Angewandte Chemie International Edition
Articles in this Issue
Fluorogenic Interacting Protein Stabilization for Orthogonal RNA Imaging
Abstract Live imaging of RNAs is crucial to interrogate their cellular functions, but genetically encodable RNA imaging systems compatible with multiplexed and in vivo applications r...
Dynamic Modulation of Interactions Between Hydrophobic Tag‐Conjugated DNA Nanoprobes and Cell Membrane Facilitates ATP Imaging in the Tumor Microenvironment
Abstract Conjugating hydrophobic tags to oligonucleotides facilitates the swift and efficient creation of membrane‐anchored DNA nanoprobes. However, the membrane‐anchoring of these h...
Indole‐Quinoline Transmutation Enabled by a Formal Rhodium Carbynoid
Abstract Skeleton editing is an emerging and powerful tool in organic chemistry because it can simplify synthetic procedures towards complex molecules. Herein, w...
Photothermal Catalytic Synthesis of Sulfonic Acid Functionalized Covalent Organic Framework Achieved by COF‐to‐COF Transformation for Photocatalysis
Abstract Although photothermal catalysis is a clean, efficient, and green approach to access organic products, its application in the synthesis and transformation of covalent organic...
A Hypoxia‐Triggered Bioreduction of Hydrophilic Type I Photosensitizer for Switchable In Vivo Photoacoustic Imaging and High‐Specificity Cancer Phototherapy
Abstract Considering that hypoxia is strongly connected with tumor proliferation, metastasis, invasion, and drug resistance, it is of significant implication for...
Suppressing Dendrite Growth by Dolosse‐Structured ZIF‐67 Polycrystalline Membranes Through Eliminating Interfacial Electrolyte Turbulence on Zinc Anode
Abstract Aqueous Zn‐ion batteries (ZIBs) are considered a promising candidate for next‐generation energy storage devices, but the Zn dendrite problem limits thei...
Photoactivated Enzymatic Reaction Network Enables Spatiotemporal Programming of Thiol/Disulfide Redox Systems
Abstract Implementing photoactivation into chemical reaction networks (CRNs) offers opportunities for on‐demand and remote activation, fuel storage, creating autonomous materials and...
A Metal‐Organic Framework with Tailored Shape‐Matched Interactions Towards Ambient‐Temperature Argon Removal for Oxygen Purification
Abstract High‐purity oxygen (O 2 ) is essential for high‐value‐added applications in the medical, aerospace, and electron...
Coupling of CuO@NiBiO <sub>x</sub> Catalyzed Glycerol Oxidation to Carbon Dioxide Reduction Reaction for Enhanced Energy Efficiency
Abstract Glycerol electrooxidation reaction (GEOR) is a promising alternative to the oxygen evolution reaction (OER) in electrolyzers, overcoming the inherent ch...
Correction to “Near‐Infrared Activatable Copper Nanoplatforms Synergize With the 5‐Azacytidine Prodrug to Potentiate Cuproptosis”
Annulated Radical Cations with a C <sub>4</sub> E <sub>2</sub> ‐Core (E = P, As, Sb): Stable Pnictogen Analogs of Elusive Aryl Radical Anions of Birch Reduction Reactions
Abstract The benzene radical anion (C 6 H 6 ) ●−...
Molecular Geometry‐Property Relationship of Benzodipyrrole‐Based A‐DA'D‐A Type Acceptors for High‐Performance Organic Solar Cells
Abstract Molecular geometry plays a crucial role in determining the physical and chemical properties of organic semiconductor materials. However, there is little research on the mole...
Gallium‐Based Eutectic Alloys as Liquid Electron Donors to Ruthenium Single‐Atom Catalysts for Selective Hydrogenation of Vanillin
Abstract Tuning the catalytic pathways of atomically dispersed single‐atom catalysts (SAC) has emerged as an effective strategy to optimize their overall catalyt...
Total Synthesis of Dactyloquinone A and Spiroetherone A via a Metal‐Hydride Hydrogen Atom Transfer (MHAT) Process and a Quinol–Enedione Rearrangement
Abstract We report the total synthesis of dactyloquinone A and spiroetherone A from a meroterpenoid scaffold obtained by the deconjugative alkylation of a Wieland–Miescher type keton...
Zwitterionic Dipeptide Surface Functionalization of Detonation Nanodiamond for Enhanced Control in Biological Environments
Abstract Utilizing nanoparticles as innovative theranostic agents for biomedical applications requires full control over the material's properties to dictate their interactions withi...
Synthesis of Sensitive RNAs Using Fluoride‐Cleavable Groups as Linkers and Amino‐Group Protection
Abstract A chemical method suitable for the synthesis of RNAs containing modifications such as N 4‐acetylcytidine (ac4C)...
The Flexibility of Tetra(N‐Heterocyclic Carbene) Ligands Controls the Nuclearity and Geometry of Polynuclear M <sup>I</sup> ‒NHC Assemblies
Abstract A series of tetrakisimidazolium salts bearing two di(phenylimidazolium)amine groups linked by differently substituted anthracenes has been prepared. The...
Core‐Shell Hyperbranched Polymers via Catalytic Ring‐Opening Metathesis Polymerization
Abstract This work explores the synthesis, characterization, and applications of hyperbranched polymers (HBP) using a divergent ring‐opening metathesis polymerization (ROMP) approach...
Deciphering Complex Electrochemical Reaction Dynamics and Interactions of Single Nanoentities via Evanescent Scattering Microscopy
Abstract Electrochemical reactions at the nanoscale are governed by intricate surface interactions, yet existing imaging techniques often lack the surface sensitivity and throughput...
Mn <sup>2+</sup> ‐Activated Alkali Lithooxidosilicate Phosphors as Sustainable Alternative White‐Light Emitters
Abstract Eu 2+ ‐activated alkali lithooxidosilicates have emerged as promising candidates for narrow‐band cyan and green‐...
Building Ultrathin MOL/MOL S‐Scheme Heterostructures toward Boosted Photocatalytic Charge Kinetics for Efficient H <sub>2</sub> Evolution
Abstract Photocatalytic efficiencies highly depend on the kinetic behaviors of photogenerated electrons in catalysts. Herein, based on the promising metal‐organi...
Flow Battery with Remarkably Stable Performance at High Current Density: Development of A Nonfluorinated Separator with Concurrent Rejection and Conductivity
Abstract Redox flow batteries show promise for large‐scale grid stabilisation. Of these, organic redox flow batteries (ORFBs) harbour the potential for sustainab...
Tandem Dual‐Ratiometric SERS Probe Enables Raman Imaging of Neurological pH Fluctuations in Epilepsy
Abstract An imbalance of brain pH is closely associated with biochemical reactions, ion regulation, and electrical activity, serving as a hallmark for various ne...
Pangenome Analysis of the Plant Pathogen <i>Pseudomonas syringae</i> Reveals Unique Natural Products for Niche Adaptation
Abstract Pseudomonas syringae is a soil‐dwelling bacterium that exhibits remarkable niche adaptability, and it is known for its devastating i...