Angewandte Chemie International Edition

Electro‐responsive Tri‐state Switch in Supramolecular Circuits

Abstract Efficiently manipulating charge transport at the molecular level is critical to developing multifunctional and responsive molecular electronic devices....

Carbon Dots‐Induced Hydrogen‐Bonding Traps in RHO Zeolite: Mechanistic Insights and Superior Flue Gas Separation Performance

Abstract Zeolites stand out as promising materials for flue gas separation, however, it poses a significant challenge to conduct pore interior modifications to i...

Intercalation Chemistry Awakens Transition Metal Hydroxide for Boosted and Sustained Electrocatalytic Sulfion Oxidation

Abstract Electrocatalytic sulfion oxidation reaction (SOR) is a sustainable approach to treat sulfion‐rich sewage for S recovery. Transition metal hydroxide (TMO...

Inside Front Cover: Visual β‐Sheet‐to‐β‐Turn Transition in Luminescent Polymeric Vesicles for Color‐Reporting Drug Delivery (Angew. Chem. Int. Ed. 37/2025)

Scalable Synthesis of Stable Hydrogen‐Bonded Organic Framework for Efficient Hexafluoroethane Purification

Abstract Developing stable, efficient and easily scalably‐synthesized adsorbents for removal of hydrofluoroethanes to obtain high purity hexafluoroethane (C...

Inside Back Cover: Flexibility‐Aided Orientational Self‐Sorting and Transformations of Bioactive Homochiral Cuboctahedron Pd ₁₂ L ₁₆ (Angew. Chem. Int. Ed. 37/2025)

Nickel‐Catalyzed Regioselective and Enantioselective Olefin–Aldehyde Cross‐Couplings Toward Acyloin Isosteres

Abstract Bioisosteric replacement of ketones with three‐dimensional (3D) motifs, such as oxetanes and azetidines, has emerged as a powerful tool in molecular des...

In Situ Sulfur Modification Enables Electrochemical Selective Deuterated Thiol–Yne Reactions

Abstract The deuterated thiol–yne reaction using D 2 O represents an attractive strategy for simultaneously introducing p...

Electrochemical Alkyne Semi‐Hydrogenation via Proton‐Coupled Electron Transfer on Cu(111) Surface

Abstract Electrocatalytic alkyne semi‐hydrogenation (EASH) powered by renewable electricity using water as a hydrogen donor provides a sustainable alternative to...

Bipyridine–Thiosumanene Isomeric Lewis Bases for Synergistic Defect Passivation and Hole Extraction Enables Over 26% Efficient Perovskite Solar Cells

Abstract Interface defects between the perovskite layer and the hole transport layer (HTL) seriously limit the power conversion efficiency (PCE) and stability of...

Exposure of Au Atom on Au(111) in Metal Nanoclusters for pH‐Universal Electrocatalysis

Abstract The control of surface and interface structures in nanocatalysts is a promising strategy for enhancing catalytic performance, but significant challenges...

Bioelectrosynthesis of Signaling Molecules for Selective Modulation of Cell Signaling

Abstract Bioelectrosynthesis holds great potential for studying and regulating biological systems through the in situ synthesis and delivery of cell signaling mo...

Fully Exposed Silver Clusters Enabling Highly Efficient Photocatalytic H ₂ O ₂ Production in Pure Water

Abstract Photocatalytic production of H 2 O 2 in pure water holds great potential...

Halogen‐Driven Ion Transport Homogenization in 3D Hierarchical MOF for Ultrastable Solid‐State Lithium Metal Batteries

Abstract Solid‐state lithium metal batteries (SSLMBs) are hindered by limited ionic conductivity, heterogeneous lithium flux and interfacial instability of solid...

Outside Back Cover: Hinge‐Like Mechanochromic Mechanophores Based on [2.2]Paracyclophane (Angew. Chem. Int. Ed. 37/2025)

Crystal Facet‐Dependent Photocatalytic Hydrogen Evolution From Ultra‐Stable Cu‐Zr/Hf Heterobimetallic Metal–Organic Frameworks

Abstract Solar‐driven water splitting for hydrogen production over metal–organic frameworks (MOFs) is particularly attractive yet remains a challenge. Here, we r...

Single‐Atom Ligation of Four Different Alcohols at One Silicon Center: Methodology Development and Proof of Concept

Abstract While critical and indispensable in diversified areas, organosilicon compounds are not naturally occurring and all rely on chemical synthesis. The de no...

Molecular‐Metallic Binding Characteristics of the Intermetalloid f‐/p‐Block Cluster [(La@In ₂ Bi ₁₁ ) ₂ Bi ₂ ] ⁶⁻

Abstract Main goals of contemporary research in chemistry are to create new materials with unique properties and to understand the chemical bonding in them, espe...

Thermally Activated Delayed Fluorescence Materials Featuring Multipathway Charge Transfer for High‐Efficiency BT.2020‐Compliant Deep‐Blue OLEDs

Abstract BT.2020‐compliant deep‐blue emitters for organic light‐emitting diodes (OLEDs) are in high demand to achieve a wide color gamut for ultrahigh‐definition...

Diogo Alves Gálico

Regiodivergent and Enantioselective Hydroboration of Dienol Ethers

Abstract Transition metal‐catalyzed asymmetric hydroboration of alkenes is one of the most straightforward methods for the synthesis of chiral organoboron compou...

Hydroxyl Spillover Activated from the Strongly Coupled Ru@Mn ₃ O ₄ Heterostructure to Promote Alkaline Hydrogen Evolution

Abstract Alkaline hydrogen evolution reaction (HER) has great potential in practical hydrogen production. However, constructing an excellent catalyst with advant...

A Photoregulated Peptidase Mimic

Abstract Proteases and peptidases play crucial roles in numerous biological processes. These enzymes bind to protein substrates and hydrolyze peptide bonds, resu...

Mechanochemical Synthesis of Recyclable Biohybrid Polymer Networks Using Whole Biomass

Abstract Whole‐plant biomass from non‐agricultural sources and waste biomass from processing agricultural products are both promising feedstocks for biopolymer production because the...

Restructured Three‐Coordinated Ni─Se Catalytic Sites for Enhanced Cross‐Condensation of Methanol and Ethanol

Abstract The cross‐condensation of methanol (MeOH) and ethanol (EtOH) offers a promising, carbon‐neutral pathway for the production of higher alcohols (HAS) from...