Angewandte Chemie International Edition
Articles in this Issue
Identifying an Active Intermediate and Monitoring O─O Bond Formation in Water Oxidation by a Cobalt(III)‐TAML Complex
Abstract A cobalt(III) −TAML complex, [(TAML)Co III ] − (TAML = tetraamido macroc...
Quantifying Å‐Scale Non‐Additive Solvation at Nanoparticle Interfaces
Abstract Solvent organization at solid–liquid interfaces dictates nanoparticle stability, catalysis, and self‐assembly. Classical physical‐chemistry theories commonly treat solvent q...
Naphthalimide‐Based Type‐I Nano‐Photosensitizers for Enhanced Antitumor Photodynamic Therapy: H <sub>2</sub> S Synergistically Regulates PeT and Self‐Assembly
Abstract Photodynamic therapy (PDT) relies on a combination of light and photosensitizers (PSs) to achieve local control over cancerous lesions. However, it is s...
Sodium‐Based Dual‐Ion Battery: From Materials to Mechanism
Abstract Sodium‐based dual‐ion batteries (SDIBs) have garnered increasing attention as a next‐generation energy storage technology, owing to their high operating voltage, cost‐effect...
Structural Dependence of Catenand Effect: Thermodynamic and Kinetic Modulation of Catenane Coordination Properties via Ring‐size and Exocyclic Substituent Variation
Abstract Although the effects of ligand interlocking on specific features of coordinated metal were first reported in 1980s’, strategies to precisely control the...
Isolation of Anionic <i>N</i> ‐Heterocyclic Olefins and Their Versatile Reactivity
Abstract N ‐Heterocyclic olefins (NHOs) have emerged as powerful bases and nucleophiles with broad applications in synthesis and catalysis. H...
Tuning Solvation Structure Via Inductive and Steric Hindrance Effects for High‐Voltage LiCoO <sub>2</sub> Batteries
Abstract High‐voltage lithium cobalt oxide (LiCoO 2 ) has a high specific capacity and energy density, making it a promis...
Arene Ruthenium(II) Carboxylates for C─H Alkylations and Arylations at Near Room Temperature
Abstract The long‐term pursuit for more efficient catalysts has stimulated the development of C─H activations under mild reaction conditions, with the overarchin...
Total Synthesis of Clerodin
Abstract The first and asymmetric total synthesis of clerodin, the earliest isolated clerodane diterpenoid, has been achieved by tail‐to‐head cyclization and mod...
Nanodroplet Array Platform for Integrated Synthesis and Screening of MEK Inhibitors: a Miniaturized Approach to Early Drug Discovery
Abstract Early‐stage drug discovery relies on high‐throughput screenings, which are costly and time‐intensive, limiting access for academic laboratories and small companies. A key bo...
Degradation of G‐Quadruplex‐Binding Proteins by G4L‐PROTAC via Quaternary Complex Formation
Abstract G‐Quadruplexes (G4s) are noncanonical nucleic acid secondary structures enriched in genomic regions critical for transcription and replication. These dy...
Driving Multi‐Step Regioselectivity in On‐Surface Polymer Synthesis by Molecular Coverage
Abstract On‐surface synthesis has revolutionized the design of low‐dimensional organic nanomaterials, introducing unprecedented families of compounds while offer...
AlCl <sub>4</sub> <sup>−</sup> ‐Deficient Eutectic Electrolytes Enable Reversible Iodine Redox‐Amphoteric Conversion for Aluminum Battery Cathodes
Abstract Aluminum (Al) batteries are promising for sustainable and large‐scale energy storage due to the inherent safety, low cost, and attractive metrics of the...
Quantification and Optimization of Interfacial Ion Transport in Polymer/Ceramic Composite Electrolytes for Solid‐State Batteries
Abstract Solid polymer/ceramic composite electrolytes have emerged as promising candidates for solid‐state batteries owing to their superior mechano‐chemical com...
Permselective Covalent Organic Framework Membrane as Self‐Extinguishing Separator for High‐Safety Lithium‐Ion Battery
Abstract As electric vehicles continue to gain popularity, the demand for high‐energy‐density battery technologies is growing rapidly. The separator, the most cr...
Tuning Microscopic Water Orientation in Nickel Single‐Atom Catalyst for Commercial‐Scale CO <sub>2</sub> Electrolysis to CO
Abstract Electrochemical CO 2 reduction (ECR) to carbon monoxide (CO) offers a sustainable route for fuel and chemical pr...
Reducing Energetic Disorder for High‐Efficiency Perovskite Solar Cells with Low Urbach Energy by in Situ NH <sub>3</sub> Generation
Abstract The high disorder in perovskite materials leads to severe carrier non‐radiative recombination, which directly determines the energy loss of photovoltaic...
Chlorine Radical‐Driven, Oxygen‐Independent Afterglow Nanoplatform for Tumor Microenvironment—Adaptive Imaging and Therapy
Abstract Persistent luminescence (afterglow) imaging offers exceptional signal‐to‐background ratios by eliminating tissue autofluorescence, yet most organic syst...
Gypsum Gardens: Self‐Assembled Tubular Structures of Calcium Sulfate with Relevance for the Detection of Extraterrestrial Life
Abstract Form is a common and intuitive criterion to distinguish between the realm of living species and the inanimate nature. However, there are in fact no stri...
From Global Flexibility to Local Flexibility: Enable A–B Stacked Metal–Organic Framework for One‐Step Ethylene Purification from Complex Gas Mixtures
Abstract Flexible metal–organic framework (MOF) adsorbents can achieve exceptional separation performances under appropriate stimuli, especially for complex gas...
Intramolecular Noncovalent Interaction‐Driven <i>Syn</i> ‐/ <i>Anti</i> ‐Conformational Regulation in Nonfused‐Ring Electron Acceptors
Abstract Molecular conformation is a critical structural attribute of organic molecules and polymers in addition to their constitution and configuration, thereby...
Metastable Crystalline Cobalt Iron Oxide Nano‐Flakes with Antiferromagnetic/Ferrimagnetic Composition Mosaicity
Abstract By thermal decomposition of a crystalline hydroxycarbonate precursor with a Co:Fe ratio of 2:1, crystals with alternating ferrimagnetic and antiferromag...