Angewandte Chemie International Edition
Articles in this Issue
A Band‐Orientation Co‐Anchoring Strategy for the Design of a High‐Performance Mid‐Infrared Nonlinear Optical Crystal
Abstract Mid‐infrared (MIR) nonlinear optical (NLO) crystals have long been pursued, yet the realization of a balance among key performance metrics remains a for...
Buried Interface Modification for High Performance and Stable Inverted Perovskite Solar Cells
Abstract Residual stress can cause distortion of the perovskite lattice, resulting in the formation of local defects such as dislocation and vacancy. These defec...
Isomeric Π Conjugated Covalent Organic Frameworks with Tunable Nitrogen Topologies for Integrated Gold Adsorption and Photoreduction
Abstract Gold recovery from electronic waste (e‐waste) presents a significant materials challenge, as conventional systems lack structural tunability, exhibit po...
Synthesis of Type II Porous Liquids from Nonporous Metal–Organic Polyhedra Enhanced by Host–Guest Complexation
Abstract The synthesis of Type II porous liquids (PLs) from metal–organic polyhedra, a kind of excellent porous molecular sources, suffers from their strong crys...
A Modular Approach to Asymmetric Mg(I) Complexes Using a Unique Cyclopentadienyl Mg(I) Complex
Abstract The first Mg I complexes with non‐N ligands have been isolated and were fully characterized. Reaction of [(BDI*)...
SiR‐XActin: A Fluorescent Probe for Imaging Actin Dynamics in Live Cells
Abstract Imaging actin‐dependent processes in live cells is important for understanding numerous biological processes. However, currently used natural‐product‐based fluorescent probe...
Design and Structural Transformations of Zinc(II) Knotted Cage Frameworks
Abstract Interwoven architectures feature in biomolecules such as proteins, DNA, and RNA. However, the high‐yielding syntheses and controlled structural transformations of artificial...
The Laccase‐Like Mechanism in Peroxymonosulfate‐Based Oxidation System for Water Decontamination: Dual‐Substrate Activation
Abstract This study demonstrates that direct electron transfer (DET)‐dominated peroxymonosulfate (PMS)‐based advanced oxidation processes (PMS‐AOPs) share a similar oxidation mechani...
Iron‐Catalyzed Tunable Double Bond Migration and Geometrical Isomerization in Olefins via a Spin‐Accelerated Alkyl Mechanism
Abstract Despite the central relevance of metal‐catalyzed alkene isomerization in academia and industry and the overarching role of iron in sustainable catalysis...
Organic Polymer Semiconductor Photocatalysts: From Building Block Design to Controllable Assembly
Abstract Organic polymer semiconductors are emerging as a promising class of photocatalysts because their highly tunable molecular structures and flexible morphological control offer...
Modular Design of Polymer Donors Regulates Solution Aggregation and Stretchability of Organic Solar Cells
Abstract The use of nonhalogenated solvents in organic solar cell (OSC) manufacturing is crucial for environmental sustainability but remains hindered by difficu...
One‐Step Assembly of α‐Aryl‐Substituted DOTAs as Superior and Universal Platforms for Multifunctional Theranostics
Abstract α‐Substituted DOTAs are promising chelators for MRI contrast agents owing to the improved coordination stability and relaxivity of the corresponding Gd(III) complexes. Howev...
Carbonyl‐Anchoring Stabilized Copper Single Sites with Cavity‐Enhanced Mass Transport for Acetylene‐to‐Ethylene Electrosynthesis
Abstract Controlling mass transfer and adsorption in single‐site catalysts is critical for the activity and selectivity of heterogeneous electrocatalytic hydroge...
Counteranion‐Controlled Chemodivergent Transfer‐Hydrothiolation/Carbothiolation Using Thioethers as Bifunctional Reagents
Abstract The pursuit of catalysis capable of forging C( sp 3 )─S bonds is extremely desired because t...
Metal‐Free Sulfur‐Dots Induced Spatiotemporal PhotoRDRP for Multi‐Arm Star Functional Polymer
Abstract Sulfur‐dots (S‐dots) serve as a cost‐effective and non‐toxic alternative to traditional photocatalysts or transition metals typically required in photoi...
Breaking Interference‐Driven Reversal Currents to Boost Single‐Molecule Conductance
Abstract Controlling charge transport in single‐molecule junctions is essential for advancing molecular electronics. This study demonstrates a novel strategy to...
Repurposing Waste Chemicals to Engineer Redox Mediators for Selective Active Species Modulation in Photo‐Fenton‐Like Systems
Abstract Resource recovery from chemical wastes offers significant economic and environmental opportunities. In particular, repurposing recycled materials to con...
Donor−π−Acceptor Conjugated Polymeric Photocatalyst for Efficient Deep Oxidation of NO Facilitated by Strong Asymmetric Local Electric Field
Abstract Photocatalytic conversion of low‐concentration NO x into NO 3 −...
Elucidating the Critical Role of Water in Selective Hydrogenation of <i>N</i> ‐heterocycles on a Cobalt Catalyst
Abstract The ambiguous role of water as a solvent in regulating liquid‐phase hydrogenation activity and selectivity is of great significance to modern organic sy...
Endogenous Template‐Directed Topological Engineering of Lignite‐Derived Hard Carbons for Kinetically Accelerated Sodium Storage
Abstract Coal is a promising precursor for the preparation of hard carbon, which shows great commercial potential as an anode material for sodium‐ion batteries (...
Achiral Catalyst‐Induced Stereoselectivity Switch at Quaternary Stereocenter: Diastereodivergent Ring‐Opening Alkylation and Enantiodivergent Arylation of Oxindoles
Abstract The development of a unified strategy to achieve both diastereodivergence and enantiodivergence is a prominent yet challenging objective. In this study,...
Metal‐Free Singlet Oxygen Generation via Excited‐State Intramolecular Proton‐Transfer‐Driven Intersystem Crossing in 2D Covalent Organic Frameworks
Abstract Singlet oxygen ( 1 O 2 ) is a key reactive species in photodynamic thera...
Directional Electron Transfer in Porphyrin‐Based Heteroleptic Metallacages for Enhanced Visible Light‐Driven Photocatalysis
Abstract The rational design of supramolecular architectures capable of mediating directional photoinduced electron transfer (PET) remains a central challenge in confined photocataly...
The Effect of Cap Structure and Poly(A) Positioning on mRNA Translation Efficiency
Abstract We investigated the relationship between mRNA structure and translation activity using our recently developed chemical method to add a cap structure to an oligonucleotide an...
Supramolecular Engineering of Twisted Intramolecular Charge Transfer (TICT) Dyes into Bright Fluorophores with Large Stokes Shifts
Abstract Twisted intramolecular charge transfer (TICT) dyes are promising candidates for bioimaging and sensing due to their environment‐sensitive fluorescence and large Stokes shift...