Angewandte Chemie International Edition
Articles in this Issue
Engineering Artificial Mitochondria with Self‐Amplifying Proton Generation for Autonomous Energy Supply and Metabolic Coupling in Artificial Cells
Abstract A continuous and autonomous energy supply is essential for sustaining life‐like biochemical processes in artificial cells. Although considerable efforts...
Azothiophenes as Visible‐Light Photoswitches via n‐π∗ Excitations
Abstract Selective excitation of the n‐π* bands of the E and Z isomers in azoswit...
Proton Conduction, Dielectric Relaxation, Photoluminescence, and Photochromism Governed by Humidity and Alcohol Vapors in a Uranyl–Cobalt Framework with Labile Coordination Sites
Abstract Stimuli‐responsive coordination polymers serve as an efficient platform for the generation of functional systems, showing tunable magnetic, electrical,...
N‐Doped Nonalternant Molecular Bowl/Saddle Hybrids
Abstract Herein, we report the straightforward synthesis and properties of N‐doped molecular bowl/saddle hybrids with nonalternant topologies via successive pall...
Photoredox/Nickel‐Cocatalyzed Asymmetric C–O and C–S Couplings for Atroposelective Synthesis of <i>N</i> ‐Heterobiaryls
Abstract Photoredox/nickel‐cocatalyzed cross‐couplings have emerged as powerful methods for constructing carbon–heteroatom bonds under mild conditions. Despite t...
Unlocking High‐Concentration PET Upcycling via Site‐Decoupled Copper Catalysis
Abstract Upcycling polyethylene terephthalate (PET) plastic waste on islands into valuable fuels represents a promising strategy for carbon resource utilization...
One‐Step Phosphine‐Oxide Post‐Modification of Multi‐Resonance Emitters for Efficient, Narrowband, Quenching‐Resistant OLEDs
Abstract Multiple‐resonance thermally activated delayed fluorescence (MR‐TADF) materials featuring high efficiency and narrowband emission are crucial for wide c...
Discovery and Biosynthesis of Rare Fungal Terpenoid‐Isonitrile Amino Acid Hybrid Natural Products
Abstract Terpenoid nonproteinogenic amino acid hybrid natural products usually have complex chemical structures and important biological functions. Herein, we di...
Unprecedented Selectivity for Arsenic(III) in a Dimercaptosuccinic Acid‐Based Zr‐MOF: The Role of Dangling Ligands
Abstract While zirconium‐metal–organic frameworks (Zr‐MOFs) show promise for arsenic remediation, their practical implementation faces critical challenges: poor...
Ultralow‐Content PdCu Disordered Nanoalloys on Carbon Nitrides for Unity‐Selective CO <sub>2</sub> Hydrogenation to Methanol
Abstract Catalytic CO 2 hydrogenation to methanol offers a dual benefit of mitigating CO 2...
Polyoxometalate‐Based MOF as a Highly Sensitive and Stable X‐ray Detector for Imaging
Abstract Polyoxometalate‐based metal–organic frameworks (POMOFs) show potential application prospects in the field of X‐ray detection in recent years. However, i...
Artificial Photosynthesis of Glycolaldehyde and Syngas from Plastic Feedstocks via Boron‐Functionalized Nickel Species on CdS
Abstract Glycolaldehyde is an important intermediate in the synthesis of pharmaceuticals and biodegradable plastics. Artificial photosynthesis of glycolaldehyde...
Unveiling the Stereochemical Uncertainty of Polyol Scaffolds: Total Synthesis of Mycapolyol E
Abstract Mycapolyol E is a cytotoxic metabolite, isolated from the marine sponge Mycale izuensis . After isolation, the s...
London Dispersion‐Induced Contraction of the Cu─O Bond in Copper(I) Phenolates
Abstract Conventional chemical wisdom holds that shorter bonds of a given type generally exhibit greater strength. Here, we reveal a counterintuitive bonding mod...
Chemical Synthesis of Arabinogalactans from the <i>Mycobacterium tuberculosis</i> Cell Wall up to the 92‐mer and Structure–Conformation–Activity Relationship Studies
Abstract Arabinogalactans (AG) from the Mycobacterium tuberculosis (Mtb) cell wall represent potential therapeutic agents...
Hydrogen Atom Capture Toward Dense Solid Electrolyte Interface for Long‐Cycling Aqueous Zinc‐Ion Batteries
Abstract Aqueous zinc‐ion batteries (AZIBs) are promising high‐safety energy storage devices, but their practical implementation has been limited by dendrite gro...
Laser‐Programmed Spatial Relay Catalysis on Co─Ag Dual Heterojunctions for Efficient Nitrate‐to‐Ammonia Conversion via Migratory *NO <sub>2</sub> Shuttling
Abstract Electrocatalytic nitrate (NO 3 − ) reduction to ammonia (NH 3...
Facile Access to Chelating CAArC‐Phosphine (CAArCPhos) Palladium Complexes
Abstract In this article, we present a synthetic route to 4‐(diphenyl‐phosphino) isoindolium salts based on a new protecting group strategy. Key to success is the use of hemi‐aminal...
Polarity Gradient CEI Driven Rapid Desolvation for Extreme Fast‐Charging Potassium‐Ion Batteries
Abstract Potassium‐ion batteries (PIBs) offer an opportunity for superior fast‐charging compared to lithium‐ion batteries, owing to their faster K...
Sulfinyl Aziridines as Stereoselective Covalent Destabilizing Degraders of the Oncogenic Transcription Factor MYC
Abstract Although MYC is a significant oncogenic transcription factor driver of cancer, directly targeting MYC has remained challenging due to its intrinsic disorder and poorly defin...
Structure‐Oriented Metal‐Organic Framework Activation via Proximal Oligoalkyl Quaternary Ammonium Grafting Enhances Long‐Chain PFAS Sorption
Abstract A structure‐oriented design of zirconium‐based metal‐organic frameworks (Zr‐MOFs) for long‐chain per‐ and polyfluoroalkyl substances (PFAS) is criticall...
High‐Selectivity Electrocatalytic Oxidation of Glycerol to C <sub>3</sub> ‐Glyceraldehyde Coupled to H <sub>2</sub> O <sub>2</sub> Production
Abstract Achieving high selectivity of glyceraldehyde (GLD) products remained challenging due to competing C─C bond cleavage and multiple reaction pathways durin...
Breaking of the Up‐Down Symmetry of DNA Origami on a Solid Substrate
Abstract Controlling the surface orientation of DNA origami nanostructures (DON) is crucial for applications in nanotechnology and materials science. While previ...
Hypercrosslinked Polymers for Volatile and Very Volatile Organic Compound Capture Beyond Commercial Benchmarks
Abstract The effective capture of volatile organic compounds (VOCs) and very volatile organic compounds (VVOCs) is crucial for controlling indoor air quality, en...
Boron‐Centered Organic Salts Enabling Na‐Ion Supply and Interfacial Protection for Na‐Ion Batteries
Abstract Sodium (Na)‐ion batteries employing hard carbon anodes suffer from a significant irreversible loss of active Na ions (up to 20%) during the initial form...