Angewandte Chemie International Edition
Articles in this Issue
Highly Sensitive Thianthrene Covalent Trimer Room‐Temperature Phosphorescent Materials for Low‐Concentration Oxygen Detection
Abstract Oxygen is ubiquitous and vital to life, industry, and environmental safety, so accurate and reliable oxygen sensing and detection are of great significance, especially for o...
Photoelectrochemical Iron(III) Catalysis for Late‐Stage C─H Fluoroalkylations
Abstract Chemo‐ and site‐selective functionalization of complex molecules poses a fundamental challenge. Herein, we introduce a resource‐economic photoelectrocatalysis strategy to en...
Low‐Redox‐Barrier Two‐Electron p‐Type Phenoselenazine Cathode for Superior Zinc‐Organic Batteries
Abstract Organic p‐type cathode materials with high redox potentials and fast kinetics have captured widespread attention in propelling Zn‐organic batteries (ZOB...
Phthalocyanine Grafting Strategy Induces Strong Intrinsic Electric Fields and Molecule‐Edge Carrier Transport Pathways for Photoelectrochemical Water Splitting
Abstract Limited charge separation, slow charge mobility, and high electron‐hole recombination rates remain critical challenges impeding the efficiency of photoe...
Reverse Regioselective Dicarbofunctionalization via <i>Anti</i> ‐Michael‐Type Addition
Abstract Vicinal dicarbofunctionalization of α,β‐unsaturated carbonyl compounds is a classical yet versatile method for constructing complex molecular architectu...
On‐Demand Regulation of Catalytic DNA Circuits Using Phosphorylated Charge Reversal Peptides
Abstract Catalytic DNA circuits have emerged as a powerful tool for high‐performance biosensing application; however, the establishment of a safe and efficient in vivo delivery syste...
Non‐Precious Metal Catalysts with Gradient Oxidative Dual Sites Boost Bimolecular Activation for Catalytic Oxidation Reactions
Abstract Catalytic oxidation emerges as a highly promising and cost‐effective approach for eliminating gaseous pollutants, greenhouse gases, and volatile organic...
3‐Oxabicyclo[3.1.1]heptane as an Isostere of <i>meta</i> ‐Benzene
Abstract 3‐Oxabicyclo[3.1.1]heptanes were designed as saturated isosteres of meta ‐benzene. Crystallographic analysis rev...
Synergistic Conversion of Hydrogen Peroxide and Benzaldehyde in Air by Silver Single‐Atom Modified Thiophene‐Functionalized g‐C <sub>3</sub> N <sub>4</sub>
Abstract This study reports the synthesis of silver single‐atom‐loaded thiophene‐conjugated carbon nitride (Ag@T─C 3 N...
Catalytically Active Coacervates Sustained Out‐of‐Equilibrium
Abstract Metabolically active membraneless organelles of extant biology have the capability to maintain their structure under nonequilibrium conditions by leveraging chemical reactio...
Carbon‐Supported Single Fe/Co/Ni Atom Catalysts for Water Oxidation: Unveiling the Dynamic Active Sites
Abstract Extensive research has been conducted on carbon‐supported single‐atom catalysts (SACs) for electrochemical applications, owing to their outstanding conductivity and high met...
Stepwise Crystallization Synthetic Strategy for Monodisperse InSb Colloidal Quantum Dots with Mid‐Infrared Absorption
Abstract Colloidal InSb quantum dots (QDs) are promising mid‐infrared (MIR) photodetection materials due to their suitable bandgap, unparalleled room temperature electronic propertie...
Vinyl‐Functionalized Linear Alkyl Chains in Nonfullerene Acceptors Enable 19.2% Efficiency and Stable As‐Cast Organic Solar Cells
Abstract Developing efficient and stable as‐cast organic solar cells (OSCs) is imperative for alleviating costs and complexity for large‐scale commercial applications. Nevertheless,...
Extending Frontier Molecular Orbitals Delocalization via Donor Fusion: Construct Long‐Wavelength Twisted Multiple Resonance Emitters with Efficient Narrowband Emission
Abstract Multiple resonance thermally activated delayed fluorescence (MR‐TADF) emitters are promising candidates for ultra‐high‐definition organic light‐emitting...
Accelerated Oxide‐Zeolite Catalyst Design for Syngas Conversion by Reaction Phase Diagram Analysis and Machine Learning
Abstract Oxide‐zeolite (OXZEO) catalyst design concept provides an alternative approach for the direct syngas‐to‐olefins (STO) with superior selectivity. Enhanci...
Modulating Active Hydrogen Supply and O <sub>2</sub> Adsorption: Sulfur Vacancy Matters for Boosting H <sub>2</sub> O <sub>2</sub> Photosynthesis Performance
Abstract Photocatalytic two‐electron oxygen reduction reaction (2e − ORR) represents a promising approach for H...
Origin of Lithium Dendrite Formation in Sulfide‐Based Electrolyte
Abstract The Li dendrite growth during battery cycles is a well‐known obstacle to the practical application of sulfide‐based electrolytes (SEs), notably Li...
The Role of Convex Edge Site in Fully‐Exposed Pt Cluster Catalyst for Hydrogen Production
Abstract Achieving a precise understanding of the active site structure has long been an ultimate goal in fundamental heterogeneous catalysis research, yet it re...
Periodic Patterning of Matter in Non‐Equilibrium Liesegang‐Type Structures
Abstract Bottom‐up self‐organization of unordered molecules into ordered, spatiotemporal patterns of complex structures through non‐equilibrium reaction–diffusion (RD) processes is u...
Constructing Large‐Area Oriented Covalent Organic Framework Based PN Heterostructure Films to Enhance Artificial Photosynthesis of H <sub>2</sub> O <sub>2</sub>
Abstract Two‐dimensional conjugated covalent organic framework (COF) films exhibit enormous application potential in the photosynthesis of hydrogen peroxide (H...
Visible‐Light‐Driven Photocatalytic Methanol Activation on Hexagonal CdS for Triggering C─H Methylation
Abstract Light‐driven methanol activation paves the way for pursuing C─H methylation of N ‐heteroarenes, where selectivel...
Ternary Metalation in a Copper‐Covalent Organic Framework for Tandem Photocatalytic CO <sub>2</sub> Reduction with High Selectivity
Abstract Developing multifunctional photocatalysts with efficient synergistic effects for selective photocatalytic CO 2 r...
α‐Amination of 1,3‐Dicarbonyl Compounds and Analogous Reactive Enolate‐Precursors Using Ammonia under Oxidative Conditions
Abstract We, herein, introduce a method for the direct α‐amination of different carbonyl compounds by employing aqueous ammonia as the N...
Artificial Cation–Chloride Co‐Transporters for Chloride‐Facilitated Lithium/Magnesium Separation
Abstract Inspired by nature, many artificial ion sieving materials have been developed, shedding light on the next‐generation ion, e.g., Li +...
Enhancing Built‐In Electric Field via Balancing Interfacial Atom Orbit Hybridization at Boride@Sulfide Heterostructure for Hydrogen Evolution Reaction
Abstract Exploring nonprecious metal‐based catalysts for cathodic hydrogen evolution reaction (HER) has facilitated the realization of hydrogen economy toward wa...