Angewandte Chemie International Edition
Articles in this Issue
Quantitative Super‐Resolution Imaging of On‐Origami DNA Conformation and Reactivity Under Electric Fields
Abstract Self‐assembled DNA nanostructures have been popularly used to develop DNA‐based electrochemical sensors by exploiting the nanoscale positioning capability of DNA origami. Ho...
Electronic Structure Reconfiguration of Zn‐N <i> <sub>x</sub> </i> B <sub>4‐</sub> <i> <sub>x</sub> </i> Sites for Enhanced Fenton‐Like Catalysis
Abstract Despite growing interest in single‐atom catalysts (SACs) for Fenton‐like reactions, zinc (Zn)‐based SACs remain unexplored due to the inherent inertness...
Catalysis of Radical Coupling Reaction via Synergistic Action of Oriented External Electric Field and Light Irradiation
Abstract Radical coupling reactions have been widely used in the synthesis of complex organic molecules, materials science, and drug research. However, restricted conditions or speci...
Enantioselective Incorporation of Amine Fragments onto Quaternary Carbons via Metallaphotoredox Catalysis
Abstract The enantioselective construction of quaternary carbon stereocenters bearing amine functionalities represents a significant challenge in organic synthesis despite their prev...
Phenylamine‐1,2‐Dioxetanes: Promising Class of Chemiluminescent Luminophores for Aqueous Sensing and Bacterial Detection
Abstract Chemiluminescence offers distinct advantages for bioimaging and sensing, notably by eliminating the need for external light excitation and minimizing ba...
Disordered Inverse Photonic Beads Assembled From Linear Block Copolymers
Abstract Structurally colored colloids, or photonic pigments, offer a sustainable alternative to conventional dyes, yet existing systems are constrained by limit...
Frontispiece: Tailor‐Made Host–Guest Organic–Inorganic Hybrid Antimony Halide Enables Efficient Light‐Emitting Diodes
Cold‐Captured Dynamic Hydration Networks in Oxime‐Based Photoswitches: A Theoretical Challenge Uncovered by Rotational Spectroscopy
Abstract With the goal of manipulating (bio)chemical processes, photoswitches emerge as important assets in molecular nanotechnology. To guide synthetic strategies toward increasingl...
Efficient Carrier Separation via Ru@TS@C Zeolite: Enabling Photo‐Cathodes for High‐Efficiency Photo‐Assisted Metal−Air Batteries
Abstract Neutral aqueous Zn−air batteries (ZABs), while promising for extended lifespans and recyclability compared to alkaline systems, are hindered by sluggish...
Frontispiece: Redefining the Coordination Mode of 1,2,4‐Triazolylidene: Bridging the Gap Between Molecular Organometallic Chemistry and Extended Porous Architectures
Amorphous Silica Induced Loose CeO <sub>2</sub> Clusters with Isolated Pt Atoms for Efficient Reverse‐Water Gas Shift Reaction
Abstract Pt‐based catalysts exhibit extraordinary potential in reverse‐water gas shift (RWGS) reactions, but often fail to possess a high reaction rate and high...
Jacob J. Lessard
Photoactivatable Synthetic Exosomes for RNA‐Based Communication Between Artificial Cells and Living Cells
Abstract Artificial cells are self‐assembled microstructures engineered to replicate the functions of natural cells, such as the capacity to interact and communicate. Until now, comm...
Modulation of Interfacial Water at Gas–Liquid–Solid Interface for Water Electrolysis
Abstract Renewable electricity‐driven water electrolysis stands at the forefront of clean hydrogen production, playing a crucial role in achieving a net‐zero carbon future. Interfaci...
Self‐Medicating Molten‐Salt Synthesis of Bulk‐Stabilized High‐Energy Cathodes for Li‐Ion Batteries
Abstract High‐energy lithium‐ion batteries necessitate stable Ni‐rich layered cathodes, yet critical challenges such as lattice distortion and surface structure...
Dynamics of Metal–Metal Bond Dissociation in Pd–Pd and Ni–Ni Complexes: Reorganization and Redistribution Reactions of the Metalloradicals
Abstract Dinuclear M(I)–M(I) complexes (M = Ni, Pd) may serve as stable reservoir forms for highly reactive mononuclear metalloradicals, which are of interest as...
Unravelling the Functional Diversity of Type III Polyketide Synthases in Fungi
Abstract Type III polyketide synthases (T3PKSs) are enzymes that produce diverse compounds of ecological and clinical importance. While well‐studied in plants, only a handful of T3PK...
Reduced Pressure Ionization Enhances Native Mass Spectrometry of Proteins and Protein Complexes
Abstract Native mass spectrometry (MS) enables the analysis of protein interactions in complex biological mixtures. However, nonvolatile salts and buffers commonly present in such sa...
In‐Field Molecular Diagnostics of Plant Pathogens Using Bioluminescent CRISPR‐Guided Caspase Assay
Abstract In‐field molecular diagnostics of plant pathogens are critical for crop disease management and precision agriculture, but tools are still lacking. Herein, we present a biolu...
Engineering Donor–Acceptor Arrangement in Perylene Diimide‐Based Covalent Organic Frameworks for Enhanced Singlet Oxygen Photocatalysis
Abstract The photocatalytic efficiency of two‐dimensional covalent organic frameworks (2D COFs) is governed by the spatial arrangement of donor–acceptor (D–A) mo...
Ultralong‐Lived Excitons in Metallo‐Quinoline‐Incorporated Covalent Organic Frameworks Promote Photoreductive Cross‐Coupling
Abstract Designing long‐lived excitons in photocatalysts is crucial for efficient charge separation. However, most of the current organic photocatalysts are char...
Proton Flux Engineering via Built‐in Electric Fields in N‐doped CuO@Co <sub>3</sub> O <sub>4</sub> @Ni(OH) <sub>2</sub> Heterostructure for Rechargeable Zn‐NO <sub>3</sub> <sup>−</sup> /5‐Hydroxymethylfurfural Multielectron Transfer Systems
Abstract Electrocatalytic coupling of nitrate reduction (NO 3 RR) to ammonia with 5‐hydroxymethylfurfural (HMF) oxidation...
Probing Host–Guest Interactions via Conductance and Thermopower Measurements
Abstract Host–guest interactions play a crucial role in molecular recognition, self‐assembly, and the development of molecular electronic devices, which requires...
Photochemistry‐Enabled Nitrogen‐Assisted Organostibines as an Efficient Alkyl Radical Precursor: Mechanistic Insights and Synthetic Applications
Abstract Organostibines exhibit significant potential as functional handles for the construction of C─C‐rich scaffolds owing to their orthogonal and robust react...
Selective Catalysis‐Mediated Interface to Stabilize Antimony Atom‐Cluster Anode for Robust Potassium‐Ion Batteries
Abstract Controlling the electrode‐electrolyte interfacial behavior is crucial for achieving a high‐quality solid electrolyte interphase (SEI) and ensuring susta...