Angewandte Chemie International Edition
Articles in this Issue
Engineering Ultrahigh‐Contrast Photoactivated Room‐Temperature Phosphorescence With a Robust and Universal Ureido‐Functionalized Siloxane Network
ABSTRACT Photoactivated room‐temperature phosphorescence (pRTP) host‐guest systems have received widespread attention due to their non‐invasive photoresponsiveness, high reversibilit...
Life‐Cycle‐Integrated Molecular Design of Hindered Phenylene Biacetal Epoxies for Practical Recyclable Composite Applications
ABSTRACT Carbon‐fiber reinforced polymer (CFRP) composites are central to lightweight wind‐energy infrastructure but suffer from poor end‐of‐life circularity due...
Electroactive Metal–Organic Frameworks Enabling Unidirectional Electrochemical Capacitors and Logic Gates (MOF‐CAPode)
ABSTRACT From concept to realization, the integration of porous redox‐active metal–organic frameworks (MOFs) into asymmetric electrochemical capacitors for the a...
Solar‐Driven Photocatalytic C─S Coupling for Organosulfur Synthesis Via Upcycling SO <sub>2</sub> and Plastic Waste
ABSTRACT Hydroxymethylsulfonate (HMS) is an important cleaning agent in the electronics industry and serves as a crucial intermediate in the synthesis of surfact...
Outside Front Cover: Polyfluoroalkyl‐Tagged Cell‐Penetrating Peptide‐Additives Enhance Intracellular Protein Delivery via Sustained Monomeric Lipid Interaction (Angew. Chem. Int. Ed. 23/2026)
Strategies Toward Accessing Enantioenriched (Hetero)Benzo‐Fused 5‐ and 6‐ Membered Rings via Intermolecular Carbometalation
ABSTRACT Enantioenriched benzofused 5‐ and 6‐ membered rings continue to be found as notable motifs in important molecules such as pharmaceuticals and natural pr...
Inside Back Cover: Mapping the Reactivity of the C═C Bond of Cyclic Enol Ether Derivatives of Sugars: Nucleophilicity Parameters of Glycals (Angew. Chem. Int. Ed. 23/2026)
Unveiling the Valence‐Driven Charge Compensation Mechanism to Direct Phase Engineering in Ru‐Based Catalysts for Acidic Water Electrolysis
ABSTRACT Phase engineering is pivotal for optimizing the electronic structure and reaction pathways of electrocatalysts, balancing high‐efficiency charge transfe...
Azide‐to‐Diazo Transformation Facilitated by Michael Addition via Phosphazide Formation
ABSTRACT A new type of Michael addition of thiols and amines to 2‐azidoacrylic acid esters through azide‐to‐diazo conversion is disclosed. This unusual transform...
Unimolecular Organic Afterglow Luminophore With Anti‐Kasha/Kasha Emission for in Vivo Activatable Imaging
ABSTRACT Afterglow luminescence holds great promise for biomedical imaging by eliminating tissue autofluorescence. Unimolecular afterglow systems avoid the need...
Asymmetric Vacancies Efficiently Couple O <sub>2</sub> Activation With Reactive Oxygen Species Evolution for Enhanced Photocatalytic Methane Conversion
ABSTRACT Photocatalytic oxidation mediated by reactive oxygen species (ROS) provides an effective platform for a wide range of important chemical transformations...
Petra Utroša
A Chiral Multifunctional Phosphine Ligand for Gold‐Catalyzed Diastereo‐ and Enantioselective Cyclization of Yne‐enones/Enol‐Addition
ABSTRACT The Au(I)‐catalyzed asymmetric cascade cyclization of yne‐enones/addition represents a powerful strategy for constructing furan skeletons; however, the use of enol‐type carb...
Large‐Scale Profiling of Kinase Degradation by Using Norbornene‐Based Hydrophobic Tag (HyT) Strategy
ABSTRACT Hydrophobic tags (HyTs) are promising bifunctional protein degraders that mimic misfolded proteins to trigger quality control‐mediated target degradation, offering key advan...
Convergent Total Synthesis of 16β‐Hydroxylpseudobufarenogin
ABSTRACT 16β‐Hydroxylpseudobufarenogin ( 1 ), isolated from the venom of Bufo bufo gargarizans...
Outside Back Cover: Domino Polymerization for the Synthesis of Reductively Degradable Poly(disulfide)s With Arbitrary Side‐Chain Structures (Angew. Chem. Int. Ed. 23/2026)
Boosting Built‐in Electric Field via COF Molecular Quadrupole Gradients for Efficient H <sub>2</sub> O <sub>2</sub> Photosynthesis
ABSTRACT Covalent organic frameworks (COFs) are promising photocatalysts for hydrogen peroxide (H 2 O...
Stiffness Reinforcement in Polymer Networks Through Supramolecular Topological Linking
ABSTRACT Polymer networks possess numerous elastically defective and isolated loops, which do not contribute to mechanical stiffness. In this report, we introduce a strategy of supra...
Process‐Driven Protonation in Benzothiadiazole‐Integrated Covalent Organic Frameworks: Activation of Peroxymonosulfate for Pollutant Oligomerization via Dominant Electron Transfer Process
ABSTRACT Traditional peroxymonosulfate (PMS) activation typically follows a static, catalyst‐centered paradigm, constrained by radical‐mediated pathways with lim...
Inside Front Cover: Enhancing Superlubricity and Wear Resistance in Mechanically Robust Hydrogel via Microliter‐Scale Subsurface‐Initiated Polymer Brush Grafting (Angew. Chem. Int. Ed. 23/2026)
Inter‐molecular Channel Gated Ion Migration for High Performance Zinc‐ion Batteries
ABSTRACT Aqueous zinc‐ion batteries (AZIBs) are plagued by dendrite growth and parasitic side reactions, which severely hinder their stable operation. Inspired b...
Schottky‐Orbital Coupling Drives Ion‐Electron Transfer: Triggering Stable Fast‐Charging in MnV‐Based Phosphate Cathode
ABSTRACT Na 4 MnV(PO 4 ) 3 , characterize...
Customized NIR‐II Dual‐Phase Carbon Dots: Elucidating the Emission Mechanism for Smart Photonic Applications
ABSTRACT Carbon dots (CDs) exhibiting dual‐phase photoluminescence (PL) in the second near‐infrared window (NIR‐II, 900–1700 nm) region have shown considerable potential for applicat...
Gradient Valence Engineering Synchronizes Charge‐Carrier and Catalytic Dynamics for Efficient Solar Water Oxidation
ABSTRACT The efficiency of photoelectrochemical water splitting is constrained by the kinetic mismatch between ultrafast charge separation and slow catalytic tur...
Atomic‐Scale Understanding of Selectivity Control in Nitrate Reduction on Cu(100) Under Acidic and Alkaline Conditions
ABSTRACT We investigate the nitrate reduction reaction (NO 3 RR) on the Cu(100) surface using grand‐canonical density fun...