Angewandte Chemie International Edition
Articles in this Issue
Multi‐Stimulus Triggered Programmable Transformation of Molecular Motor Based Chiral Supramolecular Polymers in Water
Abstract A notable characteristic of living organisms is their capacity to adapt to environmental changes and transform external signals into distinct responsiveness, facilitating th...
Surface Hydroxyl Network Promoted Hydrogen Transfer Dynamics for Efficient Photocatalytic Acetylene Semi‐Hydrogenation
Abstract Photocatalytic semi‐hydrogenation of acetylene (C 2 H 2 ) to ethylene (C...
Total Synthesis of (+)‐Melonine and (+)‐ <i> N <sub>4</sub> </i> ‐Oxy Melonine Enabled by an Intramolecular Alkene Diamination Reaction
Abstract Among more than four thousand monoterpene indole alkaloids (MIAs) isolated to date, only a few feature a 2,2,3‐trisubstituted indoline moiety. (+)‐Melon...
Paired‐Cell Ammonia over Black CoWO <sub>4</sub> via Electrocatalysis–Acidification Cascade from Wastewater at Ampere‐Level Current Density
Abstract Electrochemical nitrate reduction to ammonia (NO 3 RR) offers a sustainable alternative to the energy‐intensive...
Understanding the Entropy Decoupling for Ion Transport in Ordered Biomimetic Materials Toward Durable Aqueous Zinc Metal Batteries
Abstract Aqueous zinc metal batteries (AZMBs) have emerged as promising candidates for next‐generation grid‐scale electrochemical energy storage system, while their development is st...
Non‐Statistical Assembly of Donor–Acceptor Cages for Light‐Induced Charge Separation
Abstract We report light‐triggered charge separation in two discrete supramolecular architectures that self‐assemble in a single step from donor (...
Catalytic 1,2‐ and 1,1‐Carbocyclization of Alkenes Employing Adamantanols as Tertiary Carbocation Precursors
Abstract Catalytic alkene cyclization initiated by carbon electrophiles represents an emerging strategy for constructing valuable and challenging molecular architectures. However, du...
Selective N‐Terminal Modification of Peptides and Proteins Using Fatty Acyl Phosphates
Abstract The selective modification of proteins and peptides is an important chemical biology tool with a wide variety of applications, including the production of biopharmaceuticals...
Pore Space Multi‐Layer Functionalization Boosting Industrial Radioactive Iodine Capture with Record Capacity and Exceptional Kinetics
Abstract Capturing radioactive molecular iodine (I 2 ) from nuclear waste under industrial conditions remains a considera...
Redox‐Neutral Cu‐Catalyzed Cyclative γ‐C–H Functionalization Enroute to Aza‐ and Oxo‐heterocycles
Abstract Cyclative C(sp 3 )–H functionalization of unactivated C─H bonds with heteroatoms is a straightforward way to con...
Fluorogenic Rhodamine Probes Enable High‐Resolution Visualization of Plasma Membrane Nanostructures
Abstract The plasma membrane exhibits diverse substructures, such as pseudopodia, membrane nanotubes, and migrasomes, that are essential for cellular communicati...
Chemoenzymatic Synthesis and Antigenicity Evaluation of an O‐Antigen Octadecasaccharide from <i>Helicobacter pylori</i>
Abstract Helicobacter pylori infection represents a major global health challenge, characterized by high prevalence, significant association...
Water‐Processable Covalent‐and‐Supramolecular Polymeric Binders for Silicon/Carbon Anodes with High Interfacial Stability in Lithium‐Ion Batteries
Abstract Silicon/carbon (Si/C) composite anodes are among the most promising candidates for high‐energy‐density lithium‐ion batteries but suffer from severe volu...
Acid‐Programmed Generation of Coordination, Ionic, and All‐In‐One Cu(I) Chloride Architectures with Highly Efficient Luminescence
Abstract Copper(I)‐based hybrid halides feature highly designable structures, systematic tunability, and excellent photoluminescence; however, developing design...
Self‐Assembled Metal‐Polyphenol Colchicine Nanoparticles Targeting Oxidative Stress and Inflammation for Treatment of Atherosclerosis
Abstract Anti‐inflammatory colchicine therapy has emerged as a new era for atherosclerotic cardiovascular diseases. However, the therapeutic benefit of colchicin...
Dual Modification Strategy of Ionic Liquid for Durable Perovskite Photovoltaics
Abstract The inverted perovskite solar cell (PSC), featuring self‐assembled monolayers (SAMs) as the hole transport layer, has achieved a power conversion effici...
Synergistic Effects of Electricity and Light for Efficient Iron‐Catalyzed Recycling of Polystyrene Waste
Abstract Due to their intensive use in every aspect of our everyday life, plastics are accumulating in the environment, hence representing a major societal challenge. The accumulatio...
Selectively Electrocatalytic Reductive Dehydroxylation of 2‐butene‐1,4‐diol to 3‐buten‐1‐ol over Cu Nanowire Arrays at Industrial Current Densities
Abstract Electrocatalytic reductive dehydroxylation is a promising strategy for sustainable synthesis of commodity and high‐value‐added chemicals but remains a f...
Facet‐Dependent Solid Frustrated Lewis Pairs on Co <sub>3</sub> O <sub>4</sub> Catalysts Towards Semi‐Hydrogenation Reaction of Alkynols
Abstract The semi‐hydrogenation of alkynols to enols represents a vital industrial reaction for fine chemical synthesis, yet developing highly selective non‐nobl...
Solar‐Biohybrid Upcycling of Polylactic Acid Plastics to Alanine
Abstract Upcycling of waste plastics into commodity chemicals such as amino acids represents a promising route toward achieving negative carbon emissions and ena...
Salt Cluster With Surface Defect Shows Anomalous Acid–Base Chemistry
Abstract The acid displacement reaction of formic acid in sea‐salt aerosols to release hydrogen chloride is an enigma in atmospheric chemistry: a weak acid trans...
Long‐Wavelength Light‐Induced Group 13–15 Elementalization Reactions of Alkenes/Alkynes
Abstract We present di‐ tert ‐butyl peroxide (DTBP)‐catalyzed long‐wavelength light‐induced Group 13, 14, and 15 elementa...
Growth, Dissolution and Segregation of Genetically Encoded RNA Droplets by Ribozyme Catalysis
Abstract Active droplets, membraneless compartments driven by internal chemical reactions, are compelling models for protocells and synthetic life. A central challenge is to program...
Ga‐Induced Reversal of Pd Electronic States in ZrO <sub>2</sub> ‐Supported Pd <sub>2</sub> Ga <sub>1</sub> Nanoparticles for Enhanced Ethanol Electrooxidation via the C1 Pathway
Abstract Direct ethanol fuel cells (DEFCs) are recognized as a promising energy conversion technology due to their high energy density and the renewable, eco‐fri...
Radical Electroprecipitation from a Water|Oil|Electrode Interface Prolongs “Electro”Chemiluminescence of the Tris(2,2′‐bipyridyl)Ruthenium(II) and Benzoyl Peroxide System by 10 <sup>3</sup>
Abstract Reactive intermediates, including radicals and other short‐lived molecules, are ubiquitous in pure chemical processes and often highly difficult to isol...