Angewandte Chemie International Edition
Articles in this Issue
DNA Glass: Encasing Diffraction‐Quality, Mesoporous DNA Crystals in Architected Silica
Abstract Self‐assembling DNA crystals have emerged over the last two decades as an efficient and effective means of organizing matter at the nanoscale, but functionalization of these...
Chlorinated‐Solvent‐Based Electrolyte for Safe and Stable Lithium Battery Chemistry
Abstract The current lithium battery technology is greatly limited by safety concerns. Fluorinated and organophosphorus solvents can reduce the electrolyte flamm...
Iridium Porphyrin‐Catalyzed Asymmetric Rearrangement of Oxindoles with Aryl Diazoesters: Enantioselective Synthesis of Chiral Tertiary 2‐Indolyl Alcohols
Abstract The asymmetric functionalization of indoles at the C2 position to afford chiral tertiary alcohols poses a formidable challenge in organic synthesis, primarily due to the inh...
The Methylbismuth Dication: Pentagonal Pyramidal Coordination and Ligand‐Induced Lewis Superacidity
Abstract A profound understanding of the naturally preferred coordination geometry of molecular complexes is the basis for scientists to rationalize, predict, an...
Picosecond Stabilization of Transferred Charge Carriers at Plasmonic Metal–Molecule Interfaces
Abstract Plasmonic nanoparticles efficiently absorb light across a broad spectral range, enabling energy transfer to adjacent molecules or semiconductors for pho...
A Universal Principle of Lithium Bond Characteristics in Lithium Battery Electrolytes
Abstract Understanding the interactions between lithium (Li) and coordinated compounds is fundamental to elucidating the working mechanisms of Li batteries and i...
A Zinc Solvation‐Tailored Deep Eutectic Electrolyte for High‐Performance Zinc‐Ion Batteries
Abstract Aqueous zinc‐ion batteries (AZIBs) are gaining attention as safe and cost‐effective alternatives to lithium‐ion batteries; however, their performance is...
Molecular Solar Thermal (MOST) Energy Storage—Definitions and Requirements Revisited
Abstract Molecular solar thermal storage (MOST) systems have gained increasing attention in the past years after an intense initial exploration phase around five decades ago. Over ti...
Direct Access to Acylboranes via Formal Condensation of Carboxylic Acids with Ligated Boranes
Abstract The unique synthetic potential of acylboron species has long attracted attention from the synthetic chemistry community, but their broader application has been limited by ch...
One‐ and Two‐Electron Carbon–Halide Bond Activation at a Phosphorus Center
Abstract The activation of small molecules by main‐group elements has garnered significant attention as a potential alternative to transition metal catalysis. Wh...
Cluster Formation and Phase Transitions Induced by Vibrational Strong Coupling
Abstract Vibrational strong coupling (VSC) has been shown to significantly modify the chemical and physical properties of molecules and materials. Here we report the non‐resonant Ray...
Anionic Hofmeister Effect Differentiated Subcellular Distributions of pH‐Responsive Metal–Organic Cages for Tumor Photodynamic Immunotherapy
Abstract The precise control of subcellular distribution offers significant advantages for advancing the understanding of cellular biology and targeted theranost...
Successive Sulfur Oxidation Directs Topological Transformation From 4 <sub>1</sub> Knot to 632$6_3^2$ Link
Abstract Achieving transformation between different types of topologies remains a challenge in supramolecular chemistry. Herein, sulfur oxidation was utilized as...
Precise Regulation of Zn, S Dual Vacancies in Zn <sub>3</sub> In <sub>2</sub> S <sub>6</sub> Inducing Local Orientated Electrical Field for Photocatalytic H <sub>2</sub> O <sub>2</sub> Generation
Abstract Photocatalytic H 2 O 2 synthesis attracts interest for solar‐to‐fuel con...
Deciphering the Novel Photoreactivity of β‐Enaminones
Abstract The mechanism of a newly discovered photochemical reaction of β‐enaminones is examined by femtosecond transient absorption spectroscopy and multistate multiconfigurational q...
Chiral Boron–Formazanates as a Multifunctional NIR Chiroptical Platform: Modular Synthesis, Photothermal Conversion, and Reversible Acid–Base Chiroptical Switching
Abstract Chiral organic materials with near‐infrared (NIR) optical activity are highly sought after for advanced photonic and optoelectronic applications but rem...
Transferring Porosity Across Physical States Using Metal–Organic Cages: Porous Liquids, Glasses, Rubbers, and More
Abstract The development of porous materials that retain tailored porosity across different physical states beyond crystalline solids ( e.g...
Highly Efficient and Stable Binary‐Doped Narrowband Blue OLEDs Enabled by a Single‐Component Host Matrix with a Spatial Bipolarity Configuration
Abstract Highly efficient and stable narrowband blue organic light‐emitting diodes (OLEDs) are vital for high‐definition displays, yet the achievement of such de...
Interfacial Synthesis of Cs <sub>2</sub> PtCl <sub>6</sub> Perovskite for Strong Coupling with V <sub>4</sub> C <sub>3</sub> T <sub>x</sub> MXene Toward Efficient Hydrogen Evolution and Urea Oxidation
Abstract A key innovation in this work is the development of a trapping method to synthesize perovskite Cs 2 PtCl...
Regulating Promiscuous Catalysis via Substrate‐Induced Transient Assembly
Abstract In nature, substrate‐induced assembly is a fundamental requirement for a wide range of enzyme‐driven chemical transformations. Systems chemists have introduced synthetic sub...
Modulating Adsorption Orientation of Multi‐Site Ligand Enables Perovskite/Silicon Tandem Solar Cells with Voltage Exceeding 2 V
Abstract Rational molecular design at the perovskite/charge transport layer interface offers an effective approach for suppressing non‐radiative recombination in...
Activate 1‐TM Channel of Disordered Rock Salts via Electrostatic Repulsion Regulation for Enhanced Lithium Storage
Abstract Cation‐disordered rock‐salt (DRX) has emerged as a promising high‐capacity cathode material for next‐generation high‐energy‐density Li‐ion batteries. Ho...
Integrating Sorbents in CO <sub>2</sub> Electroreduction: A Model System to Disentangle Layer Contributions in Membrane Electrode Assemblies
Abstract Membrane electrode assemblies (MEAs) are crucial in high‐performance CO 2 electrolysis, reducing...
High‐Entropy Topologically Close‐Packed Ir Alloys Enable Interatomic Hydrogen Spillover for Hydrogen Evolution toward High‐Performing Anion Exchange Membrane Water Electrolyzers
Abstract The efficiency of alkaline hydrogen evolution reaction (HER) is strictly restricted by the insufficient active hydrogen supply. Here, we develop high‐en...
Quaternary Carbon Centers via Electrochemical Direct Dehydroxylative Alkylation
Abstract The construction of all‐carbon quaternary centers remains a formidable challenge in organic synthesis due to the steric congestion and limited accessibi...