Angewandte Chemie International Edition
Articles in this Issue
Electrochemical ⍺‐C─H Functionalization of Nitramines for Accessing Bifunctional Energetic Heterocycles
Abstract The synthesis of energetic materials (EMs) often involves hazardous reagents and harsh conditions, raising safety and environmental concerns. We herein present an electroche...
Silicon‐Based Azo Compound‐Mediated CO Activation and N <sub>2</sub> Release
Abstract Silicon‐substituted azo compounds featuring Si─N═N─Si linkages remain elusive in main‐group chemistry. Herein, we report the synthesis of a silicon‐base...
Achieving Near‐Infrared Organic Room‐Temperature Phosphorescence for High‐Resolution Immune Response Monitoring and Bioimaging
Abstract Organic near‐infrared (NIR) room‐temperature phosphorescent (RTP) materials hold great potential for bioimaging due to their ability to eliminate background noise and tissue...
Studies of α′,β′‐Epoxyketone Synthesis by Small‐Molecule Flavins and Flavoenzymes
Abstract Epoxomicin is a highly potent natural proteasome inhibitor and the structural scaffold for the anticancer drug carfilzomib. The biosynthesis of its α′,β...
Molecular Recognition Driven Organelle Cross‐Linking Induces Endoplasmic Reticulum Stress and Mitochondrial Dysfunction to Potentiate Cancer Immunotherapy
Abstract Organelles maintain cellular homeostasis through highly specialized division of labor, dynamic interactions, as well as extensive inter‐organellar infor...
Electronic Modification at Atomic Scale: Design and Preparation of Diatomic Structures by Atomic Layer Deposition for Methanol Steam Reforming
Abstract The electronic effects of bimetallic components in catalysis remain poorly understood. Herein, atomically dispersed transition metal (TM) modified plati...
Dual Spatial and Electronic Regulation in van der Waals Cu <sub>3</sub> Se <sub>2</sub> Nanosheets for Electrocatalytic Acetylene Semi‐Hydrogenation
Abstract Copper‐based catalysts are promising for electrocatalytic acetylene semi‐hydrogenation to sustainable ethylene production, yet conventional catalysts su...
Mesoporous PtPd Alloy ‐ High Entropy Oxide Heterostructures for Efficient Electrocatalytic Methanol Oxidation Reaction
Abstract The widespread adoption of direct methanol fuel cells (DMFCs) has been significantly hindered by the low activity of commercial noble metal catalysts to...
Synergistic Contact‐Electro‐Catalysis and Photocatalysis via TiO <sub>2</sub> @PTFE Composites for Efficient N <sub>2</sub> to NH <sub>3</sub> Conversion
Abstract Catalytic nitrogen fixation from N 2 and water under mild conditions offers a sustainable NH...
Enantioselective Miyaura Reaction by Desymmetrizing C(sp <sup>2</sup> )–B Cross‐Coupling of 1,1′‐Biaryl‐2,6‐diyl Bis(nonaflates)
Abstract An efficient protocol for a desymmetrizing C(sp 2 )–B cross‐coupling of achiral 1,1′‐biaryl‐2,6‐diyl bis(nonafla...
Atomic‐Level Engineering of Au–Ag Nanoclusters Enables Divergent Triplet Emission
Abstract Triplet‐state‐based luminescence holds great promise for next‐generation optoelectronic materials, yet its mechanistic modulation through structural con...
Continuous Dual Hydrogenation of Biomass Substrates in a Membrane‐Free Solid Electrolyte Reactor
Abstract Production of chemicals from biomass through electrocatalytic hydrogenation shows great potential to reduce environmental impact across various applicat...
Metal–Organic Cages for Ultrafast Photocatalytic Synthesis of Hydrogen Peroxide
Abstract In the realm of photocatalytic production, discrete metallo‐organic cages have emerged as promising photocatalysts. However, their performance is often...
24‐Hour‐Long Afterglow from Single Polymer Chains Through Engineering‐Compatible One‐Pot Polycondensation Approach
Abstract We report the unprecedented observation of 24‐h‐long afterglow (HLA) emission from single polymer chains. The polymer chains were synthesized through a straightforward engin...
Polycyclic Heteroaromatics with Planar‐Curved Hybrid Skeletons for High‐Performance Photocatalytic Hydrogen Peroxide Evolution
Abstract Creating curvature in the scaffolds of polycyclic aromatic hydrocarbons (PAHs) enables breaking their molecular planarity or even symmetry, leading to s...
Construction of Single‐Cluster Rhodium Catalyst for Efficient CO <sub>2</sub> Hydrogenation to Ethanol
Abstract Thermocatalytic conversion of carbon dioxide (CO 2 ) into ethanol is a promising strategy for efficient utilizat...
Entropy‐Driven Modulation of Ion Clustering and Polymer Crystallinity for Low‐Temperature Lithium Metal Batteries
Abstract Solid‐state Li metal batteries have garnered significant attention for their intrinsic safety and high energy density. Among various solid‐state electro...
Prediction of One‐Dimensional Metallicity and π‐Band Superconductivity in Rhodizonate Radical Pancakes
Abstract Computational exploration of condensed phases made of potassium and carbon monoxide leads to predictions of stable salts composed of cyclic six‐membered...
Failure Mechanism of High‐Temperature Li–S Batteries in Localized High‐Concentration Electrolytes
Abstract Conventional ether‐based electrolytes struggle to sustain steady operation of lithium–sulfur (Li–S) batteries at high temperatures due to inferior thermal durability and agg...
Engineering Autonomous Micro‐/Nanorobots for Neurological Diseases: From Barrier Crossing to Neuroenergetic Restoration
Abstract Neurological diseases (NDs) are associated with barrier transport dysfunction, abnormal protein aggregation, and impaired cellular energy metabolism, with bioenergetic defic...
Advanced Self‐Phase‐Separating Electrolytes for High‐Performance Lithium‐Sulfur Batteries
Abstract Lithium‐sulfur (Li‐S) batteries face a critical challenge in synergistically optimizing high‐sulfur‐loading redox kinetics and suppressing soluble lithi...
E <sup>II</sup> /E <sup>IV</sup> O (E = Ge, Sn) Catalyzed Nitrous Oxide Activation and Chemodivergent Reduction of Nitroarenes
Abstract While homogeneous catalysis remains predominantly dominated by transition metal complexes, the utilization of main group compounds as redox catalysts fo...
Synthesis of Bridge‐Substituted Bicyclo[1.1.1]Pentanes by Catalytic Metal Carbene Insertion into Bicyclo[1.1.0]Butanes
Abstract 1,2,3‐Trisubstituted bicyclo[1.1.1]pentanes (BCPs) are emerging saturated hydrocarbon bioisosteres for polysubstituted benzenes; however, their synthesis from bicyclo[1.1.0]...
Localizing the Long‐Range Disorder of Reconstructed Cobalt Oxyhydroxides for Anion Exchange Membrane Water Electrolysis
Abstract Controlling the long‐range disorder of dynamically reconstructed nanostructures represents a challenging but important approach for achieving practical...
Synergic Coordination Effect in Nonflammable Deep Eutectic Electrolyte for High‐Performance Sodium‐Ion Batteries
Abstract Deep eutectic electrolytes (DEEs) are emerging as a highly promising class of next‐generation electrolytes, poised to revolutionize the performance of s...