important for enabling the efficient use of NH 3 as a promising carrier for...
Operando Spectroscopic Insights into CO <sub>2</sub> Reduction at Electrode/Polyelectrolyte Interfaces
Abstract The electrode/polyelectrolyte interface is a notable feature in modern electrochemical technologies that utilize membrane electrode assembly (MEA) confi...
Single‐Specie Selectivity via Subnanometer Hierarchical Porous Channel Metal‐Organic Gels Toward Ultra‐stable Anodes for Zn Metal Batteries
Abstract Gel polymer electrolytes demonstrate substantial potential for aqueous zinc‐ion batteries, yet obtaining exquisite balance between molecular/ion sieving...
Molecular Design and Synthesis of Narrowband Near‐Ultraviolet and Pure Deep‐Blue Thermally Activated Delayed Fluorescence Materials by an Ether Group Strategy
Abstract Boron‐containing polycyclic aromatic hydrocarbons are promising materials for the development of displays due to their multiple‐resonance thermally acti...
Chemical Bond Covalency in Superionic Halide Solid‐State Electrolytes
Abstract Halide solid‐state electrolytes (SSEs) are promising superionic conductors with high oxidative stability and ionic conductivity, making them attractive...
Robust Ionic Gel Elastomers Derived from Molecularly Entangled Nodes
Abstract In various types of intelligent devices, such as bionic robots, flexible polymeric elastomeric materials are essential for their operation, alongside the rigid skeleton. Con...
An Atomically Precise Alkynyl‐Functionalized Silver–Polyoxotungstate Nanocluster with Sandwiched Three‐Layer {Ag <sub>13</sub> } <sup>13+</sup> Cluster Architecture and Enhanced Antitumor Activity
Abstract The synthesis of atomically precise, structurally well‐defined polyoxometalate (POM)‐stabilized silver clusters with accessible silver surfaces remains...
Frontispiece: Mechanism of First Proton‐Coupled Electron Transfer of Water Oxidation at the BiVO <sub>4</sub> –Water Interface
A <sup>19</sup> F‐Labeled Probe for the Chiral Discrimination of Thiols and Thioethers
Abstract Sulfur‐containing compounds are pivotal in cellular processes such as redox balance and signal transduction. Traditionally, these compounds, especially...
Harnessing Bifunctional <i>N</i> ‐Benzoyloxyamides for Photoredox Amidative Dual Functionalizations of Alkenes
Abstract Here, we present a photocatalytic strategy for the intermolecular dual functionalizations of alkenes using N─O bifunctional reagents in an atom‐economic...
Molecularly Engineered Circular Additive with Multisite Desolvation for High‐Performance Zinc Ion Battery
Abstract Additive engineering can effectively relieve interface issues of aqueous zinc ion batteries (AZIBs), but most additives induce the sluggish interface ki...
Direct Synthesis of Vinylene‐Linked Conjugated Polymers by Selective Methyl/Methylene C─H Activation on Gold Surfaces
Abstract Vinylene (C═C) linkage facilitates the distribution of highly conjugated electrons along the polymer chain, thereby playing a crucial role in the development of conductive p...
In Situ/Operando Probing of Dynamic Phase Structures of Alumina‐Supported Ultrasmall Copper‐Gold Alloy Nanoparticles Under Reaction Conditions
Abstract The ability to control phase structures and surface sites of ultrasmall alloy nanoparticles under reaction conditions is essential for preparing catalysts by design. This is...
Dynamic Photoacoustic Imaging of Mobile Cu(II) in Vivo via Catalytic Radical Cation Formation
Abstract Copper dyshomeostasis is associated with various diseases, making in vivo spatiotemporal imaging of mobile Cu(II) dynamics crucial for understanding pathophysiological mecha...