Angewandte Chemie International Edition
Articles in this Issue
Electroactive Chelating Groups Enable High‐Performance Aqueous Zinc‐Organic Batteries
Abstract P‐type organic electrode materials, characterized by fast kinetics and high redox potential, hold great promise for aqueous zinc‐ion batteries (ZIBs), b...
Anion‐Assisted Copper/Chiral Diamine‐Catalyzed Aerobic Oxidation for the Kinetic Dearomative Spirocyclization of Arenols
Abstract The utilization of arenols was realized via the catalytic asymmetric dearomatization (CADA) to deliver a broad range of valuable chiral compounds. In this field, CADA of are...
About a Trillion Times More Acidic than Expected? On the Difference Between the Hammett <i>H</i> <sub>0</sub> and the Unified pH Acidity of Sulfuric Acid
Abstract We report on the considerable difference between the distinct pH and Hammett's H 0 acidity f...
An Organic Sacrificial Salt with Low Decomposition Potential Driven by Substituent Effect Enables High‐Performance Lithium‐Ion Batteries
Abstract The irreversible Li + loss during solid electrolyte interphase (SEI) formation significantly critically constrai...
Reactivity of Low Valent Magnesium(I) Complexes with Epoxides and Episulfides
Abstract Chemical C–H functionalisation is traditionally the domain of potent organolithium bases that require cryogenic conditions, whereas biologically inspire...
Molecular Templating and Boron‐Doping Guides Twisted Microcrystalline Formation in Coal‐Derived Hard Carbons for High‐Rate Sodium‐Ion Storage
Abstract The development of hard carbon (HC) anodes with the low‐cost coal precursor for sodium‐ion batteries (SIBs) is usually limited by sluggish kinetics and...
Homoterpene Biosynthesis in Fungi
Abstract Homoterpenes carrying an additional methyl group in their carbon backbones are an emerging class of natural products that challenge the biogenic isopren...
How Does the Precursor Influence the Li‐Rich Layered Oxide Cathode?
Abstract As a fundamental determinant of Li‐ion battery (LIB) cathode performance and production scalability/feasibility, selection and optimization of precursors represent an essent...
Shape‐Matched Nonpolar Pore Surfaces Enhance Alkane Recognition Toward Natural Gas Upgrading
Abstract Efficiently removing C 3 H 8 and C 2...
Solvent Chain Length Directed Supramolecular Polymorphism
Abstract Although solvents are central to self‐assembly, their chain length has not been recognized as a factor controlling supramolecular polymerization. Herein...
Topochemical Alkyne Nitrile Oxide Cycloaddition for Polymer Synthesis
Abstract Topochemical reactions, characterized by their solvent‐free, catalyst‐free, and lattice‐controlled nature, offer an attractive method for crystalline polymers. The limited n...
Fully Locked Conjugated Backbones in Simple‐Structured Polymer Donors Enabling High‐Performance Organic Solar Cells
Abstract The development of wide‐bandgap polymer donors with cost‐effectiveness is pivotal for advancing the commercialization of organic solar cells (OSCs). However, these materials...
Dynamic Bridging Ligand‐Induced Regulated Coordination Chemistry for Highly Reversible Zn‐Metal Anodes
Abstract The lifespan of aqueous Zn‐ion batteries (AZIBs) is significantly affected by the Zn anode interfacial hydrogen evolution and uncontrolled dendrite grow...
Tailored Synergistic Binding Environment in Metal‐Organic Frameworks for Record One‐Step Ethylene Purification from Multicomponent Mixtures
Abstract Precise control over pore environments in porous materials remains a long‐standing challenge for efficient ethylene (C 2...
Rapid and Reversible Visible‐Light‐Induced Helix Inversion in Chiral Liquid Crystals Doped with a Negative Photochromic Molecule
Abstract Light‐induced helix inversion in chiral nematic liquid crystals (N*LCs), where helicity reverses under photoirradiation, has emerged as a promising strategy. However, existi...
Electrochemiluminescence Modulation by a Versatile Organic Redox Mediator
Abstract Adding a redox‐active iridium complex has emerged recently as a new mechanistic pathway to enhance electrochemiluminescence (ECL). But, these redox medi...
Topology‐Tuned Structural Flexibility Toward Customized Piezofluorochromism in Stable Zirconium MOFs
Abstract Albeit serving important roles in high‐techs, the rapid development of crystalline pressure‐responsive materials still heavily relied on the de novo syn...
From Pharmacophore to Warhead: NAD <sup>+</sup> ‐Targeting Triazoles as Mechanism‐Based Sirtuin Inhibitors
Abstract Sirtuins (SIRTs) are nicotinamide adenine dinucleotide (NAD + )‐dependent lysine deacylases linked to key physio...
Etter Revised: Graph‐Set Analysis for Supramolecular Patterns in Molecular Crystals <sup>*</sup>
Abstract A modification to Etter's graph‐set notation for hydrogen‐bond patterns in molecular crystals is proposed to enable the classification of supramolecular patterns based on an...
Biomimetic Hydrophobic‐Polar Metal‐Organic Frameworks for Record‐Breaking Separation and Capture of Xenon and Krypton
Abstract The separation and capture of xenon (Xe) and krypton (Kr) pose critical industrial and environmental challenges. We report two isostructural MOFs (NKMOF...
Dual‐Quinoid Backbone Synergistic with Side‐Chain Engineering Enables Ultrahigh‐Temperature Conjugated Polymers for Bridging Solar‐ and Laser‐Driven Photothermal Applications
Abstract Organic photothermal materials often perform efficiently under either solar or laser irradiation, yet achieving dual high performance within one system...
Mechanistic Characterisation of Bacterial Terpene Synthases from Chitinophagaceae Producing Marine‐Type Diterpenes
Abstract Two neodolabellane‐type diterpene synthases from Chitinophaga japonensis (CjCsS and CjNdtS) in addition to one e...
Site‐Selective RNA Modification by Programmable DNA‐Small Molecule Conjugates
Abstract Efficient strategies for site‐selective modification of native RNA are highly important for advancing fundamental research of RNA biology and translational RNA therapeutics....
Flow‐Enabled, Modular Access to α,α‐Difluoromethylene Amines
Abstract The α,α‐difluoromethylene amine (NCF 2 R) motif represents a useful functionality in medicinal chemistry, yet pr...
Record‐Breaking Discharge Capacity and Rate Capability in Li─O <sub>2</sub> Batteries Through Magnetic Field‐Induced Short‐Range Order Li <sub>2</sub> O <sub>2</sub>
Abstract Aprotic Li─O 2 batteries face significant challenges due to the insulating and insoluble nature of Li...