Angewandte Chemie International Edition
Articles in this Issue
Tellurium–Nitrogen–Carbon Support Boosting Platinum Catalysis in High‐Efficiency Proton Exchange Membrane Fuel Cells
Abstract Enhancing the energy conversion efficiency of fuel cells necessitates optimization of oxygen reduction reaction (ORR) under high‐voltage conditions thro...
Temperature‐Driven Conformational Switching of Binaphthalene‐Based Tetraimidazolium Macrocycles to Enhance Sequence‐Selective Recognition of Dinucleotides in Water
Abstract Developing artificial hosts with temperature‐driven conformational switching behaviors facilitates our understanding of the temperature‐dependent allost...
Long‐Lived Charge‐Transfer State and Interfacial Lock in Double‐Cable Conjugated Polymers Enable Efficient and Stable Organic Solar Cells
Abstract The donor/acceptor (D/A) interfaces in bulk heterojunction (BHJ) organic solar cells (OSCs) critically govern exciton dissociation and molecular diffusi...
Outside Back Cover: Programmable Bio‐Derived Noncovalent Glass via Reconfigurable H‐Bonding Networks (Angew. Chem. Int. Ed. 45/2025)
Symmetry Breaking Assisted Fast Reverse Intersystem Crossing for Efficient TADF Materials
Abstract Reverse intersystem crossing (RISC) process is critical for thermally activated delayed fluorescence (TADF) materials to realize spin–flip of triplet ex...
Inside Front Cover: Tunable Multistate Mechanoresistance in a Single‐Molecule Junction Incorporating Energy‐Dissipative Structures (Angew. Chem. Int. Ed. 45/2025)
High Performance Sulfide Solid‐State Battery Electrolytes Regulation Mechanism: A Review
Abstract Sulfide solid electrolytes (SEs) exhibit excellent ionic conductivity and good mechanical properties, but their poor air stability and solid–solid contact performance seriou...
Visible Light‐Driven Membrane‐Bound Compartment for Precise Regulation of Enzyme Activity
Abstract Photo‐responsive systems provide a powerful tool to reversibly regulate enzyme activity. However, inhibitor‐based strategies, though widely used, are of...
Outside Front Cover: Sub‐2 Nm Palladium Phosphide: A Highly Active and Selective Catalyst for the Hydrogenation of Furfural to Furfuryl Alcohol (Angew. Chem. Int. Ed. 45/2025)
Truxenone‐Based Covalent Organic Framework/Carbon Nanotube Composite for High‐Performance Low‐Temperature Sodium‐Ion Batteries
Abstract Low‐temperature rechargeable batteries face great challenges due to the sluggish reaction kinetics. Redox covalent organic frameworks (COFs) with porous...
Real‐Time Visualisation of Reaction Kinetics and Dynamics: Single‐Molecule Insights into the Iminium‐Catalysed Diels–Alder Reaction
Abstract Investigation of the fundamental microscopic processes occurring in organic reactions is essential for optimising both organocatalysts and synthetic str...
Real‐Time Eco–AI, Electrophoresis‐Correlative Data‐Dependent Acquisition with AI‐Based Data Processing Broadens Access to Single‐Cell Mass Spectrometry Proteomics
Abstract Single‐cell mass spectrometry (MS) offers unprecedented sensitivity for profiling cellular proteomes, yet widespread adoption is hindered by the cost of...
Interfacial Zn─O─Ti Sites for Efficient Photocatalytic Urea Synthesis from CO <sub>2</sub> and N <sub>2</sub>
Abstract Urea photosynthesis from CO 2 and N 2 has profound environmental and ene...
Tunable Multistate Mechanoresistance in a Single‐Molecule Junction Incorporating Energy‐Dissipative Structures
Abstract Mechanoresponsive molecular devices are capable of exhibiting dynamic responses to external mechanical stimuli, enabling applications in smart materials...
From Solvent to Catalyst: In Situ Amino Acid‐Like Species Enable PET Upcycling Without Added Catalysts
Abstract Chemical recycling of polyethylene terephthalate (PET) offers a promising route to value‐added chemical production, yet conventional methods typically d...
Ultralow‐Cost Lacunary Metal‐Oxo Framework Enables Efficient and Stable Organic Solar Cells
Abstract Organic solar cells (OSCs) with p‐i‐n architecture usually exhibit decent efficiency due to the easily tunable energy levels of organic interfacial laye...
Radical Ring‐Opening Reaction of Non‐Activated Oximes Catalyzed by Aldoxime Dehydratases
Abstract The iminyl radical is a distinctive N ‐centered radical which serves as a versatile synthon in preparation of ni...
Polymer Ligands with Quaternary Ammonium Binding Motifs on Metal Nanoparticles Enable Selective Ion Transport for CO <sub>2</sub> Electroreduction
Abstract We report a new class of hydrophobic polymer ligands with quaternary ammonium head groups for surface modification of noble metal nanoparticles (NPs). Q...
Development and Application of Radical‐Mediated Stereochemical Epimerization in Natural Product Synthesis
Abstract Precise control over stereochemistry (enantio‐ and diastereo‐selectivity) is essential in the long‐step synthetic protocol of complex molecules bearing...
Interactional Features of (RO) <sub>4</sub> Ti Species and Their Zr and Hf Analogues
Abstract Tetroxides of Group 4 elements are benchmark catalysts for aldol reactions and oxidation processes, achieving high yields and regio‐, diastereo‐, and enantioselectivities. O...
Facile Synthesis of 20‐nm‐Thick ZIF‐67 Films for Hydrogen Sieving Using β‐Co(OH) <sub>2</sub> Precursor Nanosheets
Abstract Zeolitic imidazolate framework‐67 (ZIF‐67) is an important class of nanoporous materials for high‐performance membranes for gas separation, offering uni...
Sub‐2 Nm Palladium Phosphide: A Highly Active and Selective Catalyst for the Hydrogenation of Furfural to Furfuryl Alcohol
Abstract Phosphidation offers a promising approach to tailor noble metal properties for high catalytic selectivity, yet achieving highly dispersed noble metal ph...
Stereoelectronic Insight Into Heme Carbene Catalysis: Bridging Enzymatic and Synthetic Systems
Abstract Iron porphyrin carbenes (IPCs), pivotal intermediates in enzymatic carbene transfer reactions, adopt diverse bonding modes and electronic configurations...
Programmable Bio‐Derived Noncovalent Glass via Reconfigurable H‐Bonding Networks
Abstract Glass has served as a cornerstone of modern civilization due to its exceptional optical transparency and structural integrity. Yet, its static covalent/ionic network fundame...
Control of Tetrazine Bioorthogonal Reactivity by Rotaxanation
Abstract Rotaxanation is an efficient method to control the tetrazine‐mediated inverse electron demand Diels–Alder (IEDDA) reaction. Tetrazine rotaxanes were synthesized in high yiel...