Angewandte Chemie International Edition
Articles in this Issue
Charge‐Spin‐Orbit Modulated Carbon‐Encapsulated FeP/Fe <sub>3</sub> O <sub>4</sub> Heterojunctions for Ultrafast and Stable Conversion of Low‐Concentration Nitrate to Ammonia
Abstract Electrocatalytic nitrate reduction reaction offers an effective route for ammonia synthesis and actual wastewater treatment. Despite some important achi...
Fully Aromatic Fluorinated Polyamide Nanofilms with Molecular Gating for Ultrafast Crude Oil Fractionation
Abstract Crude oil is the “black gold” of the world and its fractionation by thermal distillation is a highly energy‐consuming process. Polymer membranes are man...
Nickel‐Catalyzed Asymmetric Three‐Component Reaction of Unactivated Alkyl Halides, 1,3‐Enynes and Aldehydes
Abstract The π‐propargylnickel(II) complexes, or their resonances, the η 1 ‐allenylnickel(II) ones, are typically generat...
Absolute Configuration Determination with Electronically Enhanced Vibrational Circular Dichroism
Abstract Intensity enhancement in vibrational circular dichroism (VCD) arises in open‐shell transition metal complexes from coupling between ground‐state vibrational transitions and...
Generality‐Driven Optimization of Enantio‐ and Regioselective Mono‐Reduction of 1,2‐Dicarbonyls by High‐Throughput Experimentation and Machine Learning
Abstract The longstanding quest for substrate generality stems from the unpredictability of single‐model optimization. Leveraging high‐throughput experimentation...
Achieving Combined Photoluminescence and SHG in a New Polar Hybrid Glass‐Ceramic with Square‐Pyramidal [SbBr <sub>5</sub> ] Units
Abstract Hybrid glass‐ceramics have garnered extensive research interest due to their exceptional optical properties. Integrating luminescence and second harmoni...
Genetic Encoding of Pentafluorophosphato‐Phenylalanine Provides PF <sub>5</sub> ‐Proteins as Phosphoprotein Mimetics
Abstract Protein phosphorylation is one of the most important posttranslational modifications altering the structure, stability, and activity of more than 13 000...
Synergistic SuFEx‐Driven Covalent Cancer Therapy Using a HER2/EGFR Bivalent Affinity Protein Drug
Abstract The integration of sulfur fluoride exchange (SuFEx) chemistry into proteins is significantly advancing their applications in biological fields. However, its suboptimal react...
Phase Engineering of Mg–Pt Intermetallic Hydrogenation Catalysts for CO Poisoning Resistance
Abstract Platinum group metals (PGMs) are efficient catalysts for industrial hydrogenation reactions but are extremely sensitive to CO (ppm levels), making the d...
The Highest Oxidation States of the Rare‐Earth Elements and the Challenge of Praseodymium(+5) Compounds
Abstract Oxidation‐State is one of the most important heuristic concepts in modern practical and theoretical chemistry. Its exploration deepens our understanding of both this concept...
Incorporating Redox‐Active Hexaazatrinaphthylene into a 2D Conductive Metal–Organic Framework for Robust Sodium‐Ion Batteries
Abstract Two‐dimensional (2D) conductive metal–organic frameworks (cMOFs) hold tremendous promise as anode materials for sodium‐ion batteries (SIBs), owing to th...
<i>Operando</i> Insights into Bridging Oxygen‐Driven RuO <i> <sub>x</sub> </i> Lattice Collapse and its Mitigation Strategy for Durable Industrial PEMWE
Abstract Ruthenium oxide (RuO x ) is a promising anode catalyst for proton ex...
Distinctive Coordination Configuration and Interfacial Water Balance Induced by Anti‐Kirkendall Effect Attain Exceptional Catalytic Activity and Selectivity
Abstract A critical challenge for the application of direct ethanol fuel cells (DEFCs) lies in the sluggish kinetics of C─C cleavage. Herein, a significant porti...
Stereodivergent Deacylative Mizoroki–Heck Reaction of Unstrained Ketones
Abstract Alkene structures represent one of the most functional and widely used in organic synthesis, drug design, and material science. However, developing a pr...
Electrochemical pH‐Swing CO <sub>2</sub> Capture Facilitated by Suppressed Bubble Accumulation at Electrode/Electrolyte Interfaces
Abstract Electrochemical CO 2 capture features high modularity and low system complexity. When the pH swing produced by e...
Harnessing Colloidal Dispersion for Laccase‐Driven Enzymatic Depolymerization of Polystyrene
Abstract Polystyrene (PS) is one of the most widely used synthetic polymers, with annual global production of around 20 million tons. However, its robust C─C bac...
Bright Circularly Polarized Electrochemiluminescence from Heterobinuclear Ir <sup>III</sup> –Au <sup>I</sup> Enantiomers
Abstract The development of efficient circularly polarized electrochemiluminescence (CP‐ECL) probes is still at its infancy and examples are still very limited....
Cation‐π Mediated Weak Solvation Chemistry Enables Dendrite‐Suppressed Gel Polymer Electrolytes
Abstract Gel polymer electrolytes (GPEs), despite their flexibility, non‐leakage, and processability as promising candidates of electrolytes for high‐energy‐dens...
Hierarchical, Template‐Controlled Self‐Assembly of Two Different Organometallic Capsules from a Tetrakisimidazolium Salt
Abstract Controlling the assembly of molecular nanocapsules through metal‐carbon bonds constitutes a major challenge in the field of supramolecular organometalli...
Charge‐Driven Self‐Assembly of Cholesterol Surfactants into Biofunctional Nanodiscs with Antiviral Activity
Abstract Self‐assembly of lipid structures derived from amphiphilic molecules plays a crucial role in the development of biomimetic systems. Here we report a modular synthetic strate...
Electrostatic Landscape Design for Ionomer Adhesion and Poison‐Resistant Platinum Catalysis in Fuel Cells
Abstract Uneven ionomer distribution and sulfonate groups (–SO 3 – ) poisoning at platinum (Pt) sites...
Efficient Electrosynthesis of Dinitrile from Nylon‐66‐Derived Diamine Enabled by Highly Active Mn–O–Co Motifs in Spinel Oxides
Abstract Conventional industrial production of adiponitrile (ADN), a critical building block in energy storage devices and polymer manufacturing, is predominatel...
Polymer‐Nanodomains Regulation for Optimized Ionic Translocation Enabling High‐Voltage and Practical Utility Lithium Metal Batteries
Abstract High‐voltage solid‐state lithium metal batteries (HVSSLMBs) integrate high‐voltage cathodes (HVCs) with lithium metal anodes, offering great promise for...
Programmable Pulsed Acidic Water Oxidation for Enhanced H <sub>2</sub> O <sub>2</sub> Production
Abstract Hydrogen peroxide (H 2 O 2 ) is a high‐value, eco‐friendly chemical with...
Spin‐Matching Effect Triggering Enhanced Oxygen Reduction Reaction in Acidic and Alkaline Media
Abstract The development of high‐performance oxygen reduction reaction (ORR) electrocatalysts operable across broad pH ranges is hindered by strong adsorption of...