Angewandte Chemie International Edition
Articles in this Issue
Azine‐Pyridine Frame Generated Covalent Organic Frameworks and Self‐Polymerized Films
Abstract Engineering covalent organic frameworks (COFs) into industrializable films with inherent functionalities has remained a major challenge in synthetic che...
Si/Carbon‐dots with Surface N‐C Sites Promoting Proton and Electron Transfers in Oxygen Reduction Reaction
Abstract The oxygen reduction reaction (ORR) can proceed through either a two‐ or four‐electron pathway, both of which are important for a wide range of applicat...
Zwitterionic Heavier Pnictinidenes in Redox Catalysis
Abstract Herein, we describe a new class of zwitterionic heavier pnictogen species with bis ( N...
Chemically Recyclable Alternating Poly(thioether <i>‐alt</i> ‐ester)s with Tunable Properties Enabled by Substitution Effects and Stereochemistry
Abstract The development of innovative poly(ether‐ester)s with perfectly alternating ether and ester functionalities to overcome the trade‐offs between the polym...
Polyolefin‐based Multiblock Copolymers from Cascade ROMP‐RAFT Polymerization
Abstract Plastic disposal has become a serious environmental and social problem. Mechanical recycling of waste plastics is the most widely adopted strategy to address this issue, but...
Frank Tambornino
Modular Access to P(V)‐Stereogenic Compounds via Cu‐Catalyzed Desymmetrization of (Thio)Phosphonic Dichlorides
Abstract Chiral phosphorus(V) centers—particularly those bearing fully heteroatom‐substituted frameworks—are key stereochemical motifs in pharmaceuticals, nucleic acid therapeutics,...
Merging One‐ and Multi‐Photon Processes in Hydrogen‐Bonded Organic Frameworks for Enhanced NIR Light‐Driven Photothermal and Photochemical Conversions
Abstract Direct application of near‐infrared (NIR) light for solar‐thermal and solar‐chemical conversions is of emergent interest to improving efficiency in sola...
Tunable Oxygen Vacancy Clusters Enhanced Catalytic Activity of CeO <sub>2</sub> Nanorods on CO <sub>2</sub> Cycloaddition
Abstract Constructing heterogeneous halogen‐free catalysts featuring efficiently activated CO 2 and epoxides for the synt...
Encapsulating Ionophores in Zeolite Imidazolate Framework‐8 for Long‐Term Monitoring of Ion Fluctuations in Living Rat Brain
Abstract Various ions in the brain (e.g., H + , K + , and Ca...
Surface Engineering of Hollow Microreactors with Catalytic Nanobrushes for Orthogonal Tandem Catalysis
Abstract Micro/nanoreactors with hollow structures have traditionally focused on the design of the internal catalytic microenvironment, while precise engineering...
Enantioselective Nickel‐Catalyzed Hydrogenation of α‐Alkylidene Succinimides Enabled by Weak Noncovalent Interactions
Abstract The development of asymmetric hydrogenation catalysts based on Earth‐abundant metals presents a sustainable alternative to efficient but resource‐limite...
Sequential Reconstruction of Calicheamicin γ <sub>1</sub> <sup>I</sup> Iodo‐Thiobenzoate by Selective Carrier Protein Trapping Reveals a Flavin‐Dependent Iodinase
Abstract Flavin‐dependent halogenases (FDHs) play important roles in natural product biosynthesis, particularly chlorinases and brominases. Apart from ubiquitous...
Engineering Unspecific Peroxygenases for Enantioselective α‐Hydroxylation of β‐Ketoesters
Abstract Unspecific peroxygenases (UPOs) are promising biocatalysts for selective oxyfunctionalization. Compared to cytochrome P450 enzymes (P450s), the catalyti...
Highly Efficient Circularly Polarized Phosphorescence from Isolated Molecules Through Intermolecular Interactions
Abstract Organic room‐temperature phosphorescence with circularly polarization feature attracts considerable attentions owing to its unique exciton and photon properties. However, ac...
Three‐Dimensional Porphyrin and Phthalocyanine‐Based Covalent Organic Frameworks for Boosting Urea Oxidation
Abstract Porphyrin and phthalocyanine‐based covalent organic frameworks (COFs) have emerged as versatile scaffolds for developing high‐performance photo‐ and ele...
Regioreversed Carbosulfenylation of Fluoroalkenes via Nickel‐Mediated Radical Sorting
Abstract Carbosulfenylation of olefins represents an important class of reactions for the synthesis of structurally diverse organosulfur compounds. Previous stud...
Self‐Healable Poly(ionic liquid) Copolymers Driven by Polar and Dipolar Forces
Abstract Commodity aliphatic and aromatic acrylic‐based copolymers self‐heal due to ubiquitous key‐and‐lock ,...
Synthesis of a Linear Tetraboron Cation via Deprotonation of a Nonsupported Dimeric Hydroborylborenium Ion
Abstract The nonsupported B–H–B moiety of a dimeric hydroborylborenium ion can be readily deprotonated by 4‐(dimethylamino)pyridine, affording a H‐bridged linear...
AM‐DMF‐ddRPA: an All‐in‐One Digital Microfluidic Platform for Rapid and Automatic Digital Nucleic Acid Analysis
Abstract Accurate nucleic acid quantification analysis (NQA) is crucial for disease treatment and prevention. However, existing digital NQA methods often lack sufficient automation a...
Frontispiece: Regiodivergent Photocatalytic Annulation for the Synthesis of <i>gem</i> ‐Difluorinated Cyclic Hydrocarbons
Efficient Separation of Methanol‐to‐Olefins Products Using a Robust Polycatenated Hydrogen‐Bonded Organic Framework
Abstract The methanol‐to‐olefins process produces mixtures of ethylene and propylene, driving demand for high‐performance separation materials. We present HOF‐ZJ...
Coherently Coupled Frustrated Lewis Pairs in In <sub>2</sub> O <sub>3−</sub> <i> <sub>x</sub> </i> Nanoclusters for Selective CO <sub>2</sub> Photoreduction to CH <sub>4</sub>
Abstract Co‐catalysts integration presents unique opportunities to enhance photoactivity, yet selectivity control and mechanistic understanding within multistep...
Dynamic Active Site Evolution in Lanthanum‐Based Catalysts Dictates Ethane Chlorination Pathways
Abstract Radical‐mediated chlorination of ethane presents a low‐carbon alternative for polyvinyl chloride (PVC) synthesis, yet selectivity toward 1,2‐dichloroeth...