Angewandte Chemie International Edition
Articles in this Issue
Triple‐Functional Hydrazide‐Based Modifier for Self‐Assembled Monolayers/Perovskite to Obtain 26.29%‐Efficiency Inverted MA‐Free Perovskite Solar Cells
Abstract Inverted perovskite solar cells (PSCs) face challenges in hole‐transport layer (HTL) uniformity and buried interface defect passivation. To address thes...
Active‐Site Shifting on the Ni‐FeO <sub>x</sub> Interface Bridges Metallic and Oxidative Catalysis for Efficient Methane Partial Oxidation
Abstract Partial oxidation reforming of methane provides stoichiometrically optimal syngas as an alternative feedstock for the chemical industry currently relyin...
Photo‐, Thermal‐, and Electro‐Responsive Polyolefin‐Based Actuators
Abstract Stimuli‐responsive polymeric actuators have been applied in soft robotics and artificial muscles. Although numerous functional polymers are used during...
Atomic Ru‐Mediated Spontaneous Heterointerface Phase Transition Enables Ampere‐Level Catalytic Performance in Paired Electrolysis
Abstract Phase transition regulation is a promising strategy to optimize the catalytic properties of catalysts, playing a crucial role in enhancing electrocataly...
NdO‐Intensified Dual‐Site Synergy in IrMnO <i> <sub>x</sub> </i> for Acidic Oxygen Evolution
Abstract The development of low‐iridium (Ir) electrocatalysts for proton exchange membrane water electrolyzers (PEMWEs) remains a significant challenge. In this...
Facet Engineering of CdS/Bi <sub>2</sub> S <sub>3</sub> Heterojunction Photocatalysts for High‐Rate, Ultraselective CH <sub>4</sub> Production from Acetic Acid
Abstract Photocatalytic upcycling of organic molecules to methane is challenging due to the requisite multi‐electron transfers and competing formation of CO and...
Dual‐Salt Chaotropic Eutectic Electrolyte for Enhancing Low‐Temperature Zinc‐Ion Batteries
Abstract Aqueous zinc‐ion batteries (ZIBs) exhibit severe performance degradation at low temperatures primarily due to the freezing of water. To mitigate this is...
Single‐Atom Pt with Significantly Boosted Performance by Mesoporous Hollow Ceria Support for Dehydrogenation of Methylcyclohexane
Abstract Methylcyclohexane/toluene (MCH/TOL) is a promising liquid organic hydrogen carrier (LOHC) due to their low toxicity and compatibility with existing foss...
Monodentate Formate‐Mediated Toluene Methylation to Xylene at Low Temperature Using Formic Acid and Hydrogen
Abstract The industrial methanol–toluene methylation process for xylene production faces a challenge of lowering the reaction temperature while suppressing the s...
High‐Spin Cobalt Oxyhydroxide Enhancing Electrocatalytic Oxidation of 5‐Hydroxymethylfurfural to FDCA
Abstract The oxidation of 5‐hydroxymethylfurfural (HMF) to 2,5‐furandicarboxylic acid (FDCA) is governed by the high‐valence metal ion in the catalysts. Spin reg...
Amphiphilic Reactive Interfaces Enable Controlled Synthesis of Mesoscopic Covalent Organic Frameworks
Abstract Interfaces serve as powerful, versatile platforms that have significantly advanced the development of novel materials. However, bottom‐up construction o...
Mesoporous Engineering of Single‐Atom Catalyst for Industry‐Level Electrocatalytic CO <sub>2</sub> Reduction in Membrane Electrode Assemblies
Abstract Atomically dispersed transition metals anchored on nitrogen‐doped carbon have emerged as highly promising electrocatalysts for the electrochemical CO...
Nanocrystalline Sn for Photoelectrocatalytic Synthesis of Stereocontrolled Oxime
Abstract Oximes (including E / Z configurations) stand as pivotal intermediates i...
Steering Pulsed Electrochemistry Selectivity Toward Singlet Oxygen via Dynamic Intermediate Management
Abstract The electrocatalytic generation of singlet oxygen ( 1 O 2 ) from molecul...
Structurally Asymmetric Nonplanar π‐Conjugated Naphthoquinone Derivatives Modified from Natural Lawsone for High‐Stability Aqueous Redox Flow Batteries
Abstract Aqueous organic redox flow batteries (AORFBs) have attracted growing interest for grid‐scale energy storage by reducing reliance on scarce mineral resources used in transiti...
Yb‐Doped Cu‐Based Catalyst Boosting Electrochemical CO <sub>2</sub> ‐to‐C <sub>2+</sub> Reduction Across pH Range at Ampere‐Level Current Density
Abstract Efficient electrochemical conversion of CO 2 to multi‐carbon (C 2+ ) pro...
N‐Heterocyclic Carbene Monolayers on Nickel, Iron, and Steel by a Radical‐to‐Carbene Strategy
Abstract N‐Heterocyclic carbenes (NHCs) have recently emerged as the next‐generation surface ligands with improved stability and molecular flexibility. Despite these premises, resear...
Multilayer Sulfide‐Electrolyte Engineering Stabilizes Interfaces for Long‐Cycling, Wide‐Temperature Lithium–Organic Solid‐State Batteries
Abstract Interfacial instability remains a key barrier for sulfide electrolyte‐based all‐solid‐state lithium–organic batteries (ASSLOBs). While prior efforts hav...
Amino Acid Platform for Poly(amino ester)s: Controlled Ring‐Opening Polymerization, Complete Recyclability, and Tunable Polymerizability/Depolymerizability
Abstract Poly(amino ester) (PAE) is a class of polyesters featuring backbone tertiary amines and ester bonds, combining biodegradability with tunable functionali...
Energy‐Transfer‐Enabled Skeletal Rearrangement of Cyclic Ketones into Strained Cyclopropane‐Fused Medium Rings
Abstract Cyclopropane‐fused medium rings (CFMR) are attractive structural motifs that combine high strain with unique three dimensionality, however their efficient and modular synthe...
Geometric Preorganization Enables Entropy‐Constrained Proton Migration for Ultrafast and Stable Aqueous Proton Batteries
Abstract The development of aqueous proton batteries (APBs) is hindered by the scarcity of electrode materials capable of regulating proton migration. Although o...
Selective Singlet Oxygen Generation over a Silver–Porphyrin Single‐Atom‐Site Catalyst for Ultrafast Sulfide Photooxidation
Abstract The selective oxidation of sulfides to sulfoxides represents a fundamental transformation in synthetic and pharmaceutical chemistry, yet most catalytic...
Correction to “Activatable Type I Photosensitizer with Quenched Photosensitization Pre and Post Photodynamic Therapy”
Thiourea‐Functionalized Ionizable Lipids Enable Systemic mRNA Delivery to Secondary Lymphoid Organs and Dual‐Modal Lymphatic Metastasis Imaging
Abstract Systemic delivery of messenger RNA (mRNA) to non‐hepatocytes using lipid nanoparticles (LNPs) remains challenging. Inspired by anion coordination chemis...
Mimicking Macrophage Immune Mechanism for Infection and Thrombosis Prevention on a Dual‐Activity Hybrid Enzyme‐Assembled Surface
Abstract Surfaces with antithrombotic and anti‐infective properties are essential for ensuring the successful clinical performance of extracorporeal circuits and indwelling medical d...