Angewandte Chemie International Edition
Articles in this Issue
Chemistry in Transformation: A European Moment
Abstract Chemistry stands at a pivotal juncture, facing unprecedented expectations to decarbonize, enable circularity, and sustain essential sectors, while remai...
Regiodivergent Chain‐Growth Polymerization of Aza‐π‐Allylpalladium Zwitterions via Proton Transfer
Abstract Proton transfer is a fundamental process in many ring‐opening polymerization (ROP) strategies, imparting precise control over polymer chain growth under...
Engineered Metal–Organic Cages Drive Ultra‐Selective CO <sub>2</sub> Separation from Air
Abstract The urgent challenge of rising atmospheric CO 2 necessitates efficient capture technologies like membrane separa...
Co <sub>1</sub> Zn Single‐Atom Alloy Boosts Active Hydrogen Spillover for Highly Efficient Electrosynthesis of Ammonia Over 2 A cm <sup>−2</sup> Current Density
Abstract Electroreduction of nitrate to ammonia reaction (NO 3 RR) involves a series of hydrogenation steps involving nit...
Coexistence of G‐Quadruplex and i‐Motif Within a DNA Duplex is Tolerated by a PCBP2‐Assisted Replisome
Abstract G‐quadruplexes (G4s) and i‐motifs (iMs) are non‐canonical, four‐stranded DNA structures that are formed in guanine‐ and cytosine‐rich sequences, respect...
Cation Effect‐Engineered Electrocatalytic Interfaces Boost Pure‐Water CO <sub>2</sub> Electrolysis with Optimized Ion Dynamics
Abstract Electrochemical CO 2 reduction in zero‐gap electrolyzers using pure water provides a sustainable pathway for fue...
Modulating Janus Effect of Cations to Control Electronic Symmetry and Hole Mobility in Spiro‐OMeTAD for Perovskite Solar Cells
Abstract Li‐TFSI‐doped Spiro‐OMeTAD (Spiro) remains the benchmark hole transport material in perovskite solar cells (PSCs). The success of Li‐TFSI doping has rei...
Screening Metal Ions to Tailor Carrier Dynamics in Porphyrin‐Based Covalent Organic Polymers for Enhanced Sonocatalytic Pyroptosis and Immunotherapy
Abstract Precise induction of tumor pyroptosis represents an effective strategy to potentiate antitumor immune responses; however, it still confronts challenges...
Electrocatalytic Migratory Carboxylation of Unactivated Olefins or Halides with CO <sub>2</sub>
Abstract Coupling carbon dioxide (CO 2 ) with organic molecules through the electrocarboxylation reaction constitutes a p...
Sequential Phosphorus Doping and Selective Etching: A Dual‐Step Approach for CO <sub>2</sub> Reduction Pathway Regulation in Rhodium Catalysts
Abstract CO 2 hydrogenation is a significant way to reduce carbon emissions, but it is facing serious challenges in selec...
In Situ Coordination‐Assembly Nano‐Drugs/Probes for Enhanced Tumor Retention and Responsive Release
Abstract Improving the retention of probes/drugs in tumor and achieving tumor microenvironment (TME) responsive sustained release are highly desirable but face g...
Reverse Lipid Droplet Function for Hepatocellular Carcinoma Immunotherapy
Abstract Lipid droplet (LD)‐mediated organelle interactions promote tumor progression and immune evasion in tumors, but directly targeting LD remains challenging. Here, we developed...
Symmetric Vs Asymmetric Imide Anion Decomposition Pathways And Their Influence On Solid Electrolyte Interphase Stability For Si Anodes
Abstract A sturdy solid electrolyte interphase (SEI) is imperative for extending the calendar‐life of Si anodes in lithium‐ion batteries (LIBs). However, carbona...
Self‐Compressive Stress Promoting Densification of Proton‐Conducting Electrolyte Membranes
Abstract Dense asymmetric ceramic membranes are key components in solid oxide cells (SOCs) and gas separation technologies. In particular, proton‐conducting SOCs...
Pioneering Interface Configuration with Fermi‐Level Tailoring for Tin Perovskite Photovoltaics
Abstract Tin‐based perovskite solar cells (TPSCs) have attracted attention for their environmentally friendly and high theoretical efficiency. However, their current efficiency remai...
Driving Adsorbate Evolution via Oxygenated Surface Species Modulation for Ammonia Electrooxidation
Abstract The electrochemical ammonia oxidation reaction (eAOR) to dinitrogen offers a promising pathway for sustainable nitrogen cycles and hydrogen generation....
Structure–Reactivity Relationships of Oxime–Oxalate/Glyoxylate/Ester Derivatives: Dual Photo/Thermal Initiators for Visible Light Polymerization and Composite Preparation
Abstract In this study, we reported the design, synthesis, and comprehensive evaluation of a series of nitro carbazole‐based oxime photoinitiators (OPIs, OP1: ox...
Ligand‐Promoted Site‐Selective Regiodivergent Lactamization of Activated δ‐ versus Inert γ‐Methylene C(sp <sup>3</sup> )–H Bonds via Open‐Shell Copper(II) Nitrenoid Catalysis
Abstract Significant advances have been achieved in developing transition metal catalysts capable of regioselectively functionalizing benzylic or tertiary C–H bo...
Photogenerated Radical Amplified D–A–D Metal‐Covalent Organic Frameworks for Highly Efficient Photodynamic Tumor Therapy
Abstract While metal covalent organic frameworks (MCOFs) possess excellent optical properties and electron transport capabilities, their performance in antitumor...
Understanding and Quantifying the Contribution of Oxygen Species in Hydrogen Sensing by Pd/In <sub>2</sub> O <sub>3</sub> Nanosheets
Abstract Conventional metal oxide semiconductor (MOS) hydrogen sensors rely on surface oxygen‐mediated redox reactions, while the distinct contributions of each...
Programmable Microwaveable Chemistry in the Chemputer
Abstract The advancement of laboratory automation relies on both sophisticated control software and modular hardware capable of supporting diverse chemical processes. While microwave...
Ligand Engineering Enhances the Phosphatase Property of Zr‐MOF Nanocrystals as Regulators to Alleviate Plants Phosphorus Deficiency Stress
Abstract This work establishes a structure‐activity relationship to enhance the phosphatase activity of MOF nanozymes and demonstrates a method to alleviate phos...
Scalable Roll‐to‐Roll Dry Processing of 10 mAh cm <sup>−2</sup> Iodine Cathodes for Establishing Ah‐Level Aqueous Zn–I <sub>2</sub> Pouch Cell Evaluation Protocol: Bridging Laboratory Research and Industrial Application
Abstract The deployment of aqueous Zn‐I 2 batteries is limited by inadequate energy density, restricted cycle life and th...
MFI Zeolite Membrane with Surface Mo─O Clusters for Inverse CH <sub>4</sub> /CO <sub>2</sub> Separation
Abstract Separation of methane (CH 4 ) and carbon dioxide (CO 2 ) is of significa...
High‐Entropy Lanthanide Metal‐Organic Frameworks as Multifunctional Porous Scintillators for Radiation Detection and Dual‐Mode Uranyl Sensing
Abstract Despite the burgeoning interest in high‐entropy materials (HEMs), their application as scintillators remains largely untapped. Herein, we report the fir...