Angewandte Chemie International Edition
Articles in this Issue
Iron‐Catalyzed Asymmetric [4+2]/Cheletropic Retro‐[4+1] Cycloadditions of Thiophene <i>S</i>,<i>S</i>‐Dioxides with 3‐Substituted Indoles
AbstractThe Diels–Alder/cheletropic retro‐[4+1] cycloadditions of thiophene S,S‐dioxides are a prominent method for synthesizing unsaturated six‐membered carbocycles. However, to the best of our knowl...
Adjusting Chemical Hardness–Softness Balance of Electrolyte to Enable High‐Voltage Reversible Fluoride Ion Batteries
AbstractFluoride ion batteries (FIBs), as a promising next‐generation high‐energy‐density storage technology, have attracted significant attention. However, developing an ideal fluoride‐ion electrolyt...
P450 Enzyme LyoI Performs Hydro‐2,2′‐Bifuran Oxidation in the Polyether Ionophore Lysocellin
Abstract Polyether ionophores are potent antimicrobials, albeit also cytotoxic against mammalian cells. We have identified several polyether ionophores containin...
Semiconductor Cluster with High Reduction Potential and Efficient Charge Transfer Enables Visible‐Light‐Driven Activation of Inert Organic Substrates
AbstractPhotoredox catalysis is an essential component of modern organic synthesis. However, current photocatalysts face the challenge of simultaneously requiring strong redox potentials and efficient...
<i>d</i>‐<i>p</i> Orbital Hybridization of Ternary Transition Metal Toward High‐Performance Proton Storage
AbstractElectrochemical proton storage offers grid‐scale energy storage system with long lifespan, great safety, and eco‐friendliness. However, preparing proton storage materials with balanced conduct...
Enhancement of Emission Efficiency and Color Tuning by Mixing Platinum(II) and Palladium(II) Complexes in a One‐dimensional Chain
AbstractA series of mixed metal crystals comprising square‐planar platinum(II) and palladium(II) complexes, K[M(CN)2(dFppy)]·H2O (M = Pt2+, Pd2+; dFppy = 2‐(4,6‐difluorophenyl)pyridinate), were prepar...
Dihydroxanthene‐Derived Dioxetane Chemiluminophores for Activatable in Vivo Imaging
AbstractChemiluminophores with optimal chemiluminescence properties and versatile structures adaptable into activatable chemiluminescent probes are of particular interest for biosensing and imaging ow...
Creating Abundant Open Metal Sites in MOFs by Dual‐Coordination Design for Enhanced Electrocatalytic Activity
AbstractMetal–organic frameworks (MOFs) with well‐defined crystalline structures offer ideal platforms to unravel structure–property relationships, but their low density of accessible metal sites limi...
Photo‐Mediated Silacyclization by Wavelength‐Dependent Selective C─F or C─H Functionalization
AbstractSilacycles have gained significant attention within the synthetic community due to their pivotal roles in medicinal chemistry and materials science. Despite recent advancements, the defluorosi...
Polymerization of L‐Arginine into Nanomicelles for Immunometabolic Engineering of Adoptive Macrophages in Solid Tumor Therapy
AbstractThe therapeutic efficacy of adoptive cell therapy is highly dependent on the status and function of the infused cells. However, insufficient nutrient availability within the immunosuppressive...
Halogenation‐Engineered Acceptor Enables 20.14% Efficiency in Hydrocarbon‐Solvent Processed OSCs: From Binary Trade‐Offs to Ternary Synergy in Exciton and Energy Loss Management
AbstractHalogenation emerges as a key strategy to enhance the performance of organic solar cells (OSCs) by tuning molecular packing, energy levels, and charge dynamics. Here, we report three new benzo...
Outside Front Cover: Mechanistic Insight into <i>Para</i>‐Substituent Control of Thermal Half‐Lives in Arylazopyrazole Photoswitches (Angew. Chem. Int. Ed. 43/2025)
Origin and Suppression of Intragranular Cracks for Long‐Cycling High‐Ni Co‐Free Cathodes
AbstractIntragranular cracks have been identified as a direct reflection of failure in high‐energy‐density cathodes, especially for high‐Ni Co‐free cathodes with severe electrochemical–mechanical degr...
Ligand Engineering‐Enhanced Catalytic Activity of Octanuclear Zn(II)−Siloxane Clusters for Advanced Lithium–Sulfur Batteries
AbstractPolynuclear metal clusters (PMC) with atomically defined architectures exhibit unique electrochemical catalytic behaviors in lithium−sulfur battery (LSB). Nevertheless, the precise fabrication...
Selectively Modulating the Donor and Acceptor Aggregation Behaviors Through Solid Additive Isomerization Engineering for Organic Solar Cells Exceeding 20% Efficiency
AbstractRegulating the film morphology is essential for achieving high‐performance organic solar cells (OSCs). Given the distinct features of donor and acceptor materials, designing solid additives to...
Correction to “ <i>J</i> ‐Aggregates Formed by NaCl Treatment of Aza‐Coating Heptamethine Cyanines and Their Application to Monitoring Salt Stress of Plants and Promoting Photothermal Therapy of Tumors”
Photocatalytic H<sub>2</sub>O<sub>2</sub> Production with a Nearly 2% Solar‐to‐Chemical Conversion Efficiency via a Dedicated Construction of Redox Centers in Metal–Organic Frameworks
AbstractHydrogen peroxide (H2O2) is a green oxidant widely used in a variety of industries. Photocatalytic generation of H2O2 from water and oxygen by sunlight is an appealing strategy compared to the...
Inside Back Cover: Toward Bimetallic Nanowire Arrays with Controlled Compositions Using Block Copolymer Films: the Interplay Between Metal Precursors (Angew. Chem. Int. Ed. 43/2025)
A New Phase Indium Tin Oxide (ITO) Activated Selective CO<sub>2</sub> Reduction into Formate for Underwater Antifouling Glass
AbstractDesigning unique electrocatalysts that utilizes carbon dioxide reduction reaction (CO2RR) for real applications is highly appreciated, yet still suffers from low selectivity, stability, and co...
Discrete Actuation of Water‐Responsive Crystalline Metal–Peptide Frameworks
AbstractEngineering guest‐responsive materials capable of controlled and precise sorption behavior and structural deformation in response to external stimuli is imperative for various applications. Ho...