Angewandte Chemie International Edition
Articles in this Issue
Unraveling the Impact of Organic Cation Dipole Moment on Rashba Spin‐Splitting in 2D Hybrid Organic–Inorganic Perovskites
Abstract Rashba spin‐splitting in hybrid organic–inorganic perovskites (HOIPs) holds great potential for spintronic applications. However, strategies for control...
Constructing Supported Metallic Pt Single Atoms in Molten NaAlCl <sub>4</sub>
Abstract Supported platinum‐group‐metal single‐atom catalysts (SACs) have garnered widespread attention in heterogeneous catalysis due to their theoretical 100%...
Regioselective Hydrocyanation of Internal Alkynes Enabled by a Transition‐Metal‐Free Dual‐Catalytic System
Abstract Since its discovery in 1954, the hydrocyanation of multiple carbon‐carbon bonds has emerged as a powerful strategy for the synthesis of nitriles. However, the elusive contro...
Correspondence on “Suppressing Energy Migration via Antiparallel Spin Alignment in One‐Dimensional Mn <sup>2+</sup> Halide Magnets with High Luminescence Efficiency”
Abstract The photoluminescence quantum yield (PLQY) of tetramethyl ammonium manganese(II) chloride, (CH 3 )...
An Atomically Dispersed Photocatalyst for Undirected <i>para</i> ‐Selective C─H Bond Functionalizations
Abstract Regioselective C─H bond functionalization is pivotal in modern scientific exploration, offering solutions for achieving novel synthetic methodologies an...
Zwitterion‐Modified NiFe OER Catalyst Achieving Ultrastable Anion Exchange Membrane Water Electrolysis via Dynamic Alkaline Microenvironment Engineering
Abstract The development of efficient nonprecious metal electrocatalysts for industrial anion exchange membrane water electrolysis (AEM‐WE) remains challenging,...
Scalable and Practical Electrooxidation of Electron‐Deficient Methylarenes to Access Aromatic Aldehydes
Abstract Aromatic aldehydes are pivotal synthetic intermediates with applications in fine chemicals, pharmaceuticals, agrochemicals, and advanced materials. Alth...
Recyclable Quasi‐Homogeneous Carbon Nitride Colloidal Catalyst for Sustainable Photocatalytic H <sub>2</sub> O <sub>2</sub> Generation
Abstract Graphitic carbon nitride (g‐C 3 N 4 ) photocatalysts have attracted grow...
Nature of Anti‐Dissipative High‐Energy Excited States in Quaterpyridine‐Bridged Ruthenium Complexes
Abstract High‐energy excited states with slow rates for internal conversion to the lowest‐energy excited state are prone to be intercepted before they dissipate...
Insight into the Carbon Monoxide Reduction Reaction on Cu(111) from <i>Operando</i> Electrochemical X‐ray Photoelectron Spectroscopy
Abstract In this work, we introduce a modified dip‐and‐pull electrochemical X‐ray photoelectron spectroscopy (ECXPS) approach that offers new mechanistic insight...
Transform the World through Chemistry
Automated Iterative N─C and C─C Bond Formation
Abstract Small molecule solutions to many contemporary societal challenges await discovery, but the artisanal and manual process via which this class of chemical...
An Immobilized Rh‐Based Solid Molecular Catalyst for the Reductive Hydroformylation of 1‐Octene
Effect of Ambient Organic Acids on the Water Structure at TiO2${\rm TiO}_{2}$ Interfaces
Abstract A molecular‐level understanding of the effects of ambient organic compounds on the wettability of titanium dioxide () surfaces is relevant to many of its energy‐related and...
Fortification of FeS Clusters Reshapes Anaerobic CO Dehydrogenase into an Air‐Viable Enzyme Through Multilayered Sealing of O <sub>2</sub> Tunnels
Abstract The inherent O 2 sensitivity of Ni─Fe carbon monoxide dehydrogenases (CODHs), crucial for rapid CO to CO...
A Bidirectional Ion Kinetic Regulator Suppressing Lithium Dendrites in Advanced Lithium‐Sulfur Batteries
Abstract Liquid organic electrolytes (LOEs) are of crucial significance in secondary battery deposition processes. Based on Sand's time formula, this study propo...
Electrolytes with Tailored Solvent–Solvent Interactions for Flame‐Retardant Stable Sodium‐Metal Batteries.
Abstract Sodium metal batteries (SMBs), which possess abundant sodium resources and high energy density, have attracted widespread attention. However, the contin...
Controlling Asymmetry Amplification Through Supramolecular Polymorphism
Abstract Supramolecular polymorphism has recently emerged as a powerful concept, enabling a single chemical entity to form distinct, stable assemblies in solutio...
Backbone Protecting Groups for Enhanced Peptide and Protein Synthesis
Abstract Solid‐phase peptide synthesis has become an indispensable technique for the routine preparation of linear peptides of up to approximately 40 amino acids...
Trigonal Planar <i>Bis</i> (carbene)Cu(I) Complexes Enable Divergent H <sub>2</sub> Activation with H <sub>2</sub> O for Accelerated Olefin Hydrogenation
Abstract CuH‐catalyzed olefin hydrogenation is rare compared to those of carbonyl‐derived substrates. Olefin insertion into Cu–H to form Cu‐alkyl is ubiquitous;...
Synthesis and Physical Properties of [ <i>n</i> ]Cycloparaphenylene Ketone ( <i>n</i> = 6, 7, 8, and 10)
Abstract [ n ]Cycloparaphenylene ketone 4 , [ n...
Si─O Molecular Engineering Enhances Cathode‐Anode Interface Stability for High‐Loading and High‐Voltage Layered Cathode‐Lithium Metal Batteries
Abstract Nickel‐rich layered cathodes and lithium metal anode are promising for the next generation high‐energy‐density batteries. However, the unstable electrod...
Visible‐Light‐Driven Selective Mineralization of Organohalides on Spatially Close Au Single‐Atom and Nanocluster Neighbors Over Poly(Heptazine Imides)
Abstract Organohalides are commonly found pollutants with long‐term persistence in industrial wastewater and drinkable water. Although these pollutants only cons...