Angewandte Chemie International Edition
Articles in this Issue
Minutes‐Scale Ultrafast Synthesis of New Oxyhalides Solid Electrolytes with Interfacial Ionic Conduction for All‐Solid‐State Batteries
Abstract Halide solid‐state electrolytes (SSEs) show exceptional promise for all‐solid‐state batteries (ASSBs), yet their dependence on prolonged ball milling to...
Beyond Local Coordination: How Global Structure Engineers the Selectivity of Single Atom Catalysts for CO <sub>2</sub> Reduction
Abstract The local structure of the active center is generally believed to determine the catalytic performance, but this rule fails in many situations. One of th...
DFT‐Guided Design and Synthesis of Bipyridine‐Anchored Copper Single‐Atom Catalysts for Efficient Nitrate‐to‐Ammonia Electroreduction Across a Broad pH Range
Abstract The electrochemical conversion of nitrate to ammonia represents an efficient approach to alleviate nitrate pollution, concurrently providing a sustainab...
Contact Electrification via Redox‐Active Molecules
Abstract Contact electrification, as the transfer of charge upon the contact of two (dis)similar materials, is strongly influenced by surface chemistry, which go...
Switching the Reaction Pathway to the Oxide Path for High‐Efficiency Acidic Oxygen Evolution
Abstract Understanding dynamic structure–activity relationships in the oxygen evolution reaction (OER) remains challenging due to electrocatalysts’ structural co...
High‐Throughput Theoretical Screening of Single‐Atom Catalysts for Electrochemical Urea Synthesis
Abstract Electrochemical urea synthesis offers a promising approach for sustainable nitrogen and carbon utilization, yet its progress is hindered by the unclear...
Conformation‐Matched Symbiotic Noncovalent Sites Facilitated Supramolecular Nanotwists Featuring both P and M Sub‐Helical Domains
Abstract Living system can use homochiral blocks to simultaneously fabricate diverse structures with opposite chirality (e.g., right‐handed α‐helices and left‐ha...
Modulation of Photoluminescence and Solar Thermal Energy Storage in Norbornadiene–Quadricyclane Dimers
Abstract The norbornadiene/quadricyclane (NBD/QC) photoswitch pair is a promising system for molecular solar thermal (MOST) energy storage. Multichromophoric sys...
Cationic Covalent Organic Framework for Photocatalytic Defluorinative Amination of Fluoroarenes
Abstract Covalent organic frameworks (COFs)—a unique class of crystalline, porous materials—are distinguished for their structural tunability, large surface area, high chemical stabi...
In situ Crystal Structure Growth and Control for Enhancing Comprehensive Performance in Ultra‐High Nickel‐Layered Lithium Cathodes
Abstract The ultra‐high nickel‐layered cathodes, LiNi x Co...
High‐Efficient Raman Enhancement on Organic Semiconductor‐Stabilized Perovskite Heterostructures for Guiding Early Theranostics of Alzheimer's Disease
Abstract Perovskites have recently emerged as attractive optoelectronic semiconductors due to tunable bandgap, large absorption coefficient, and long carrier lif...
Ultrasmall Nickel Nanoclusters Accelerating Protonation for Efficient CO <sub>2</sub> Electroreduction towards CO
Abstract Proton‐coupled electron transfer (PCET), particularly the protonation step is widely recognized as the kinetic bottleneck in electrochemical CO...
Transient‐Promoter‐Stabilized NiFe Oxyhydroxide Enables Durable kW‐Scale Water Splitting Under Fluctuating Power
Abstract Renewable‐powered water electrolysis provides a carbon‐neutral route to hydrogen, yet large‐scale deployment is constrained by reliance on stable but ca...
Strong Metal‐Support Interactions on TiO <sub>2</sub> ‐Supported Metal Catalysts for Fine‐Tuning Catalysis
Abstract The concept of strong metal‐support interaction (SMSI), a topic of investigation for over four decades, remains an important area of research in heterog...
Microcondensate‐Mediated Intracellular Infusion of mRNA Across the Plasma Membrane
Abstract This study presents a strategy for developing micrometer‐sized coacervates comprised of cationic intracellular delivery peptide FcB(L17E)...
Two‐in‐One Strategy for Photoinduced Atom Transfer Radical Polymerization Using Cu(I)‐Phenothiazine Integrated Covalent Organic Frameworks
Abstract The concurrent development of innovative photocatalysts (PCs) that achieve fast reaction rates while ensuring efficient catalyst recycling remains a sig...
Stereoselective Synthesis of 2‐Deoxy‐ <i>β</i> ‐ <i>O</i> ‐Aryl Glycosides by a One‐Pot Strategy Involving C─O Coupling and Catecholborane Reduction
Abstract Naturally occurring 2‐deoxy‐β‐ O ‐aryl glycosides are an important class of anticancer and antibacterial compoun...
Competitive Coordination Constructed Heteronuclear Pt <sub>1</sub> ‐Fe <sub>1</sub> Dual Single‐Atom Sites for Selective Oxidation of Allylic Alcohol
Abstract Dual single‐atom catalysts (DSACs) have attracted considerable attention owing to their exceptional atom efficiency and synergistic catalytic effects. N...
Temperature‐Induced Morphological Transitions for On‐Demand Detachment in Worm‐Based Polymer Hydrogels
Abstract Temperature‐responsive materials are vital for applications relating to on‐demand detachable adhesives, as they enable rapid, damage‐free detachment. However, low‐temperatur...
Coordination‐Induced Amplification of Birefringence and Nonlinear Optical Response in a Chiral Metal–Organic Framework
Abstract Crystalline materials exhibiting programmable optical anisotropy are of great interest for advanced photonic applications but remain challenging. In thi...
Amide and Thioester Synthesis Via Oxidative Coupling of Alcohols with Amines or Thiols Using Alcohol Dehydrogenases
Abstract Amide and thioester moieties are prevalent in pharmaceuticals, natural products, and functional materials, but their chemical synthesis suffers from poor atom economy and un...
Multi‐Field Coupling Driven in Situ Interfacial Growth of COF‐functionalized Membranes for Lithium–Sulfur Batteries
Abstract Conventional modification methods for the separator of high‐performance lithium‐sulfur batteries often struggle to realize the functional materials well...
Structural Effects in Polyoxometalate‐Based Supramolecular Assemblies for Enhanced Proton Conduction
Abstract Proton conductors with engineered charge‐assisted hydrogen‐bonding networks are pivotal for advancing proton exchange membrane fuel cells (PEMFCs). Here...
Steric Pruning Unlocks Hierarchical Structuring, Thermochromism, C‐H/O Activation, and 6‐electron Redox Transmetalation in Planar Bismuth Triamides
Abstract Planar bismuth triamides with tunable stereoelectronics offer a versatile platform for studying the effects of geometric constraints in p‐block elements. Here we show that e...
Crystal Facet Engineering of BiOCl Fillers in Solid Polymer Electrolytes
Abstract Solid polymer electrolytes (SPEs) have attracted much attention due to their high flexibility and good interfacial contact with electrodes. Incorporatin...