Angewandte Chemie International Edition
Articles in this Issue
Balancing Dimerization and Hydrogenation Kinetics by Stabilizing Cu <sup>+</sup> and Tightening H‐Bond Network for Electrocatalytic Acetylene Hydrodimerization
ABSTRACT The electrocatalytic hydrodimerization of acetylene (EHDA) offers a promising alternative to energy‐intensive naphtha steam cracking for producing 1,3‐b...
Atomically Dispersed Iron‐Catalyzed Aerobic Hydroxylation of Allylic and Propargylic C─H Bonds
ABSTRACT Selective functionalization of carbon–hydrogen bonds represents a central goal in modern organic synthesis, yet achieving site‐ and chemoselective oxida...
Homogeneous/Heterogeneous Catalyst Design for Lithium–Sulfur Batteries via Phase Separation
ABSTRACT The dual regulation of sulfur redox kinetics and lithium deposition behavior represents a pivotal breakthrough toward overcoming the performance limitat...
Atroposelective Dearomative Cross‐Coupling of Benzofuran Derivatives by Z‐Selective Functionalization of the Vinyl C─O Bond
ABSTRACT Catalytic asymmetric transformation of benzofuran derivatives has received significant attention owing to its capacity to prepare chiral molecules from...
Outside Back Cover: Selective Synthesis of [2]Rotaxane Orientational Isomers With Precisely Arranged Luminogens: Toward Orientation‐Dependent Emissions for Information Storage and Encryption (Angew. Chem. Int. Ed. 33/2026)
Coordination‐Engineered Interfacial Pathway Partitioning for Electrocatalytic CO <sub>2</sub> Conversion and Downstream Upgrading
ABSTRACT Electrochemical CO 2 reduction (eCO 2 RR) is increasingly capable of del...
Coordination Engineering of Ir─Mo Atomic Pair Sites to Break Scaling Limitations for Acidic Oxygen Evolution
ABSTRACT Coordination engineering of single‐atom catalysts (SACs) is a powerful strategy to address durability and activity challenges in the acidic oxygen evolu...
Intracellular Proton Enrichment Drives Unified Dual‐Cofactor Regeneration for Biohybrid CO <sub>2</sub> Fixation
ABSTRACT Photocatalytic biohybrid systems, which interface photosensitizers with whole‐cell biocatalysts, represent a platform for sustainable solar‐to‐chemical...
Activating π‐Electron Conjugated Networks of Self‐Assembled Multilayers for 21.1% Efficiency Organic Solar Cells
ABSTRACT Self‐assembled monolayers suffer from the insufficient electrical conductivity, stemming from their ultrathin nature and disordered molecular orientatio...
Inhibition and Formation of Amyloid Fibrils in the Bulk and at the Interface of Biomolecular Condensates
ABSTRACT Cells can form open compartments, known as biomolecular condensates, which possess distinct environments and concentrations compared to their surroundings. These biomolecula...
Valency‐Controlled Multiphotochromism: Gated Switching and Photoswitchable Lewis Superacidity at Silicon
ABSTRACT Multiphotochromic systems promise multistate molecular information storage, yet strategies to control their switching‐state distributions and interchromophore communication...
Ordered Pt <sub>3</sub> Mn Intermetallic Nanoparticles Supported on Atomically Dispersed Mn–N–C as Electrocatalysts for Fuel Cells
ABSTRACT Compared with conventional solid‐solution alloy nanoparticles with disordered atomic structures, platinum (Pt)‐based intermetallic compounds (IMCs) are...
Redox Chemistry Enables Excellent Capacity and Ultra Long Life Aqueous Ammonium Ion Batteries
ABSTRACT Ammonium‐ion batteries are promising for energy storage with low cost, high ionic conductivity, and excellent safety. However, their long‐term cycling s...
Boosting Natural Rubber Performance by Backbone Rigid Functionalization
ABSTRACT Natural rubber relies on irreversible vulcanization to enhance material performance, but the resulting densely crosslinked networks resist breakdown, rendering conventional...
Amidase‐Catalyzed Desorption of CO <sub>2</sub> Captured in Aqueous Monoethanolamine (MEA) Solutions
ABSTRACT Aqueous monoethanolamine (MEA) solutions can absorb CO 2 from industrial point sources via amine scrubbing. Mech...
Modern Cyanine Dye‐Based Photosensitizers for Medical Applications
ABSTRACT The emergence of photochemical technology has revolutionized the fields of biology and medicine. Among them, photodynamic therapy represents a highly precise oncological tre...
Regiodivergent Hydrogermylation of Alkynes Enabled by Dinuclear Cobalt Catalysts Bearing Different Ligands
ABSTRACT Transition‐metal‐catalyzed hydrogermylation of alkynes represents an ideal atom‐economical method to prepare vinylgermanes that are valuable reagents in...
Molecular N‐Type Doping Unlocks Low‐Threshold Nanosecond Lasing in a Microcavity‐Integrated OLED Toward Electrically Pumped Organic Lasers
ABSTRACT Organic semiconductors are attractive for the development of flexible, wavelength‐tunable lasers. However, most reported organic micro/nanolasers rely on femtosecond‐pulsed...
Precise Multi‐Site Borylation Engineering of Indolo[2,3‐c]Carbazole‐Bridged Narrowband MR‐TADF Emitters
ABSTRACT Indolocarbazole‐bridged double‐boron multi‐resonance thermally activated delayed fluorescence (MR‐TADF) materials enable precise modulation of emission...
A Self–Cascade Nanozyme of Metformin–Stabilized Amorphous Iron Oxide With Ultrahigh Fe(II) for Potent Tumor Therapy at Ultralow Dose
ABSTRACT The therapeutic efficacy of iron oxide nanozymes in cancer catalytic therapy has been severely constrained by the insufficient endogenous H...
Positive Electrochemical Potentials Induce Enhanced Chemoselectivity and Activity in the Thermocatalytic Hydrogenation of 3‐Nitrostyrene
ABSTRACT Electrochemical promotion of catalysis is emerging as a powerful approach to control chemical reactions externally without complex catalyst modification, but this has mostly...
Atomically Engineered RuO <i> <sub>x</sub> </i> ‐Cu Interfaces Enabling Tandem Catalysis for Ampere‐Level Nitrite–Ethanol Co‐Electrolysis
ABSTRACT Designing tandem catalysts with well‐defined interfacial architectures is of great significance for promoting multi‐step electrochemical transformations...
Fibers and Double‐Layered Tubes Formed From a Single Self‐Complementary DNA Oligonucleotide
ABSTRACT This study reports the first observation that a short self‐complementary DNA oligonucleotide can self‐assemble into two distinct liquid‐crystalline arch...
Crystalline Small Molecule‐Polymer Superlattice for Spatially Isolated Tetrathiafulvalene Spin Qubit Arrays
ABSTRACT Molecular electron spins are compelling qubit candidates; however, mitigating their rapid relaxation and decoherence driven by structural disorder and p...
Mimicking Overall Photosynthesis by Incorporating Paired Ce(III) Single‐Atom Sites Into Covalent Organic Framework
ABSTRACT Artificial photosynthesis that mimics overall photosynthesis towards converting CO 2 and H 2...