Angewandte Chemie International Edition
Articles in this Issue
Tuning Local Charge‐Density in COFs to Suppress Protonation and Unlock Binding Sites for Efficient Palladium Recovery
ABSTRACT Imine‐linked COFs are increasingly being used to recover palladium from aqueous waste streams, but the binding sites undergo protonation in acidic media...
Stereospecific Epoxide‐to‐Cyclopropylamine Conversion by a Homologous Horner–Wadsworth–Emmons‐Type Reaction With an Imine‐Substituted Phosphine Oxide
ABSTRACT We report a homologous Horner–Wadsworth–Emmons‐type reaction of an imine‐substituted phosphine oxide with epoxides, enabling a formal O‐to‐C(NH...
Polymorphism‐Controlled Exciton Dissociation in Hydrogen‐Bonded Organic Framework Photocatalysts
ABSTRACT Organic photocatalysts have attracted extensive attention, while multiple interrelated factors influence photocatalytic activity, making it challenging...
High‐Throughput Virtual Screening of Small Molecule Quenchers for Near‐Infrared Fluorophores
ABSTRACT Energy transfer (EnT)‐based near‐infrared (NIR) fluorescent probes are preferred for biosensing due to their low phototoxicity, deep photon penetration, and high signal‐to‐n...
Aggregation‐Induced Doping Enhancement Enabled by Non‐Covalent Conformation Locking on Conjugated Polyelectrolyte Toward Efficient Hole Collection in Organic Solar Cells
ABSTRACT The development of anode interlayers (AIL) with a non‐corrosive nature and good compatibility with large‐area fabrication techniques has long been an im...
Silver Cluster‐Mediated Polyoxotantalate 1D Molecular Heterostructure Toward Ultra‐Low‐Loss Active Optical Waveguides and Information Coding
ABSTRACT This work investigates the first one‐dimensional (1D) silver cluster‐mediated polyoxotantalate molecular heterostructures of ‐[Ag 9...
Leveraging Molecular Weight Dispersity for Scalable, Precise Synthesis of Nanocylinders Via Quasi‐Polymerization‐Induced Self‐Assembly
ABSTRACT The scalable and precise synthesis of polymeric nanostructures represents a significant challenge due to the inherent trade‐off between production effic...
Ligand‐Enabled Stereoselective Coupling of Methylene C(sp <sup>3</sup> )─H Bonds With Alkenyl Bromide via Pd <sup>II</sup> /Pd <sup>0</sup> /Pd <sup>II</sup> Catalysis
ABSTRACT Utilizing C(sp 3 )─H bonds as coupling partners for the formation of C(sp 3...
Iron‐Catalyzed Asymmetric <i> NH <sub>2</sub> </i> ‐Amination of Sulfenamides
ABSTRACT The increasing prominence of stereogenic‐at‐sulfur motifs in drug discovery and catalysis has created a growing demand for versatile synthetic methods....
A Radial‐Linear π‐Conjugated Polymer by Integrating Poly(Para‐phenylene Vinylene) and Cycloparaphenylene for Enhanced Optoelectronic and Electrochemical Performance
ABSTRACT Herein, we present a new class of hybrid conjugated polymer that integrates [8]cycloparaphenylene ([8]CPP) directly into poly(para‐phenylene vinylene) (...