Angewandte Chemie International Edition
Articles in this Issue
Thermally Activated Delayed Photoluminescence Based on Functionalized Quantum Dots
Abstract Colloidal quantum dots (QDs) are promising light‐harvesting materials that offer advantages of high extinction coefficients and tunable absorption/emission wavelengths. Howe...
Interplay of Polar Order and Positional Order in Liquid Crystals–Observation of Re‐entrant Ferroelectric Nematic Phase
Abstract We show that development of polar order may spontaneously destroy the lamellar structure of a liquid crystal. This results in an unusual sequence of phases, with the ferroel...
Time‐Dependent Divergent Synthesis via Photochemical Rearrangement
Abstract Divergent synthesis is a powerful and economical approach in synthetic chemistry and materials science. However, achieving precise control over divergent reactions using onl...
Bismuth–Selenopeptides Combine Potent Bioactivity with Exceptional Kinetic Inertness
Abstract Bismuth peptides and proteins are emerging as versatile tools for medicinal chemistry and chemical biology. Bismuth(III) binds three cysteine residues in peptides and protei...
Microdroplet‐Driven Synthesis of a Metal–Organic Framework Catalyst
Abstract We report a room‐temperature synthesis of copper‐based metal–organic frameworks (Cu‐MOFs) using microdroplet chemistry, offering a fast and energy‐efficient alternative to c...
Outside Front Cover: Formation of Monolithic Magnesium–Calcium Carbonates Through Aggregation of Carbonate‐Cluster Nanodroplets (Angew. Chem. Int. Ed. 46/2025)
Fluorescent Peptide Tracers for Simultaneous Oxytocin Receptor Activation and Visualization
Abstract The oxytocin receptor (OTR) regulates critical physiological functions and has been implicated in a range of diseases, including psychiatric and neurodevelopmental disorders...
Silylative Amide to Nitrile Conversion Mediated by Simple Lanthanide–Organoamides: Scope and Mechanism
Abstract Efficient, selective, and environmentally benign catalytic nitrile synthesis is attractive for pharmaceuticals, specialty chemicals and materials, and l...
Engineering Localized Aromaticity in Amine‐Embedded Polycyclic Aromatic Hydrocarbons for Narrowband Fluorescence Emitter
Abstract The development of narrowband fluorescent emitters remains a long‐standing challenge in organic optoelectronics. Herein, we present an aromaticity engin...
Plasma‐Electrocatalysis Cascade Synthesis of Deuterated Ammonia
Abstract Deuterated ammonia (ND 3 ) exhibits growing market demand in the fields of chemical analysis, pharmaceutical ind...
Photochemical Spin‐State Switching of an All‐Organic Molecular System with Visible Light
Abstract Controlling the spin state of a molecule using the spatiotemporal properties of visible light is of interest for spintronic devices in information technology or (bio)medical...
Contemporary Strategies in SmI <sub>2</sub> Catalysis: A Reagent Reborn
Abstract The strategies adopted in the development of Sm II ‐catalyzed processes are critically evaluated. In particular,...
Chiral Hybrid Cu(I) Halide Scintillation Films with Polarization‐Engineered Light Management for High‐Resolution X‐ray Imaging
Abstract Scintillators are typically based on achiral structures, where the emitted light propagates isotropically, resulting in significant optical crosstalk an...
Outside Back Cover: Reversing Lanmodulin's Metal‐Binding Sequence in Short Peptides Surprisingly Increases the Lanthanide Affinity (Angew. Chem. Int. Ed. 46/2025)
Submolecular‐Resolution Probing of Vibrational Anharmonicity Using Tip‐Enhanced Raman Spectroscopy
Abstract Vibrational spectroscopy can reach atomic spatial resolution via highly confined optical probes, offering local chemical insight. Yet, overtones and combination bands have n...
<i>trans</i> ‐Silaboration of Terminal Alkynes Enabled by Development of a New Si─B Reagent
Abstract The 1,2‐silaboration of alkynes is a powerful strategy for regio‐ and stereoselective yielding versatile 1‐boryl‐2‐silyl alkenes, which are ubiquitous s...
Corrrection to “1,4‐Dearomatization of Pyridines and Quinolines Enabled by the Carbodication Lewis Acid”
Acceleration of [2]Catenane Formation by One of its Rings
Abstract [2]Catenanes were prepared from a crown ether, a diamine, and a diester in moderate to good yields in mild conditions by single‐step, metal‐free active...
Defluorinative <i>Fluoro</i> ‐Aza‐Nazarov Cyclization
Abstract A highly efficient approach toward polysubstituted β‐fluoropyrroles is described herein. Starting from α,α‐difluoro‐β,γ‐unsaturated ketone, which is eas...
Inside Front Cover: Breaking the Deep‐UV Transparency/Optical Nonlinearity Trade‐Off: Three‐Parameter Optimization in Oxyfluorides by Tailoring d <sup>0</sup> ‐Metal Incorporation (Angew. Chem. Int. Ed. 46/2025)
Enhanced Efficiency and Stability of Inverted Perovskite Solar Cells via Isomerization Engineering of Self‐Assembled Monolayers
Abstract Carbazole‐based SAMs show great promise as interfacial modifiers in inverted perovskite solar cells (PSCs). Their large dipole moments and covalent bind...
Haifeng Zheng
Visible‐Light‐Driven α‐C(sp <sup>3</sup> )−H Carboxylation of Primary Benzylamines with CO <sub>2</sub> to Access α‐Amino Acids
Abstract α‐Amino acid motifs, serving as essential building blocks, are ubiquitous in natural products, bioactive molecules and drugs. Despite significant advanc...
Restoring Porosity and Uncovering Flexibility in Pillared 3D‐Linker Metal‐Organic Frameworks
Abstract Porous adsorbents have emerged as leading materials for carbon capture, where pressure‐controlled regeneration offers a key advantage over energy‐demand...
Transient Induction of Chirality from an Activated Carboxylic Acid to a Zinc Complex
Abstract Enantiomerically pure activated carboxylic acids (ACAs), ( R )‐ and ( S...