Angewandte Chemie International Edition
Articles in this Issue
Near‐Infrared‐Activated Multiphoton Photocatalytic System for Synergistic Therapy via CO Generation and •OH Production
ABSTRACT Light‐triggered controllable carbon monoxide (CO) release represents a promising approach for cancer therapy but is limited by the poor tissue penetrati...
Construction of Chiral Frustrated Lewis Pair Framework for Efficient Asymmetric Hydrosilylation of Imines and Enantiomeric Separation
ABSTRACT Construction of stable and highly crystalline chiral frustrated Lewis pair (FLP) frameworks can enhance their prospects for application in practical tra...
Single‐Atom and 1 nm Cluster Co‐Modified Thermoelectrics
ABSTRACT The size‐dependent electronic and phononic configurations of single atoms and nanoclusters enable tailored functionalities. Their synergistic effects al...
A Facile Neutral Nickel Catalyst Platform for High‐Temperature Solution Copolymerization of Ethylene and Acrylate
ABSTRACT Polyolefins are among the most important large‐scale polymers. High‐temperature solution polymerization is one of the most effective methods for prepari...
Steering Zeolite Brønsted Acidity and Catalytic Consequence Through Manipulating the Coordination Environment of Framework Aluminum
ABSTRACT The strong acidity of Brønsted acid sites in zeolites often leads to uncontrollable reactions and rapid deactivation. Therefore, strategically weakening...
Electron Transfer Mediator–Enabled Modular Control of <sup>1</sup> O <sub>2</sub> and O <sub>2</sub> <sup>•–</sup> Generation in Porphyrin Supramolecular Frameworks for Selective Photosynthesis
ABSTRACT The inherent preference of classical type II photosensitizers for generating singlet oxygen ( 1 O...
Enantiospecific Optical Sensing of Terpenes by an Aggregated Atropisomeric Platinum(II) Complex
Abstract Terpenes are unfunctionalized small volatile organic compounds (VOCs) that are naturally abundant, relevant to climate change, and impose potential health risks. Herein, we...
Dual‐Site Geometry Mediates Dynamic LiO <sub>2</sub> Binding for Efficient Lithium–Oxygen Batteries
ABSTRACT Lithium–oxygen batteries (LOBs) offer high energy density through multi‐electron transfer, but their 2e − pathwa...
Temperature‐Potential Coupled Regulation of LiPF <sub>6</sub> Decomposition to Construct LiF Grain Boundary‐Rich Interphase on Graphite Anode for Fast‐Charging Li‐Ion Batteries
ABSTRACT Regulating the electrolyte decomposition to evolve a LiF‐rich solid‐electrolyte interphase (SEI) can reduce the energy barrier of the interfacial Li‐ion...
Unveiling the Superior Birefringence Property of a Record‐Birefringent Crystal with Unique Building Block
Abstract Despite being crucial for various advanced optical components, obtaining optically anisotropic crystals with giant birefringence (e.g., Δ...
Leveraging Diamines to Unlock the Mn‐MACHO Catalyst in the Reduction of CO <sub>2</sub> to Methanol
Abstract The conversion of CO 2 into energy‐dense liquid fuels, such as methanol, represents a cornerstone of sustainable...
Sulfone–Isoquinoline Dopants Activated Phosphorescence Beyond Room Temperature
ABSTRACT Purely organic room‐temperature phosphorescence (RTP) materials are of growing interest for bioimaging, anti‐counterfeiting, and optoelectronic applications. However, impuri...
Building Molecules by a Self‐Replicator That Catalyzes Acyl Hydrazone Formation
Abstract Catalysis of bond‐forming reactions is key to the development of life‐like chemical systems as it allows to build up new material, increasing molecular complexity and divers...
Molecular‐Scale Tuning of Low‐Molecular‐Weight Gelators Controls Supramolecular Assembly and Directs Human Mesenchymal Stem Cell Growth
Abstract We report the synthesis and characterization of a simple alcohol‐functionalized low‐molecular‐weight gelator (LMWG) based on a 1,3:2,4‐dibenzylidenesorb...
Carbonyl Functionalized Azaphosphinine‐Based Multiple‐Resonance Emitters via Regulated p/n/σ–π Hybrid Conjugation
Abstract Doping heteroatoms with non‐typical electronic couplings offered the great opportunity to fine‐tune chemical structures and optoelectronic properties of...
Temperature‐Responsive Near‐Infrared Emission Enabled by Reversible π‐Umpolung with an Alkenyl‐Strapped Diarylboryl Unit
Abstract Coordination of a Lewis base to a tricoordinate boryl group generates a tetracoordinate species, thereby inverting the electronic character of the boryl...
Where Enantioselection is Set: A Mechanistic Framework for Asymmetric Hydrogen‐Atom Transfer
Abstract Hydrogen‐atom transfer (HAT) lies at the heart of radical chemistry, yet asymmetric HAT has been difficult because the high reactivity of radicals often...
Core‐Shell: Resolving the Dilemma of Hard Carbon Anodes by Sealing Nanoporous Particles With Semi‐Permeable Coatings
Abstract A core‐shell strategy is introduced to overcome the dilemma of common non‐graphitic hard carbon anodes, linking high reversible storage capacity to prac...
Outside Front Cover: Dual Circularly Polarized Luminescence from Chiral Boron‐Embedded Polycyclic Aromatic Hydrocarbons (Angew. Chem. Int. Ed. 10/2026)
Biomass‐Derived Ion‐Selective Binder Modulates Zn <sup>2+</sup> Solvation Enabling High‐Capacity Cathodes in Aqueous Zinc Batteries
Abstract The electrochemical performance of aqueous zinc batteries (AZBs) critically relies on advanced binders to regulate the solvation structure of hydrated Z...
Outside Back Cover: Stability Thresholds of Atomically Dispersed Platinum Catalysts for Solar Hydrogen Production (Angew. Chem. Int. Ed. 10/2026)
Enhanced‐mRNA Delivery Using Ultrasound‐Delivered Anchors for Bioorthogonal Ligation
Abstract Therapeutic nucleic acid delivery has many potential applications, but it remains challenging to target extrahepatic tissues in a flexible and image‐guided manner. To addres...
Nickel‐Catalyzed Enantioselective Reductive Heck Reaction of Olefins with Aryl Bromides and Chlorides Enabled by Chiral NHC Ligands
Abstract Despite significant advances in catalytic asymmetric reductive Heck reaction, most reported methods rely on highly reactive aryl electrophiles and exhib...
Diffraction‐Enabled Operando Nanoscale Tracking of Li‐ion Dynamics of Solid Electrolyte and Inhomogeneous Diffusion in Composite Cathode
Abstract Li + diffusion has mostly been studied in cathode active materials (CAMs) in liquid batteries, whereas it remain...
Reimagining <i>o</i> ‐Carborane‐Based Fluorophores: Charge‐Transfer from Boron Substituents Triggers Aggregation‐ and Crystallization‐Induced Emission
Abstract o ‐Carborane‐based fluorophores are widely recognized for their aggregation‐induced and crystallization‐induced emission (AIE and CI...