Angewandte Chemie International Edition

High‐Conductivity Argyrodite Electrolyte with Self‐Passivating Stability for Single‐Electrolyte All‐Solid‐State Lithium Batteries

Abstract All‐solid‐state lithium batteries (ASSLBs) are promising candidates for next‐generation energy storage due to their enhanced safety and energy density....

Ag ₁₂ [Ge ₉ (Hyp) ₂ ] ₆ An Intermetalloid Cluster with Bis‐Silylated Ge ₉ Units

Abstract We present the synthesis and characterization of the novel intermetalloid cluster compound Ag 12 [Ge...

Regio‐Divergent and Stereo‐Controlled Alder‐Ene Reaction: Harnessing the Unique Electronic and Steric Properties of B(MIDA) Moiety

Abstract 1,4‐Dienes are pivotal structural motifs in bioactive natural products and serve as valuable intermediates in synthetic chemistry. Among the various met...

Inside Front Cover: Insight into the Behavior of Interstitial Electrons in CuZn Alloy‐Functionalized Covalent Organic Framework Catalysts for Enhanced CO ₂ Electroreduction (Angew. Chem. Int. Ed. 4/2026)

Gyroid Labyrinth of Supertwisted Double Helices in a Liquid Crystal Polymer

Abstract A liquid crystal (LC) polymethylsiloxane (PMS) with rod‐like aromatic side‐groups attached via an alkylene spacer and bearing three n‐dodecyl end‐tails is found to form an u...

Beyond Solution Processing: Vacuum Evaporation of Carbazole‐Phosphonic Self‐Assembled Molecules Enables Flexible Perovskite Solar Cells with >25.4% Efficiency

Abstract High‐quality and uniform self‐assembled molecule (SAM) films are critical for the controllable fabrication of high‐performance inverted flexible perovskite solar cells (F‐PS...

Switching CO ₂ Electroreduction Pathways via Polyvinylpyrrolidone‐Mediated Water Configuration Control

Abstract The water configuration plays a critical role in steering the CO 2 electroreduction pathway, yet achieving preci...

Molding of Li _5.5 PS _4.5 Cl _1.5 Particles Based on Regulating Li ⁺ Transport for All‐Solid‐State Li Metal Battery

Abstract All‐solid‐state Li metal batteries (ASSLBs) are coming with sulfide solid‐state electrolytes (S‐SSEs) for superior Li +...

Energy Interception‐Enhanced Ultrasound‐Induced Luminescence Enables Efficient Anticancer Monitoring

Abstract Ultrasound‐induced luminescence (UIL) imaging uses the ultrasound mechanical force to trigger luminescence from different materials within tissue, offering improved signal‐t...

Constructing High‐Efficiency and Stable Hyperfluorescence Blue OLEDs via TADF Sensitizers with Very Short Delayed Lifetimes

Abstract Hyperfluorescence blue organic light‐emitting diodes (OLEDs) are promising for fabricating pure organic blue devices with high efficiency and color puri...

Efficient Solar‐Driven Electrocatalytic Halogen‐Mediated Ethylene Oxidation in Seawater by Metallophthalocyanine‐Based COFs

Abstract The electrocatalytic strategy to convert ethylene (C 2 H 4 ) into high v...

Light‐Induced Orthogonal Reactivity of Photoinitiators from One‐Electron Reduction to Nanocomposites

Abstract Photoinitiators for radical polymerization have been well established. This minireview indicates a palette of applications beyond their original scope. Depending on the expe...

Thermodynamic and Kinetic Separation Within a Flexible Hydrogen Bonded Organic Framework for Ternary Benzene/Cyclohexene/Cyclohexane Mixture

Abstract The separation of benzene (Bz), cyclohexene (CHE), and cyclohexane (CHA) is crucial in the petrochemical industry but remains highly challenging due to...

Activation of Cyanate Anions by Phosphine Radical Cations Enables Formal Hydrocarbamoylation of Alkenes

Abstract Catalytic methods that enable functionalization of alkenes with radical intermediates generated from common feedstock chemicals are valuable in syntheti...

Boosting Magnesium Storage Performance of π‐Conjugated Polyimide Cathodes Through Synergistic Molecular and Electrolyte Engineering

Abstract Magnesium metal batteries (MMBs) offer the promise of low cost, intrinsic safety, and high volumetric energy density, but their development is hindered...

NIR‐II‐Photopyroelectric Catalysis for Immunoactivation/Ferroptosis Combined Therapy of Tumor

Abstract Second near‐infrared (NIR‐II) light is desired to drive photocatalytic therapy owing to its high tissue penetrability and operationality, but the effici...

H ⁺ /OH ⁻ Switchable Coordination Chemistry Enables Sustainable and Selective Critical Metal Recovery from Spent Li‐Ion Batteries

Abstract Sustainable end‐of‐life management of lithium‐ion batteries (LIBs) is essential for minimizing environmental impact and enhancing supply chain resilienc...

Low‐Cost NaNO ₃ ‐Based Phosphate Electrolytes with Exceptional Stability Toward Sustainable and High‐Safety Sodium‐Ion Batteries

Abstract The pursuit of cost‐effective and sustainable sodium‐ion batteries (SIBs) necessitates innovative electrolyte designs to address the limitations of conv...

Biomarker‐Gated Photocatalysis Uncaging in Live System

Abstract Spatiotemporal precision in photocontrolled biochemical reactions remains a central challenge. We report a sequential activation platform that integrate...

Ruthenium Complexes in Protein Science: Heading a New Generation of Therapeutic and Analytical Tools

Abstract Ruthenium complexes are distinguished by their versatile coordination chemistry, redox behaviors and photochemical properties. In recent years, this tunability has enabled p...

Reticular Chemistry‐Guided Topology Engineering of Pillar‐Layer Metal−Organic Frameworks for Boosting SF ₆ /N ₂ Separation

Abstract Pillar‐layered metal−organic frameworks (MOFs) hold high promise in the field of gas adsorption and separation. Capitalizing on reticular chemistry and...

Total Syntheses of Diketopiperazine Alkaloids via Divergent C3–N1' and C3–C5' Bond Anchor

Abstract Diketopiperazine alkaloids are typically soldered via an inner tryptophan–tryptophan linkage diversely from C3–carbon/nitrogen anchor. The manifold ster...

Diazirines Beyond Photoaffinity Labeling: A Comprehensive Overview of Applications in Biological Sciences, Materials Chemistry, and NMR‐Spectroscopy

Abstract Diazirines are well‐known for their role in photoaffinity labeling (PAL) probes, acting as reactive groups to fish out proteins for drug target identification or tag install...

High‐Performance Squaramine Macrocycles as Molecular Sieves for Selective Halogen Separation and Aromatic Bromination

Abstract Selective separation of bromine (Br 2 ) from iodine (I 2 ) remains a fun...

Design of Piezoelectric, Hydrophobic, and Metal‐Free Porous Frameworks for High‐Rate Conversion of Water and Air to Hydrogen Peroxide

Abstract Production of hydrogen peroxide (H 2 O 2 ) as a crucial chemical is impo...