Angewandte Chemie International Edition
Articles in this Issue
Transition Metal Atom–Cluster Synergistic Modification with Tuned d‐band Center Imparts Longevous Potassium Metal Anodes
Abstract The tailored nucleation and growth of potassium metal over a current collector is essential to realize longevous potassium metal anodes. The commercial current collector lac...
Regiodivergent Photocatalytic Annulation for the Synthesis of <i>gem</i> ‐Difluorinated Cyclic Hydrocarbons
Abstract Regiodivergent synthesis is a powerful strategy for expanding chemical space. Given the significance of fluorine‐containing molecules in pharmaceutical...
Length Ratio‐Driven Configurational Modulation of Heteroleptic Pd <sub>6</sub> L <sub>6</sub> L’ <sub>6</sub> Cages
Abstract Biomolecular configurational modulation is essential for maintaining the stability and functionality of biological systems. Drawing inspiration from thi...
Angularly Resolved Tip‐Enhanced Raman Spectroscopy
Abstract Despite intensive research in tip‐enhanced Raman spectroscopy (TERS), the angular distribution of Raman scattering in the TERS gap remains experimentall...
Cyclo‐Octasulfur Crystals as Light‐Controlled Molecular Muscles
Abstract Here, we describe the synthesis and photo‐responsive properties of 2D cyclo‐octasulfur microcrystals (α‐ S8 MCs)...
MXene‐Supported Ru–Ni: A Common Active Site for Hydrolysis, Hydrogen Oxidation, and Hydrogenation
Abstract Insights into the activation and conversion of hydrogen using a single‐mode catalyst are crucial for advancing fuels and fine chemical production. In th...
Sustainable Closed‐Loop Recycling of Polyester Waste Using Reconstructed Defective‐Metal–Organic Frameworks
Abstract Chemical recycling of polyester waste presents a promising strategy for achieving a sustainable circular economy. However, the development of efficient,...
Controlled Electrocatalytic Glycerol Upgrading to Glyceraldehyde in Near Neutral Media by Cobalt Oxide Lattice Activation
Abstract Electrocatalytic upgrading of biomass‐derived glycerol driven by renewable electricity offers a greatly attractive green way to produce value‐added chem...
Reactivity of a Methylene‐Bridged 1,3‐Bis(germylene) in Dynamic Equilibrium with Its Dimer
Abstract We report the properties and reactivity of an unprecedented methylene‐bridged 1,3‐bis(germylene) derivative. In the solid state, it undergoes dimerizati...
Tunable Thermally Activated Delayed Fluorescence from Supramolecular Polymers Toward Application in Aqueous Media
Abstract Thermally activated delayed fluorescence (TADF) offers great potential for application in light emitting devices and bioimaging. Supramolecular polymers can offer intriguing...
Operando XAFS Deciphering Dynamic Evolution of Heteronuclear Cu–Ni From Atomic Sites to Atomic Clusters for Enhanced CO <sub>2</sub> Electroreduction
Abstract Revealing the dynamic evolution of atomic‐level active sites during catalytic reactions is critical for identifying true catalytic centers and optimizin...
High‐Capacity and Long‐Life Cathode Constructed Solely by Carbon Dots for Aqueous Zinc‐Ion Batteries
Abstract Carbon dots (CDs) have been explored widely in the electrochemistry field, owing to their unique structures and rich properties. However, in the reporte...
Electrocatalytic C─S Cross‐Coupling via Engineered Frustrated Lewis Acid‐Base Pairs for High‐Efficiency Methanesulfonate Synthesis
Abstract The electrochemical synthesis of sulfonyl compounds under mild conditions remains a significant challenge due to the reliance on harsh reagents, high en...
Highly Oxygen‐Tolerant and Self‐Adaptive Surface‐Initiated Bimetal‐Mediated Controlled Radical Polymerization
Abstract We report herein a self‐adaptive surface‐initiated bimetal‐mediated controlled radical polymerization (SI‐BMCRP) for fabricating various polymer brushes using microliter vol...
Multiactivity of Nanozyme Liposome Regulates the Homeostasis of Biochemical Microenvironment
Abstract In living systems, cascade reactions involving multiple enzymes, critical for regulating the biochemical microenvironment's homeostasis, are essential t...
Blood Retention and Kidney Clearance of Renal‐Clearable Gold Nanoparticles Strongly Correlate with Renal Injury Biomarkers
Abstract Renal‐clearable engineered nanoparticles are typically filtered through the glomeruli and transported along the renal tubules before entering the bladde...
Transforming Single‐Atom Site to Dual‐Atom Site in Fe–N–C Catalysts: A Universal Strategy for Enhancing Durability in Proton‐Exchange Membrane Fuel Cells
Abstract Fe–N–C catalyst is the most promising non‐noble metal oxygen reduction catalyst for proton‐exchange membrane fuel cells (PEMFCs); however, their practic...
Visible Light‐Driven Deracemization of Cyclic Sulfonamides by Quinuclidine and Chiral Arylthiol Catalysis
Abstract A photocatalytic system comprising an achiral tertiary amine and a chiral C 2 ‐symmetric ary...
Spatiotemporal Regulation in Porous Organic Cage Salt–Metal Cluster Hybrids for Efficient Orthogonal Tandem Catalysis
Abstract Developing artificial biomimetic catalysts with precise spatiotemporal control remains challenging. Here, we present a pH‐responsive organic cage salt c...
Resiquimod‐Induced Nanovaccine (RINV) for Personalized Cancer Immunotherapy
Abstract Cancer nanovaccines have emerged as a promising modality for cancer immunotherapy due to their capability of eliciting robust tumor‐specific immune responses. However, struc...
Dual Chemical Scissors Strategy Enables 1D Antimony Selenates with Ultraviolet Nonlinear Optical Properties
Abstract The rational, function‐driven design of advanced inorganic functional materials remains a significant challenge, primarily attributed to their inherentl...
Exploring Mesoionic Imine‐Carbodiimide (MII‐CDI) Adducts: 1,3 H‐Shift, N(I) Compounds and Guanidinate‐Type Ligands
Abstract In this study, we report our recent findings on the synthesis and reactivity of a novel 1,2,3‐triazolin‐5‐imine‐type mesoionic imine‐carbodiimide (...
First Chiral Catalan Solid Based on Molybdenum Halide with Efficient Circularly Polarized Luminescence in the Deep‐Red Region
Abstract The design of novel chiral metal halides with exceptional chiroptical properties has attracted significant research attention due to their potential app...
Ligand‐Controlled Chemoselectivity in the Rhodium‐Catalyzed Synthesis of Pentafulvenes via (2 + 2 + 1) Alkyne Cyclotrimerization
Abstract The synthesis of pentafulvenes with varied substituents has been efficiently achieved using novel rhodium‐based catalysts via (2 + 2 + 1) alkyne cyclotrimerization. A ration...
“Outside‐in” Design of Single‐Atom Catalysts: Linking Specific Peripheral Geometry to Defined CO <sub>2</sub> Reduction Performance
Abstract The regulation of single‐atom catalyst (SAC) through microenvironment engineering, particularly via peripheral species, has recently garnered significan...