Strong, Yet Split Hydrogen Bonding with Ice Rules in Delafossite (H/D)RhO <sub>2</sub>
Abstract
Abstract Despite remaining enigmatic, strong hydrogen bonding provides an advanced design handle for tailoring the properties of functional materials. Here, 3 R –(H/D)RhO 2 delafossites (prepared by ion exchange of Na + from NaRhO 2 ) contain H/D in linear coordination with O, linking Rh III O 2 layers. Bragg and real‐space X‐ray and neutron scattering analysis, vibrational and solid‐state NMR spectroscopy, and density functional theory (DFT)–based electronic structure calculations have been employed to understand the nature of the hydrogen bonding. Despite short distances between H/D and the two O to which they are bonded, a clear double‐minimum corresponding to a shorter and longer (H/D)–O distance is established. The triangular lattices formed by H/D appear to display ice‐like disorder, corroborated by low‐temperature heat capacity measurements.
Article Details
Authors (10)
Matthew A. Wright
Materials Department
Anya S. Mulligan
Materials Department University of California Santa Barbara CA USA
Dibyata Rout
Materials Department University of California Santa Barbara CA USA
Jerry G. Hu
Materials Research Laboratory University of California Santa Barbara CA USA
Jue Liu
Rachel L. Behrens
Materials Research Laboratory University of California Santa Barbara CA USA
Juan R. Chamorro
Materials Science and Engineering Carnegie Mellon University Pittsburgh PA USA
Stephen D. Wilson
Anthony K. Cheetham
Department of Materials, Materials Research Laboratory
Ram Seshadri
Materials Department and Materials Research Laboratory