Angewandte Chemie International Edition
Articles in this Issue
Efficient I <sup>−</sup> /I <sub>3</sub> <sup>−</sup> /I <sub>2</sub> Conversion and Shuttle‐Suppression in High‐Rate Ah‐Level Zinc‐Iodine Batteries Enabled by Bifunctional Confined‐Catalyst ZrB <sub>2</sub> /AC Host
ABSTRACT Rechargeable aqueous Zn||I 2 batteries have received significant attention for the high energy density, inherent...
Ultrastable Heterocluster Metal‐Organic Framework Scintillator via Reticular Armoring of Iodocuprate Modules for X‐ray Imaging
ABSTRACT Metal‐organic framework (MOF)‐based scintillators promise advanced X‐ray detection and imaging by virtue of their structural tunability. However, the si...
Delayed Halide‐Rich Molecular Passivation of CsPbCl <sub>3</sub> Perovskite Nanocrystals Enables Bright Violet Light‐Emitting Diodes
ABSTRACT CsPbCl 3 perovskite nanocrystals (NCs) are promising violet emitters owing to their narrow emission and high col...
Nanoconfinement Enabled High‐Efficiency and Long‐Lifetime Multicolor Afterglow Hydrogels for Advanced Spatiotemporal Encryption and Pathogen Eradication
ABSTRACT Multicolor organic afterglow hydrogels that simultaneously possess efficient exciton harvesting, ultralong lifetimes and large deformations are still rare. Here, a nano‐rest...
Manipulating Heavy Halogenated Asymmetric Terminals Affords Regio‐Regular Hetero‐Fluorinated/Brominated Dual Asymmetric Acceptor With a Binary Photovoltaic Efficiency of 20.3%
ABSTRACT Asymmetric terminal engineering of small molecular acceptors (SMAs) is one promising approach to efficient organic solar cells (OSCs), while synthesizin...
Protonation‐Triggered Fluorescence Switching in COF Membranes for the Selective and Rapid Detection of New Psychoactive Substances
ABSTRACT New psychoactive substances (NPS) typically exhibit low saturated vapor concentrations and are susceptible to interference such as water vapor and carbo...
Boron‐Doping of a Macrocyclic Tetrafuran Framework Unveils an Expanded Porphyrinoid With Switchable (Anti)Aromaticity and Conformational Dynamics
ABSTRACT Expanded porphyrinoids are an emerging class of organic chromophores with often exceptional optoelectronic properties such as broad absorption extending...
Precise Modulation of Excited‐State Energy Flow via Consecutive Twisted Intramolecular Charge Transfer (ConTICT) for Autophagy‐Blocking Photothermal Therapy
ABSTRACT The efficacy of photothermal therapy is fundamentally governed by the efficiency of non‐radiative decay; however, current organic photothermal agents ar...
Iterative Synthesis of Pentacene Derivatives with Continuous Boron–Oxygen Bonds
ABSTRACT Iterative syntheses—repeating sequences of the same reactions to construct complex molecules—can facilitate the synthesis of specific classes of small m...
Interfacial Water Reorientation in Gadolinium‐Doped Ru/RuO <i> <sub>x</sub> </i> Heterostructures Boosts Alkaline Hydrogen Oxidation Electrocatalysis
ABSTRACT The sluggish proton transfer in alkaline electrolytes severely limits hydrogen oxidation reaction (HOR) kinetics of fuel cells. Although the orientation...
Ligand‐Switched Regiodivergent Fluoroallylic Alkylation of Secondary Nitroalkanes via an Unusual Inner‐Sphere Pathway
ABSTRACT As one of the cornerstones of modern organic synthesis, the Tsuji–Trost reaction is fundamentally governed by the “hard–soft” characteristics of nucleop...
Cs <sub>3</sub> Bi <sub>2</sub> Br <sub>9</sub> Quantum Dots‐Driven Photogenerated Bromine Radical Relay Enables Efficient Cleavage of C <i> <sub>α</sub> </i> /C <i> <sub>β</sub> </i> ─O Bonds for Lignin Depolymerization
ABSTRACT With the remarkable activation efficiency, hydrogen atom transfer (HAT) strategy has emerged as a promising approach for promoting lignin depolymerizati...
Electrolyte Covalent Organic Frameworks for Exceptional Potassium Ion Conduction
ABSTRACT In this research we report the concept and strategy of electrolyte covalent organic frameworks for high‐rate low‐activation‐energy potassium ion conduct...
Dimeric Self‐Assembled Monolayer Materials for High‐Performance Perovskite and Perovskite/Organic Tandem Solar Cells
ABSTRACT While perovskite/organic tandem solar cells (POTSCs) hold great potential in terms of power conversion efficiencies (PCEs), achieving highly efficient P...
Self‐Limiting Polymerization‐Induced Crystallization‐Driven Self‐Assembly (SL‐PI‐CDSA) Enables Templated Synthesis of Chiral Plasmonic, Hybrid 2D Hexagonal Assemblies
ABSTRACT Examples of self‐regulating synthetic self‐assembly are relatively few, with most known chemical systems relying on kinetic rather than thermodynamic co...
An Artificial Molecular Pump Powered by Light
ABSTRACT Replicating the ability of biological systems to convert energy into directional molecular motion to perform functions is a central challenge in nanoscience. Artificial mole...
Polyfluoroalkyl‐Tagged Cell‐Penetrating Peptide‐Additives Enhance Intracellular Protein Delivery via Sustained Monomeric Lipid Interaction
ABSTRACT Recent advances in cell‐penetrating peptide (CPP)‐mediated intracellular protein delivery emphasized the critical role of sustained membrane association in enhancing deliver...