Angewandte Chemie International Edition
Articles in this Issue
Chiral Aza‐Helicene Phosphonic Acids for Stabilizing Efficient Perovskite‐Silicon Tandem Solar Cells
Abstract The popular planar carbazole‐based hole‐selective self‐assembled molecules (SAMs) for perovskite solar cells (PSCs) suffered from intrinsic instability...
Light‐Gated Amine Exchange in Diarylethene‐Crosslinked Microgels
Abstract The functionalization of microgels with photoswitchable moieties enables the construction of multi‐responsive systems, which are highly interesting for...
Direct Production of Cyclohexanones from Lignin via Chlorine‐Mediated Catalytic Hydroprocessing
Abstract Cyclohexanones, as critical biopolymer precursors, could be produced from lignin yet rarely reported due to the formidable challenge of simultaneously r...
Bimolecular Synergy Reshapes the Interfacial Reactivity of Wide‐Bandgap Perovskites
Abstract Wide‐bandgap (WBG) perovskites have garnered significant attention owing to their extensive applicability in tandem photovoltaic devices. However, the c...
Synergistic Enhancement of Photocatalytic Hydrogen Evolution in Covalent Organic Frameworks via Isoreticular Design, Isomerism, and Protonation
Abstract Rational structural engineering of covalent organic frameworks (COFs) has significantly advanced their application in photocatalytic hydrogen evolution...
Direct Synthesis of Amino Acids from Plastic, Air, and Water
Abstract Amino acids as fundamental building blocks exhibit versatile applications spanning from food science to pharmaceutical development. Conventional biologi...
Impacts of the Conductive Networks on Solid‐State Battery Operation
Abstract The micromorphology of composite cathodes is known to play a vital role in determining all‐solid‐state battery (ASSB) performance. However, much of our...
Modulating Ion‐Dipole and Dipole–Dipole Interactions for Stable Wide‐Temperature‐Range Lithium–Sulfur Batteries Enabled by Quantum‐Dot Catalysts
Abstract The incomplete conversion of sulfur species, particularly the pivotal intermediate solid Li 2 S...
Electrochemical Upgrading Plastic to Organosulfurs Through Fe‐N <sub>3</sub> Single Atom Catalyst Under Ambient Conditions
Abstract Cycling and electrochemical upgrading of plastics present a sustainable approach to transforming waste into high‐value chemicals, yet the focus has pred...
Metabolic Engineering of the 5‐Aminolevulinate Biosynthetic Pathway in <i>E. coli</i> Improves Efficiency of Hemoprotein‐Based Biocatalysis
Abstract Biocatalysis using heme‐dependent enzymes provides a powerful synthetic platform to facilitate a variety of chemical transformations required for organi...
Toward Stable Zinc Anode: An AI‐Assisted High‐Throughput Screening of Electrolyte Additives for Aqueous Zinc‐Ion Battery
Abstract Currently, challenges such as zinc dendrites, hydrogen evolution reactions, and byproduct formation on the zinc anode damage the performance and cycling stability of aqueous...
Light‐Fueled Non‐Photoisomerized Dissipative Self‐Assembly System Through Transient Radical‐Radical Interactions
Abstract Living organisms inspire intensive exploration of artificial dissipative systems under far‐from‐equilibrium thermodynamics. Light, as an ideal fuel form...
Divergent Synthesis of ΔAA‐Peptides Using a Bioorthogonal <i>pro</i> ‐Amino Acid and Aqueous Flavin Photocatalyst: Green Light Enhances Catalyst Performance and Product Selectivity
Abstract Dehydroamino acids (ΔAAs) are vital building blocks in the design and optimization of peptide drugs. The exact olefin geometry, side chain chemotype, an...
Targeted Discovery and Characterization of Type‐II PKS‐NRPS Hybrid DNA‐Alkylating Antibiotics
Abstract DNA alkylating natural products usually exhibit diverse bioactivity and serve as a crucial source of drug leads. Here, we employed genome mining guided...
Fragment‐Based Drug Discovery of Novel High‐affinity, Selective, and Anti‐inflammatory Inhibitors of the Keap1‐Nrf2 Protein‐Protein Interaction
Abstract Activating the cytoprotective response of nuclear factor erythroid 2‐related factor 2 (Nrf2) can reduce oxidative stress and inflammation. A promising s...
Anisotropic Second‐Harmonic Generation in Chiral Hybrid Palladium Halides
Abstract Chiral hybrid metal halides (HMHs) have attracted considerable attention due to their promising application in various optoelectronic devices. In this w...
Photocatalytic Synthesis of Unprotected Sulfonimidamides and Their Application in Photochemical Nitrene Transfer Reactions
Abstract The selective incorporation of nitrogen into organic molecules remains a central challenge in modern synthetic chemistry, particularly when aiming to access complex, functio...
Impact of Coordination Environment for Designing Ru‐Based Alloy Catalysts for Ammonia Decomposition
Abstract Alloying is an effective strategy to modulate a metal catalyst's electronic structure and optimize its performance, but developing a fundamental design principle has been ch...
Frontispiece: An Electrochemical Study of Key Catalytically Active Gold Complexes
Hydrothermal Processing as an Effective Strategy for Producing Coordinated Non‐Aromatic Hydrogels With Persistent and Reversible UV‐Activated Room‐Temperature Phosphorescence
Abstract The development of non‐aromatic hydrogels with unique persistent room‐temperature phosphorescent (RTP) through simple preparation methods remains a great challenge. Here, we...
Pt Colloidosomes with Broadband Absorption for Near‐Infrared Light Photocatalysis Through D‐Band Hot‐Carriers Generation
Abstract Interband and intraband electronic excitations in transition metals as nanocatalysts are crucial for the generation of hot carriers. Unlike the well‐kno...
Locked Nucleic Acid Modification for Base‐Stacking Engineering of Self‐Assembled DNA Crystals
Abstract DNA hybridization and assembly processes are governed by the concerted effects of Watson–Crick pairing and base‐stacking interactions. While sequence engineering and chemica...
Design of Carbon–Carbon Ylides
Abstract Here, we have reported the computational design of a new class of ylides, elusive carbon–carbon ylides featuring zwitterionic σ‐bonds, derived from the...
Highly Selective Adsorption of Para‐Xylene, Ethylbenzene, and Explicit Exclusion of Ortho‐Xylene from Xylene Isomers Using a Pillar‐Layered MOF with Tuned Pore Channels
Abstract Xylene isomer separation is a long‐standing challenge due to the nearly identical properties of para‐xylene (PX), meta‐xylene (MX), ortho‐xylene (OX), a...