Angewandte Chemie International Edition
Articles in this Issue
Supramolecular Engineering of Cluster‐Assembled Materials for Amplification and Dynamic Modulation of Chiral Luminescence
Abstract Chiral metal clusters have garnered significant research interest in recent years due to their unique photophysical and chiroptical properties. Increased attention is direct...
Spin‐Orbit Effects in a Thallium Borohydride Stabilized by Coordination to Bis(diisopropylamino)Cyclopropenylidene (BAC)
Abstract Reaction of Tl(OTf) with 2 equiv of bis(diisopropylamino)cyclopropenylidene (BAC) in THF results in formation of [Tl(BAC) 2...
Unconventional Fast Room Temperature Synthesis of Covalent Organic Framework Single Crystals Unveiling Precise Structural Insights
Abstract Two‐dimensional covalent organic frameworks (COFs) are a special kind of crystalline polymers produced by the polycondensation reaction of organic linkers. However, the poly...
Mechanistic Insights into the Dissolution Relay for Deep Progression of Active Sites Toward Efficient and Ultralong‐Life Energy Storage
Abstract Transition metal (oxy)hydroxides serve as efficient aqueous cathode materials but suffer from the challenge of structure degradation during long‐term cy...
Selective Scission of Orthogonal Bonds in Four‐Membered Ring Mechanophores upon Activation by a Rotaxane Actuator
Abstract Mechanophores (mechanosensitive molecules) are usually activated by pulling force transduced by polymer covalently attached to their structures. A variety of mechanophores h...
pH‐Dependent Packing Mode Variations and Chirality Inversion in Short Peptide Self‐Assembly
Abstract Precise control of structures and morphologies in peptide self‐assembly has been challenging. We report the self‐assembly of amphiphilic peptides I...
Frontispiece: Stable Yet Strongly Lewis‐Acidic Anions Enabling Cooperative Catalysis with Cationic Transition‐Metal Complexes
Dual Co Sites in n─n Type Heterojunction Enable Selective Electrochemical Co‐Valorization of HMF and CO <sub>2</sub>
Abstract Electrocatalytic oxidation of biomass‐derived hydroxymethylfurfural (HMF) to 2,5‐furandicarboxylic acid (FDCA) and electrocatalytic reduction of CO...
Feedstock‐Derived Thiophene Radical Anions Exhibiting Redox Stability at Extreme Potentials
Abstract Organic radicals that are both readily synthesized from commodity chemicals and stable at extreme redox potentials are rare, yet highly desirable for ap...
Plasma‐Engineered Sub‐10 nm Surface Fluorination Enables Ultraselective Hollow Fiber Membranes
Abstract While polymeric hollow fiber membranes (HFMs) offer scalable solutions for gas separations, their performance is fundamentally limited by the permeance‐...
Platinum‐Catalysed Hydrofluorination of Alkynes at Room Temperature Promoted by a Fluoride Shuttle
Abstract Hydrofluorination of alkynes provides a synthetic route to access fluoroalkenes, a class of compounds with wide applications in chemical research. Herew...
Frontispiece: Dual Co Sites in n─n Type Heterojunction Enable Selective Electrochemical Co‐Valorization of HMF and CO <sub>2</sub>
Chloromethoxytrityls: Tuning the SOMO Level of Stable Luminescent Radicals
Abstract Luminescent radicals are of significant recent interest because of the unique quantum properties of the doublet excited state. Control of the energy level of the singly‐occu...
Constructing Water‐Stable Porous Organic Salts via Suppressed Proton Integration Using Fluorinated Tetrazole Tectons
Abstract Porous organic salts (POSs) are an emerging class of materials with ordered ionic architectures, offering excellent proton transfer and water uptake properties. However, con...
Lili Lin
Atomic Metal‒Nonmetal Catalytic Pair Cooperatively Drives Efficient Enzyme‐Mimetic Catalysis
Abstract Single‐atom catalysts with maximum atom utilization and well‐defined coordination environments are promising alternatives to natural enzymes. However, their catalytic perfor...
Atorvastatin‐Loaded Mineralized Vaccine Reprograms Endosomal Trafficking to Amplify STING‐Driven Cancer Immunotherapy
Abstract Dendritic cell (DC)‐targeted nanovaccines offer great promise for cancer immunotherapy but are severely limited by premature lysosomal degradation of an...
Asymmetric Coordinated Single‐Atom Catalysts Offering Zero‐Order Sulfur Redox Kinetics for High Performance Li–S Batteries
Abstract Accelerating the sluggish sulfur redox kinetics through electrocatalysis has been regarded as one of the key factors to achieve Li–S batteries of cell‐l...
Insight into how PETase Functions at the Solid‐Liquid Interface and an Activity‐Stability Trade‐Off
Abstract Enzymatic degradation of poly(ethylene terephthalate) (PET) has garnered considerable interest in plastic recycling efforts. However, the underlying molecular mechanism gove...
Ligand Type Guided Keto‐Arylation Enables Modular Total Synthesis of Polycyclic CBS Xanthones
Abstract The first total synthesis of the potent polycyclic xanthone antibiotics CBS72, CBS87 and CBS100 was accomplished by a modular strategy featuring a very demanding intermolecu...
The Design of Interfacial Organic‐Riched Phase by Molecular Interlocking for Stable Zn Anodes
Abstract Rechargeable aqueous zinc‐ion batteries (ZIBs) are promising energy storage devices due to their high safety and environmental friendliness. However, th...
1,4‐Dearomatization of Pyridines and Quinolines Enabled by the Carbodication Lewis Acid
Abstract 1,4‐Dihydropyridines (DHPs) are valuable compounds in medicinal chemistry and organic synthesis. The most straightforward pathway for preparing 1,4‐DHPs is the direct 1,4‐re...
Monodisperse Regulation of Self‐Assembled Monolayer Via Dipole Molecules for Efficient Perovskite Solar Cells
Abstract The application of self‐assembled monolayers (SAMs) significantly drives the enhancement in the efficiency of perovskite solar cell (PSC). However, the...
General Base‐Free Suzuki‐Miyaura Cross‐Coupling Reaction via Electrophilic Substitution Transmetalation
Abstract The transition‐metal‐catalyzed Suzuki‐Miyaura cross‐coupling (SMC) reaction of organoboron nucleophiles with aryl (pseudo)halide electrophiles is a reliable method for carbo...
Dizygotic Atomic Platinum and Palladium on Carbon for High‐Performance Ethanol and Methanol Electro‐Oxidation
Abstract Dizygotic‐atom‐site catalysts (DASCs), consisting of multi‐atomic dispersed catalytic centers, perform well in several reactions but have poor electroca...