Angewandte Chemie International Edition
Articles in this Issue
Reductive N <sub>2</sub> Cleavage and Nitride Insertion Reactivity at Molybdenum Complexes Supported by a Rigid PNP Pincer
Abstract Metal‐nitride species represent key reactive intermediates in reductive N 2 cleavage and functionalization. Towa...
Unlocking the Power of Lewis Basicity in Oxide Lattice Oxygens: A Regulating Force for Enhanced Oxygen Evolution Kinetics in Li‐O <sub>2</sub> Batteries
Abstract Lithium‐oxygen batteries (LOBs) require fast oxygen conversion kinetics to achieve good cycling performance and high energy efficiency. In the text of c...
Boosting Performance of Quasi‐Solid‐State Zinc Ion Batteries via Zincophilic Solubilization
Abstract Hydrogel electrolytes hold great promise in tackling severe issues facing aqueous zinc‐ion batteries (AZIBs). However, to satisfy the quest of flexible...
Nuclear Quantum Confinement Enables Robust Deuterium Bonds for Highly Reversible Aluminum Anodes
Abstract The hydrogen evolution reaction (HER) fundamentally limits aluminum electroreduction in aqueous electrolytes by dominating interfacial charge transfer....
Solution‐Processed Amorphous Zero‐Dimensional Organic Metal Halide Hybrid Films for Direct X‐Ray Detectors
Abstract Zero‐dimensional (0D) organic metal halide hybrids (OMHHs) are emerging materials with significant potential for optoelectronic applications, including...
Vacancy‐Induced Atomic Diffusion in a Molecular Metal Cluster Complex
Abstract The presence of atomic vacancies in a close‐packed material is believed to allow the migration of atoms adjacent to the vacancies, which induces dynamic...
Photocatalytic Reduction of CO <sub>2</sub> to CO in 100%: The Synergistic Effect of Nickel and Europium in Heterometallic Clusters
Abstract Heterometallic transition‐rare earth metal (3d‐4f) clusters with synergistic catalytic activity are rarely identified. Herein, two families of closely r...
Tandem‐Activatable PROTAC Prodrug for Tumor Biomarker‐Driven Near‐Infrared Opto‐Proteolysis
Abstract Tumor‐specific protein degradation is crucial for successful cancer treatment by proteolysis‐targeting chimera (PROTAC), which however still remains cha...
Chiral Cryptographic Key‐Based Fluorescence Encryption Enabled by Stimuli‐Responsive Metal–Organic Frameworks
Abstract Increasing threats of data forgery breaches necessitate the development of advanced encryption strategies beyond traditional cryptographic methods. Fluorescence encryption h...
Design Strategy for Small‐Molecule Organic Cathodes: Regulated Active Groups Enable High Capacity and Voltage in Aqueous and Seawater Aluminum Ion Batteries
Abstract Organic materials demonstrate significant potential as electrodes for aqueous batteries, owing to their high theoretical capacity, structurally tunable...
Optimizing Bromine Complexation and Kinetics: a Bisimidazole Strategy for High‐Performance Zn‐Br Static Batteries
Abstract Zinc–bromine (Zn–Br) static batteries are promising for large‐scale energy storage, yet the practical application is hindered by the long‐standing trade...
Selection of Ribofuranose‐Isomer Among Pentoses by Phosphorylation with Diamidophosphate
Abstract The unique structure–function relationship of the ribofuranose ring in RNA has inspired various chemical pathways to select for the ribofuranose form (over the ribopyranose...
Orthogonal Multiple Hydrogen Bonds of Nucleobases Enable Precise Tunability of DNA‐Polymer Nanostructures
Abstract DNA‐polymer nanostructures manifest enhanced stability and chemical diversity for various applications such as sensing, imaging, and immune modulation. However, the function...
From Corrosion to Creation: Interfacial De‐Electronation Drives Hydrogenation‐Energy Symbiosis
Abstract Metal corrosion, conventionally perceived as a destructive phenomenon driven by de‐electronation, imposes significant economic burdens and safety hazard...
Lignin‐Derived Polyanionic Crosslinked Gel Interfacial Layer with Ion‐Sieving and Ion‐Regulating Capabilities for Dendrite‐Free Zinc Anodes
Abstract The severe side reactions and rampant dendrite growth on the zinc (Zn) electrode significantly hinder the practical applications of aqueous zinc‐ion bat...
Unveiling the Influence of Cyanogen Vacancies in Prussian Blue for Sodium‐ion Batteries
Abstract Prussian blue (PB), recognized as a promising cathode material, has gained significant attention for sodium‐ion batteries due to its high theoretical energy density, low cos...
Frontispiece: Reduction of CO <sub>2</sub> Accompanying ATP Synthesis in Polydopamine Microreactors Covered by Lipid Bilayers with ATPase
Ultrathin PtSe <sub>2</sub> Nanowires in Single‐Walled Carbon Nanotubes for Hydrogen Evolution Reaction
Abstract Platinum selenide (PtSe 2 ) has shown great potential for application in electrocatalysis. One‐dimensional (1D)...
Frontispiece: Merging Photocatalysis with Chiral Lewis Acid Catalysis for Enantioselective Hydrosilylation/Hydrogermylation of Electron‐Deficient Alkenes
A Phenomenological Symmetry Rule for Chemical Reactivity Under Vibrational Strong Coupling
Abstract Symmetry is known to strongly influence the course of a chemical reaction. It has also been found to play a key role in vibrational strong coupling (VSC), where it can influ...
A Single‐Molecule Junction Based on a Covalent Organic Cage
Abstract As the applications of molecular cages hinge on their properties, understanding the true nature of the cage structures is imperative. Single‐molecule co...
Orbital Coupling‐Engineered Coordination‐Unsaturated CuAg Nanochains Drives Spontaneous Electrocatalytic Acetylene Semihydrogenation and Zn‐C <sub>2</sub> H <sub>2</sub> Batteries
Abstract Electrocatalytic semihydrogenation of acetylene (C 2 H 2 ) offers a mild...
Synthesis of a Library of <i>N</i> ‐monofluoromethyl Compounds from <i>N</i> ‐monofluoromethyl Carbamoyl/Thiocarbamoyl Fluorides
Abstract The distinctive chemical properties of fluorine atoms have enabled fluorine‐containing compounds to make significant strides in the pharmaceutical and m...
Strain‐Release Driven Arsenium Ion Bond Insertion
Abstract Although it marks a cornerstone of pnictogenium ion [R 2 Pn] + reactivit...
In Situ Electrochemical Reconstruction of Cation‐Vacancy‐Enriched Ni@Ni <sub>2</sub> P Particles in Hollow N‐Doped Carbon Nanofibers for Efficient Nitrate Reduction
Abstract Electrochemical nitrate (NO 3 − ) reduction to ammonia (NH 3...