Angewandte Chemie International Edition
Articles in this Issue
Pre‐Polymerization and Pre‐Etching Dominated by Carbon Dots to Fabricate the Sub‐Nanometer Microporous Carbon for Supercapacitors
Abstract The self‐templating method is a facile and low‐cost strategy to synthesize porous carbon materials, but the obtained products usually have low yields, l...
Redox‐Acidity Interplay in Eu‐Promoted PtSn <sub>2</sub> Catalysts for Selective and Stable Propane Dehydrogenation
Abstract Heterogeneous catalysts based on Pt alloys are widely employed in propane dehydrogenation (PDH), yet challenges such as coking and poor nanoparticle sta...
Reversible Zn <sup>2+</sup> ‐Activated Channel Transport Through Monomer‐Dimer Interconversion of Rotaxane
Abstract Inspired by natural ligand‐gated ion channels, artificial counterparts are of great interest for understanding biological transport mechanisms and devel...
Enhancing NMR Signals in Liquids by Fluorine‐19 Overhauser Dynamic Nuclear Polarization (DNP) and Hyperpolarization Transfer to Carbon‐13
Abstract Nuclear magnetic resonance (NMR) plays an essential role in life and material science but suffers from low sensitivity due to the small energy differenc...
Outside Back Cover: Solvent Channels and Electric Fields Guide Proton Delivery to the Active Site of Heme Peroxidases (Angew. Chem. Int. Ed. 50/2025)
Nor[7]circulenyl Neutral Radical and Its Charged Species: Synthesis, Structures, and Efficient NIR‐II Photothermal Conversion for Imaging and Laser Ignition
Abstract [ n ]Circulenes have attracted considerable research interest; however, open‐shell [ n...
Inside Back Cover: Redox Reactions with Calcium‐Metal Nanoparticles (Angew. Chem. Int. Ed. 50/2025)
Rational Engineering of a Pseudaminic Acid Synthase Enzyme Enables Access to a 3‐Fluoro Sugar with Motility Inhibition in Bacterial Pathogens
Abstract We report the rational engineering of a pseudaminic acid synthase (PseI), which enables the first synthesis of a 3‐fluorinated pseudaminic acid sugar (3...
Molecular‐Rotor‐Engineered Metal–Organic Frameworks with Various Interpenetrated Degrees/Modes Featuring Tunable Porosity/Stability for Binary/Ternary C <sub>2</sub> H <sub>2</sub> /CO <sub>2</sub> /C <sub>2</sub> H <sub>4</sub> Separation
Abstract Efficient separation of challenging acetylene/ethylene (C 2 H 2 /C...
A Photoswitchable HaloTag for Spatiotemporal Control of Fluorescence in Living Cells
Abstract Photosensitive fluorophores, whose emission can be controlled using light, are essential for advanced biological imaging, enabling precise spatiotemporal tracking of molecul...
Breaking Diffusion Limit in Ester‐Flame‐Proof Na‐Ion Electrolytes Through Solvent Coordination Chemistry
Abstract Traditional electrolyte systems are struggle to meet practical needs for high performance of sodium‐ion batteries (SIBs) due to their limited functional...
Double‐Donor and Anion‐π Polymer Electrolytes for Fast Li <sup>+</sup> Conduction in Lithium Metal Batteries
Abstract Cellulose‐based quasi‐solid polymer electrolytes (QPE) offer advantages such as cost‐effectiveness, renewability, and environmental friendliness, making...
Deciphering Ball Milling Mechanochemistry via Molecular Simulations of Collision‐Driven and Liquid‐Assisted Reactivity
Abstract Mechanochemistry by ball milling proceeds through a series of discrete, high‐energy collisions between milling balls and the sample, yet the molecular‐level processes that g...
Pd(II)/PIDA‐Enabled Migratory Triple Functionalization of Terminal Alkenes via a 1,2‐C/Pd(IV) Dyotropic Rearrangement
Abstract We report a Pd(II)‐catalyzed migratory triple functionalization of terminal alkenes. The reaction of homoallylic amides with phenyliodine(III) diacetate...
Construction of Tetrasubstituted α‐Amino‐ and α‐Alkoxy Phosphine Oxides via Pd‐Catalyzed Regio‐ and Enantioselective Hydrophosphinylation of Dienes
Abstract Significant progress has been made in the asymmetric hydrofunctionalization of dienes to construct vinylic stereogenic carbon centers. However, achieving enantioselective hy...
Controlled Dual Activation of Rhenium(I) Photosensitizers and Profluorophores/Prodrugs via a Dissociative Bioorthogonal Tetrazine–Isonitrile Reaction
Abstract Strategies for prodrug activation have been developed to enhance treatment efficacy, with bioorthogonal dissociation reactions emerging as a promising a...
Two‐Stage Catalytic Conversion of Carbon Dioxide Into Aromatics Via Methane
Abstract In the refinery of the future, the input shifts from crude oil to biomass, plastic, and CO 2 . Therefore, we nee...
RETRACTION: An Amphiphilic Dendrimer for Effective Delivery of Small Interfering RNA and Gene Silencing In Vitro and In Vivo
RETRACTION : T. Yu, X. Liu, A.‐L. Bolcato‐Bellemin, Y. Wang, C. Liu, P. Erbacher, F. Qu, P. Rocchi, J.‐P. Behr, and L. Peng, “An Amphiphilic Dendrimer for Effective Delivery of Sma...
Inside Front Cover: Click‐Cyclized Cell Penetrating Peptides Containing Hydrophobic Proline Derivatives for Efficient Intracellular Delivery (Angew. Chem. Int. Ed. 50/2025)
Catalytic Asymmetric Synthesis of Chiral Allenylic Fluorides Enabled by Multiple Radical Sorting
Abstract Here, we disclose a nickel‐catalyzed, three‐component asymmetric radical sorting strategy that enables the enantioselective synthesis of axially chiral allenylic fluorides f...
Fast‐Charging Hard Carbons: A Fully Organic SEI Enables Low‐Coordination Interfacial Environments and Fast Na <sup>+</sup> Desolvation
Abstract Fast‐charging capability becomes a critical bottleneck for the practical deployment of sodium‐ion batteries (SIBs), particularly due to sluggish Na...