Angewandte Chemie International Edition
Articles in this Issue
Quinuclidinium‐Based Microporous Anion Exchange Membranes for Water Electrolysis
Abstract Anion exchange membrane water electrolysis (AEMWE) is a promising green hydrogen production method; however, it is constrained by the moderate OH...
Dual‐Functional Molecular Stabilization of Spacer Cation‐Mediated Aging Dynamics in Low‐Dimensional Perovskite Precursors Enables Efficient Solar Cells
Abstract The aging dynamics of perovskite precursor solutions critically govern the photovoltaic performance of solar cells. However, the underlying degradation...
Alloying Small‐Cation into Low‐Dimensional Perovskite Motif Gives Multiaxial Ferroelectrics with Enhanced Photo‐Pyroelectricity
Abstract Photoactive ferroelectrics have shown huge potentials for assembling high‐performance optoelectronic devices. Bismuth‐based halides are emerging as a vi...
Chloride‐Bridged Compact Interfacial Shielding for Practical Seawater Zinc Batteries
Abstract Substituting natural seawater (NS) for deionized water significantly reduces the electrolyte manufacturing cost of aqueous zinc (Zn) ion batteries, but...
Naoki Yasukawa
Spatiotemporal Control of the Formation of Luminescent Lanthanide Complexes in Liposome‐Based Nanoreactors
Abstract The controlled mass transfer across compartmentalised environments in synthetic nanoreactors is essential for enhancing precise spatiotemporal manipulation of chemical trans...
Supramolecular Interactions Modulate RNA:DNA Folding Observed via Nanopore Sensing
Abstract DNA and RNA nanotechnology enables the precise assembly of molecular architectures, with applications in bioengineering, supramolecular chemistry, and sensing. The material...
Partitioning COF Membrane Channels into Ultramicroporous and π‐Electron‐Rich Compartments for Multicomponent Ion Separations
Abstract Covalent organic frameworks (COFs) build a versatile platform for constructing separation membranes, affording them disruptive candidates for nanoscale...
Defect‐Promoted Reductive Regeneration on Cobalt Catalysts Enables Efficient Dual‐Pathway Hydrazine Electrooxidation
Abstract Hydrazine oxidation reaction (HzOR) represents a promising low‐energy pathway for sustainable hydrogen production, yet mechanistic ambiguities and catal...
Donor–Acceptor Interaction Optimized Film‐Forming Processes Lead to Efficient Organic Solar Cells and Modules Fabricated with Non‐Halogenated Solvents
Abstract While the transition from halogenated to eco‐friendly processing solvents is vital for the industrialization of organic solar cells (OSCs), obtaining id...
Polyanion Electrointercalation Enables Termination‐Tailored Oligolayer Ti <sub>3</sub> C <sub>2</sub> T <i> <sub>x</sub> </i> MXene Synthesis in Alkali Chloroaluminate Melt
Abstract Tailoring surface chemistry and achieving non‐destructive interlayer exfoliation are crucial for controlling MXene properties. Conventional synthesis st...
Javier Mateos
Solvent Chain‐Length Engineering Enables All‐Climate Sodium‐Ion Batteries
Abstract Achieving high‐rate capability, long‐term cycling stability, high‐voltage tolerance, and wide‐temperature adaptability in sodium‐ion batteries (SIBs) re...
Bandgap Engineering of Graphene Nanoribbon via High‐Pressure Topochemical Synthesis
Abstract Graphene nanoribbons (GNRs) have attracted broad attention for their potential application in nanoelectronics. The electronic properties of the GNRs are...
Development of Indolo‐Bicyclo[3.1.1]Heptane as a Carbazole Isostere Through Radical Indolization of Bicyclo[1.1.0]Butanes
Abstract Semisaturated ring systems with a balanced fraction of C(sp3) have garnered increasing attention in drug development. In this study, we propose indolo‐bicyclo[3.1.1]heptane...
Breaking the Performance Limit of Pure Metals for N <sub>2</sub> Electroreduction
Abstract The electrocatalytic nitrogen reduction reaction (NRR) offers a sustainable pathway for ambient‐condition ammonia synthesis, yet its efficiency is funda...
Fully‐Functionalized Natural Product Probes to Expand the Chemical Tractability of the Human Proteome
Abstract Photoaffinity (PA)‐based chemoproteomic methods have emerged as a powerful means for proteome‐wide mapping of ligandable proteins directly in cells, as...
Synthesis, Isolation, and Reactivity of a Phosphinidene Telluride
Abstract The synthesis and isolation of a phosphorus(III) telluride is reported. The compound was accessed by means of a double bond metathesis reaction between...
Probing the Structural Dynamics of In <sub>2</sub> O <sub>3</sub> Using in Situ Raman Spectroscopy: Bridging Material Dynamics and Sensor Functionality
Abstract Metal oxide semiconductor (MOS) gas sensors still face the critical challenge of high operating temperatures. While material engineering strategies have...
Strengthening Intermediate Adsorption on a Cobalt Phthalocyanine Assembly by Polymeric Modification for Electrochemical Carbon Dioxide Reduction into Methanol
Abstract Electrochemical carbon dioxide reduction (CO 2 R) to generate value added methanol (MeOH) in water has been cons...
Mechanofluorochromic Elastomers Based on Reversible Helical Transition of Poly(phenylacetylene)s
Abstract Mechanofluorochromic (MFC) materials possessing both high sensitivity and excellent reversibility are crucial for achieving real‐time mechanical sensing...
Steering Amide Synthesis from Acetonitrile by Electrochemically Derived Active Superoxide
Abstract Amides with unique carbonyl‐nitrogen linkage are fundamental functional groups that are active and essential for a wide range of natural and synthetic p...
In Situ Orthogonal Chemistry for Facile Preparation of Uniform COF‐Based Composite Polymer Electrolytes
Abstract Covalent organic framework (COF)‐based composite polymer electrolytes (CPEs) represent a promising platform for advanced lithium‐metal batteries (LMBs)...
Continuous Flow Photocatalysis Boosting C─N Coupling for Sustainable High‐Efficiency Formamide Synthesis
Abstract The construction of C─N bonds from simple precursors under ambient conditions is a fundamental challenge in green chemistry, especially when it comes to...
Unlocking the Free Radical Evolution for Directed Conversion of Furoic Acid to 2,5‐Furandicarboxylic Acid Over Lattice‐Distorted MnO <i>x</i>
Abstract Developing the efficient C─H bond activation carboxylation processes for furoic acid (FA) represents a critical technological challenge in achieving ato...