Angewandte Chemie International Edition

Near‐Infrared Biosensing of Drug‐Induced Cell‐Heterogeneous Injuries with an Ultrahigh Turn‐On Ratio

Abstract Fluorescence probes of reactive oxygen species in the near‐infrared (NIR) spectral region, i.e., 800 nm and beyond, are desired for in vivo biosensing,...

Inside Front Cover: A Bidirectional Ion Kinetic Regulator Suppressing Lithium Dendrites in Advanced Lithium‐Sulfur Batteries

Absolute Asymmetric Synthesis of a Homochiral Polymer from an Achiral Monomer

Abstract A compelling hypothesis for the origin of homochirality that led to the origin of life is that a chiral informational polymer, formed somehow from achiral monomers, biased t...

Efficient Harvesting of Triplet Excitons via a T ₁ ‐Blocked TADF Mechanism in Series MOFs for Optimal X‐ray Detection and Imaging

Abstract Scintillators play vital roles in fields such as medical imaging, high‐energy physics, astronomy, and radiation monitoring. Their operational principle,...

Photothermal CuS as a Hole Transfer Layer on BiVO ₄ Photoanode for Efficient Solar Water Oxidation

Abstract Sluggish hole transport kinetics are one of the key limitations of bismuth vanadate (BiVO 4 ) photoanodes in pho...

Axial‐N Induced Square‐Pyramidal Crystal Filed of Atomically Iron Sites for Enhancing Acidic Oxygen Reduction

Abstract Atomically dispersed Fe‐based catalyst represents a promising alternative to platinum for the oxygen reduction reaction (ORR). However, the prevalent Fe...

A Nitrogen‐Containing Graphenic Buckybowl for Photocatalysis and Assembly With Fullerenes

Abstract A nitrogen‐containing graphenic buckybowl (3N‐HBC) has been synthesized through pentagonal cyclization at the bay positions of hexa‐...

Mediating Solid Electrolyte Interphase Formation Kinetics on SiO <i> _x </i> Anodes Using Proton Acceptors

Abstract Silicon (Si)‐based anodes offer high energy density but suffer from significant volume variations, leading to an unstable solid electrolyte interphase (SEI). To enhance SEI...

Laser‐Induced Nanoscale Engineering of Iridium‐Based Nanoparticles for High‐Performance Oxygen Evolution

Abstract While ruthenium oxide exhibits higher activity, it suffers from significantly lower stability in the acidic oxygen evolution reaction (OER). In contrast...

Frontispiece: Deciphering and Predicting Thermal and pH Stabilities of Triplex DNA Under Multifactorial Conditions

Frontispiece: Mechanoactivated Celite as a Catalyst for C‒H Bond Perfluoroalkylation and Other Radical Reactions

Desolvation‐Induced Network Reformation and Cracking in the Single Crystals of Hydrogen‐Bonded Frameworks Composed of Tetraazaanthraquinone and Anthraquinone Derivatives

Abstract A molecular‐level understanding of how structural transformations induce morphological changes in organic crystals is essential for developing flexible...

On‐Surface Synthesis and Characterization of Tetraazanonacene

Abstract Isosteric replacement of CH units of acenes by nitrogen induces significant changes in their electronic, redox, and spectroscopic properties. Here, we describe the on‐surfac...

Electronic Structure Modulation of Nb ₂ O ₅ by Ru Single Atoms Enabling Efficient Hydrogen Storage of Magnesium Hydrides

Abstract Magnesium hydride (MgH 2 ) is a promising solid‐state hydrogen storage material due to its high capacity and low...

[TeSeS ₂ ] ²⁻ : The First Heterotriple‐Chalcogenide Motifs Decode Giant Mid‐Far Infrared Birefringence

Abstract Optical anisotropy, a cornerstone of polarization control, presents fundamental challenge in functional optical material design due to the intricate int...

A Universal Metal Ion‐Targeting Coordination Strategy for Precise Synthesis of Heteronuclear Dual‐Atom Electrocatalysts for Oxygen Reduction

Abstract Heteronuclear dual‐atoms catalysts (DACs) represent an emerging frontier in heterogeneous catalysis due to maximum atom utilization and synergistic cata...

Reduction‐Induced C─C Cleavage and Site‐Specific Hydrogenation of a Highly Strained Bilayer Spironanographene

Abstract The chemical reduction of a bilayer spironanographene, spiro‐NG (C 137 H...

Chiral Supramolecular Clamps for the Passive Cell Diffusion of DNA and siRNA

Abstract The safe and effective delivery of DNA and RNA therapeutics continues to be a major hurdle toward personalized medicine, mainly due to the digestion of this genetic material...

Multifunctional and Radii‐Matched High‐Entropy Engineering Toward Locally‐Regulable Metal Oxide Layers in Sodium‐Layered Oxide Cathode

Abstract Layered oxides, one of the most fascinating cathodes for sodium‐ion batteries (SIBs), have appropriate voltage window and feasible preparation process,...

Identifying the Role of Pt Active Species in CO‐Sensitive Photocatalytic H ₂ Evolution

Abstract Platinum (Pt) has been widely employed in photocatalytic H 2 production. However, the influence of CO on proton...

Internally BN‐Doped Coronene

Abstract We present the first synthesis of internally BN‐doped coronenes ( B2N2‐C , H‐B2N2‐C...

Interplay Between Stereochemically Active Lone Pair Repulsions, Sigma Hole Interactions, and Delocalized Redox Processes in Topochemical Fluoride‐Ion Insertion

Abstract Topochemical insertion/extraction of cations has emerged as a generalizable strategy for modulating the crystal and electronic structure of periodic sol...

π‐Electron Donation at the Sulfoximidoyl Nitrogen Atom

Abstract Knowledge of the physicochemical properties and the reactivity of functional groups is invaluable in organic chemistry. Although substantial understandi...

A Structure‐Preserving, Dimensionality‐Increasing Strategy for the Stepwise Synthesis of Microporous α‐MoO ₃ with a Broad (100) Surface

Abstract Metal oxides with diverse structures and dimensionalities are typically synthesized via solid‐state or hydrothermal reactions. However, it is quite diff...

A Combined Aptamer Pulldown‐DNAzyme Cleavage Assay for Intact Methicillin Resistant <i>Staphylococcus aureus</i> Cells

Abstract Accurate and convenient detection of methicillin resistant Staphylococcus aureus (MRSA) plays a vital role in de...