Angewandte Chemie International Edition
Articles in this Issue
Domino Polymerization for the Synthesis of Reductively Degradable Poly(disulfide)s With Arbitrary Side‐Chain Structures
ABSTRACT The environmental persistence of conventional plastics has driven the development of degradable polymers with functional versatility. Poly(disulfide)s a...
Chiral Self‐Sorting Assembly of Au <sub>16</sub> Rings for Cancer Therapy via Enantioselectivity‐Induced Ferroptosis and Apoptosis
ABSTRACT Chirality‐induced biochemical response has emerged as a prominent research focus. This research demonstrates the chiral self‐sorting assembly of atomica...
Bypassing Hydrogenation Pathway for Sustainable Nitrate Water Remediation via Direct N─N Coupling
ABSTRACT Catalytic nitrate (NO 3 − ) reduction (CNR) to dinitrogen (N 2...
Inhomogeneous Strain‐Modulated Phonon Scattering Sustains Hot Electrons for Enhanced Enzymatic Therapy
ABSTRACT Enzymatic therapy holds potential as a tumor therapeutic approach, yet enhancing the catalytic activity of nanozymes remains a challenge in tumor cells....
Diffusion‐Selective Tandem Catalysis for Alkane Hydroisomerization
ABSTRACT The molecular diffusion behaviors in catalytic systems can influence product selectivity. Such a phenomenon, analogous to shape selectivity in zeolite catalysis, can be refe...
Solvent‐Controlled Pathways Enable Structure‐Programmable Metal‐Organic Framework Membranes for Isomer Separation
ABSTRACT The separation of structurally similar aliphatic and aromatic isomers remains a critical industrial challenge, as their nearly identical sizes render co...
Temperature‐Responsive Evolution and Mechanism Exploration of Static and Dynamic Solvation Structures in Localized High‐Concentration Electrolytes
ABSTRACT Solvation structures in localized high‐concentration electrolytes (LHCEs) critically govern ion transport and interfacial reactions. However, the temperature mismatch betwee...
Trinity Cooperative Electrode as a High‐Performance Electrocatalytic Host for Ultra‐Stable, High‐Rate Zinc–Halogen Batteries
ABSTRACT Aqueous zinc–halogen batteries (ZHBs) offer safety and low cost but are hindered by halogen dissolution, shuttle effects, and sluggish interfacial kinet...
Logic‐Gated Molecular Machines Encapsulate Environment‐Responsive DNA Actuators for Tunable Cellular Lysosome Interference
ABSTRACT Intracellular DNA nanoassemblies have proven to potently induce organelle dysfunction and cell death, while their scale‐dependent capacity of cellular interference remains u...
Why Is Methanol Formation Suppressed in CO <sub>2</sub> Reduction Over Copper Electrocatalysts?
ABSTRACT Electrocatalytic CO 2 reduction (CO 2 RR) to produce methanol (CH...
Quasi‐Crowding Solvation Design of Ionic Liquid Electrolytes for Stable High‐Temperature Potassium‐Ion Batteries
ABSTRACT A quasi‐crowding solvation structure design principle was proposed to develop phosphate‐mediated ionic liquid electrolyte (PILE), enabling high ionic conductivity, low desol...
Empowering Reversible Anionic Redox in Sodium Layered Oxide Cathodes via Ionic Impedance Matching Interphase
ABSTRACT Anionic redox reaction (O 2− /O − , ARR) in low‐cost sodium manganese‐ba...
Precisely Controlled Electrochemical Phosphonylation: Tailoring π‐Conjugated Polymer Properties for High‐Performance Organic Electrochemical Transistors
ABSTRACT To achieve high performance, organic electrochemical transistor (OECT) channels must support efficient transport of electronic charges and ions. When de...
Spin‐State Engineering of Ni Centers by Dual‐Ligand Competitive Coordination for Superior Oxygen Evolution Reaction
ABSTRACT Modulating electronic spin states of metal active centers is an effective strategy to address the sluggish oxygen evolution reaction (OER) kinetics. Her...
Unraveling the Crystal‐Field‐Mediated Cobalt Spin‐State Evolution for Electrocatalytic Ethylene Glycol Oxidation by In Situ X‐Ray Emission Spectroscopy
ABSTRACT The electrocatalytic oxidation of polyethylene terephthalate (PET) derived ethylene glycol (EG) into valuable formate and hydrogen represents a sustaina...
Dissimilar Electrolyte Decouples Zn and MnO <sub>2</sub> Redox Chemistry Enabling Dual‐Electrode‐Free Lean‐Electrolyte Batteries
ABSTRACT Dual‐electrode‐free Zn–MnO 2 batteries offer exceptionally high theoretical energy density (616 mAh g...
Photo‐Tautomerization‐Driven Energy Transfer at the Hole‐Transport Interface Stabilizes Efficient Inverted Perovskite Solar Cells
ABSTRACT Perovskite solar cells (PSCs) offer high power conversion efficiencies (PCEs) but suffer from UV‐induced degradation, hindering their practical deployme...
Thermally Induced Macromolecular Sequence Inversion in Triblock Copolymers and Terpolymers
ABSTRACT Dynamic control over polymer sequences remains a major challenge in synthetic macromolecules, limiting their adaptability relative to biomacromolecules. Herein, we introduce...
Spatially Proximate Acid Sites in Zeolites Synergistically Boost Alkane Activation
ABSTRACT The activation of light alkanes on zeolites has long been attributed to strong Brønsted acid sites (BAS), a focus that has constrained further catalyst...
Single‐Atom/Nanocluster Synergistic Electrode Derived From Phthalocyanine Salts for Efficient Electroreduction of Nitrate to Ammonia
ABSTRACT Electrochemical nitrate reduction reactions to ammonia represent a promising route to close the global nitrogen cycle, but their practical implementatio...
Light‐Induced Chiral Aldehyde/Palladium Catalysis‐Enabled Asymmetric Allylic C─H Alkylation of Alkenes With NH <sub>2</sub> ‐Unprotected Amino Acid Derivatives
ABSTRACT The catalytic asymmetric allylic C–H alkylation of alkenes with the α‐carbon of readily available amino acid derivatives represents an ideal strategy fo...
Tuning Selectivity in Reductive Amination Through Orbital Symmetry Engineering of Metal‐Organic Supports
ABSTRACT Controlling selectivity in the reductive amination of carbonyls, a pivotal green route to amines, remains a long‐standing challenge within complex react...
Homoleptic and Heteroleptic Carbones L1‐C‐L2
ABSTRACT Quantum chemical calculations using density functional theory at the BP86‐D3(BJ)/def2‐TZVPP level and ab initio theory at the CCSD(T)/def2‐TZVPP level h...
Ribozymes for RNA‐Catalyzed RNA Methylation and Labeling
ABSTRACT RNA is a cornerstone of life, executing diverse essential functions. A key determinant of RNA's functional versatility lies in natural nucleoside modifications, which greatl...
Spatial Solvation Regulation by a Swollen Polymer Interphase Enables Ultrastable Sodium Metal Batteries
ABSTRACT Sodium (Na) metal batteries are considered promising candidates for next‐generation electrochemical energy storage because of their low costs and high e...